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第3期 刘应书等:密闭环境内固体吸收剂循环净化C02反应特性 ·365· 2.13nc02 救生专业分会第五届学术年会论文集.北京,1998:201) (m,)c=-0.12nm.+0.55nr-0.07 [8]Jiang L,Zhao J H.Research on absorption methods of carbon di- 2.48nco2 oxide applied in human occupied vehicle.Shipbuild China,2010, (rcm)-0.02-0.075nn+0.46n0' 51(3):169 (姜磊,赵俊海.载人深潜器二氧化碳清除方式研究.中国造 且最大反应速率rA>IH>TcA· 船,2010,51(3):169) (4)实际应用LI-1、CA-1和NA1三种吸收剂 [9] Zhu W Y,Gong Z G,Zhang Z M,et al.The technologies of syn- 进行密闭环境C02质量浓度控制时,环境中的C02 thetical decontaminating harmful gases in submarine.Ship Sci Technol,.2008,30(6):179 体积分数理论上会在0.27%、0.45%和0.24%这三 (祝维燕,宫志刚,张志梅,等.潜艇有害气体综合净化技术 个中间值附近波动. 舰船科学技术,2008,30(6):179) [10]Bamsey M,Graham T,Stasiak M,et al.Canadian advanced life 参考文献 support capacities and future directions.Adr Space Res,2009, 44(2):151 [1]She Y Z,Jiang Y L,Li J,et al.Experimental study on CO dispo- [11]Li J,Jin LZ,Wang S.Research on the device of carbon dioxide sition methods in an enclosed chamber.J China Coal Soc,2011, purification in coal mine refuge chamber.Saf Coal Mines,2010 36(9):1519 (10):1 (佘阳梓,蒋彦龙,李俊,等.密闭小空间内C0净化方法探 (栗婧,金龙哲,汪声.矿用救生舱中二氧化碳净化装置研 究.煤炭学报,2011,36(9):1519) 究.煤矿安全,2010(10):1) Wang PX.Space Enrironmental Control and Life Support Engi- [12]Du Y,Jin L Z,Wang S,et al.Study on purification characteris- neering.Beijing:National Defense Industry Press,2003 tic of carbon dioxide in mine refuge chamber.J Saf Sci Technol, (王普秀.航天环境控制与生命保障工程基础.北京:国防工 2012,8(7):20 业出版社,2003) (杜焱,金龙哲,汪声,等.矿用救生舱内二氧化碳净化特性 B]Chen G N.Carbon dioxide control in closed environment//Pro- 研究.中国安全生产科学技术,2012,8(7):20) ceedings of the Second Session of National of Man-Machine-Enri- [13]State Administration of Work Safety.MT454-2008 The Calcium ronment System Engineering Academic Conference.Beijing,1995: Hydroxide Specification for the Isolation Type Oxygen Respirator 152 and Self-rescuer.Beijing:Coal Industry Press,2009 (陈根年.密闭环境中二氧化碳的控制/第二届全国人一机一 (国家安全生产监督管理总局.MT454一2008隔绝式氧气呼 环境系统工程学术会议论文集.北京,1995:152) 吸器和自救器用氢氧化钙技术条件.北京:煤炭工业出版 4]Cao L B,Xu L,Li J.Purification method for CO,in mine rescue 社,2009) capsule and experimental study.Coal Min Saf Enriron Prot, [14]Zhu B C.Chemical Reaction Engineering.5th Ed.Beijing: 2012,39(2):16 Chemical Industry Press,2012 (曹利波,徐雷,李俊.矿用救生舱C02净化方法与试验研 (朱炳辰.化学反应工程.5版.北京:化学工业出版社, 究.矿业安全与环保,2012,39(2):16) 2012) 5]Stutte G W,Wheeler R M.Accumulation and effect of volatile or- [15]Shih M S,Ho C S,Song Y S,et al.Kinetics of the reaction of ganic compounds in closed life support systems.Ade Space Res, Ca(OH)2 with CO2 at low temperature.Ind Eng Chem Res, 1997,20(10):1913 1999,38(4):1316 [6]He Z J,Yu F,He XX,et al.Gas chromatography/mass spectro- 016]Haghnegahdar M R,Rahimi A,Hatamipour M S.A rate equa- metric analysis for volatile organic compound of human metabolites tion for Ca(OH)2 and CO2 reaction in a spouted bed reactor at in sealed cabin.Chin J Anal Chem,2011,29(8):978 low gas concentrations.Chem Eng Res Des,2011,89(6):616 (何正杰,于芳,何新星,等.密闭环境中人体自身代谢挥发 17] Haghnegahdar M R,Hatamipour M S,Rahimi A.Removal of 性有机化合物气相色谱/质谱分析.分析化学,2011,29(8): carbon dioxide in an experimental powder-particle spouted bed re- 978) actor.Sep Purif Technol,2010,72(3):288 ]Xu C L.Qi Z N,Chang S Y,et al.Experimental observation of 18] Specifications for Coal Mine Mobile Refuge Chambers [EB/OL]. the confined cabin body energy metabolism and harmful gas effu- State Administration of Work Safety [20119-3].http://www. ent/Proceedings of the Fifih Annual Conference Proceedings of chinasafety.gov.en/newpage/Contents/Channel_6292/2011/ the Chinese Society of Aeronautics and Astronautics Human Engi- 0914/148432/fle5_founder_2860120146/201964623.doc neering,Ariation Medicine,Life-saving Professional Chapters.Bei- (煤矿可移动式硬体救生舱通用技术条件EB/0L].国家安 jing,1998:201 全生产监督管理总局[20119-3].http:/hwww.chinasafety.. (徐国林,祁章年,常绍勇,等.密闭舱内人体能量代谢及有 gov.cn/newpage/Contents/Channel_6292/2011/0914/148432/ 害气体排出物的实验观察/中国航空学会人体工程、航医、 fles_founder_2860120146/201964623.doc)第 3 期 刘应书等: 密闭环境内固体吸收剂循环净化 CO2 反应特性 ( rCO2 ) CA--1 = 2. 13nCO2 0. 12nCO2 + 0. 55n0. 752 CO2 - 0. 017, ( rCO2 ) NA--1 = 2. 48nCO2 0. 02 - 0. 075nCO2 + 0. 46n0. 88 CO2 , 且最大反应速率 rNA--1 > rLI--1 > rCA--1 . ( 4) 实际应用 LI--1、CA--1 和 NA--1 三种吸收剂 进行密闭环境 CO2 质量浓度控制时,环境中的 CO2 体积分数理论上会在 0. 27% 、0. 45% 和 0. 24% 这三 个中间值附近波动. 参 考 文 献 [1] She Y Z,Jiang Y L,Li J,et al. Experimental study on CO dispo￾sition methods in an enclosed chamber. J China Coal Soc,2011, 36( 9) : 1519 ( 佘阳梓,蒋彦龙,李俊,等. 密闭小空间内 CO 净化方法探 究. 煤炭学报,2011,36( 9) : 1519) [2] Wang P X. Space Environmental Control and Life Support Engi￾neering. Beijing: National Defense Industry Press,2003 ( 王普秀. 航天环境控制与生命保障工程基础. 北京: 国防工 业出版社,2003) [3] Chen G N. Carbon dioxide control in closed environment / / Pro￾ceedings of the Second Session of National of Man-Machine-Envi￾ronment System Engineering Academic Conference. Beijing,1995: 152 ( 陈根年. 密闭环境中二氧化碳的控制 / / 第二届全国人--机-- 环境系统工程学术会议论文集. 北京,1995: 152) [4] Cao L B,Xu L,Li J. Purification method for CO2 in mine rescue capsule and experimental study. Coal Min Saf Environ Prot, 2012,39( 2) : 16 ( 曹利波,徐雷,李俊. 矿用救生舱 CO2 净化方法与试验研 究. 矿业安全与环保,2012,39( 2) : 16) [5] Stutte G W,Wheeler R M. Accumulation and effect of volatile or￾ganic compounds in closed life support systems. Adv Space Res, 1997,20( 10) : 1913 [6] He Z J,Yu F,He X X,et al. Gas chromatography /mass spectro￾metric analysis for volatile organic compound of human metabolites in sealed cabin. Chin J Anal Chem,2011,29( 8) : 978 ( 何正杰,于芳,何新星,等. 密闭环境中人体自身代谢挥发 性有机化合物气相色谱/质谱分析. 分析化学,2011,29( 8) : 978) [7] Xu G L,Qi Z N,Chang S Y,et al. Experimental observation of the confined cabin body energy metabolism and harmful gas efflu￾ent / / Proceedings of the Fifth Annual Conference Proceedings of the Chinese Society of Aeronautics and Astronautics Human Engi￾neering,Aviation Medicine,Life-saving Professional Chapters. Bei￾jing,1998: 201 ( 徐国林,祁章年,常绍勇,等. 密闭舱内人体能量代谢及有 害气体排出物的实验观察 / / 中国航空学会人体工程、航医、 救生专业分会第五届学术年会论文集. 北京,1998: 201) [8] Jiang L,Zhao J H. Research on absorption methods of carbon di￾oxide applied in human occupied vehicle. Shipbuild China,2010, 51( 3) : 169 ( 姜磊,赵俊海. 载人深潜器二氧化碳清除方式研究. 中国造 船,2010,51( 3) : 169) [9] Zhu W Y,Gong Z G,Zhang Z M,et al. The technologies of syn￾thetical decontaminating harmful gases in submarine. Ship Sci Technol,2008,30( 6) : 179 ( 祝维燕,宫志刚,张志梅,等. 潜艇有害气体综合净化技术. 舰船科学技术,2008,30( 6) : 179) [10] Bamsey M,Graham T,Stasiak M,et al. Canadian advanced life support capacities and future directions. Adv Space Res,2009, 44( 2) : 151 [11] Li J,Jin L Z,Wang S. Research on the device of carbon dioxide purification in coal mine refuge chamber. Saf Coal Mines,2010 ( 10) : 1 ( 栗婧,金龙哲,汪声. 矿用救生舱中二氧化碳净化装置研 究. 煤矿安全,2010( 10) : 1) [12] Du Y,Jin L Z,Wang S,et al. Study on purification characteris￾tic of carbon dioxide in mine refuge chamber. J Saf Sci Technol, 2012,8( 7) : 20 ( 杜焱,金龙哲,汪声,等. 矿用救生舱内二氧化碳净化特性 研究. 中国安全生产科学技术,2012,8( 7) : 20) [13] State Administration of Work Safety. MT454—2008 The Calcium Hydroxide Specification for the Isolation Type Oxygen Respirator and Self-rescuer. Beijing: Coal Industry Press,2009 ( 国家安全生产监督管理总局. MT454—2008 隔绝式氧气呼 吸器和自救器用氢氧化钙技术条件. 北京: 煤炭工业出版 社,2009) [14] Zhu B C. Chemical Reaction Engineering. 5th Ed. Beijing: Chemical Industry Press,2012 ( 朱炳辰. 化 学 反 应 工 程. 5 版. 北 京: 化 学 工 业 出 版 社, 2012) [15] Shih M S,Ho C S,Song Y S,et al. Kinetics of the reaction of Ca( OH) 2 with CO2 at low temperature. Ind Eng Chem Res, 1999,38( 4) : 1316 [16] Haghnegahdar M R,Rahimi A,Hatamipour M S. A rate equa￾tion for Ca( OH) 2 and CO2 reaction in a spouted bed reactor at low gas concentrations. Chem Eng Res Des,2011,89( 6) : 616 [17] Haghnegahdar M R,Hatamipour M S,Rahimi A. Removal of carbon dioxide in an experimental powder-particle spouted bed re￾actor. Sep Purif Technol,2010,72( 3) : 288 [18] Specifications for Coal Mine Mobile Refuge Chambers [EB /OL]. State Administration of Work Safety[2011-9-13]. http: / /www. chinasafety. gov. cn / newpage /Contents/Channel _ 6292 /2011 / 0914 /148432 /files_founder_2860120146 /201964623. doc ( 煤矿可移动式硬体救生舱通用技术条件[EB /OL]. 国家安 全生产监督管理总局[2011--9--13]. http: / /www. chinasafety. gov. cn / newpage /Contents/Channel _ 6292 /2011 /0914 /148432 / files_founder_2860120146 /201964623. doc) · 563 ·
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