Second law- Gibbs Spontaneous processes increase the overall"disorder of the universe Reasoning through an example microstates to achieve macrostate Gibbs postulate: for an isolated system, all microstates compatible with the given constraints of the macrostate Chere E,v and w are equally likely to occur Here 2 ways to distribute n molecules into 2 bulbsSecond Law – Gibbs ƒ Spontaneous processes increase the overall “disorder” of the universe ™ Reasoning through an example - microstates to achieve macrostate Gibbs postulate: for an isolated system, all microstates compatible with the given constraints of the macrostate (here E, V and N) are equally likely to occur - Here 2N ways to distribute N molecules into 2 bulbs