Radical Reactions and How They Occur Radicals react to complete electron octet of valence shell A radical can abstract an atom and one bonding electron from another molecule,leaving behind a new radical Unpaired electron /Unpaired electron Rad.+A:B Rad:A B Reactant Substitution Product radical product radical A radical can add to an alkene to give a new radical (radical addition reaction) Unpaired electron Unpaired electron Rad Rad. Reactant Alkene Addition product radical radicalRadical Reactions and How They Occur Radicals react to complete electron octet of valence shell A radical can abstract an atom and one bonding electron from another molecule, leaving behind a new radical A radical can add to an alkene to give a new radical (radical addition reaction)