第10章烯烃、炔烃、共轭二烯烃和脂环烃 10-1 CH3 HBeCHCl H -C<O· CH3 OH Br Br ®机过单QG码 ~Br w,○CH 69C<0· OH (顺式产物) OH OH -CH3 2)H02,0H OH eoaa9Co CH3 2)NaBH4 0 3)Zn.H.O→CH,CCH6CH0 03 Br y器，○aH,+cH,cBr Br DHs0,了oH CHz 10-2 一丁炔 CI (CH2=CCH:CHs CHs CCH.CHs ，0S8auG4 C.C.CHC (s)CH2=CHCH2CH3 (CH;CH2CH2CH3 ()CH2=CHCH2CH3 (AgG=CCH2CH3 (s)CHCH2C=CCH2CH3 (10)CH:CCH2CH3 (CHCH2COOH CO2 1 1
10    10
1 Br2 /CCl4 CH3 CH3 Br Br CH3 Br H Br CH3 Br + HBr/CHCl3 CH3 OH Br Br2 /H2O OH CH3 Br + CH3 Br HBr /￾✂✁☎✄✂✆☎✝✂✞ CH3 OH H2 /Pd CH3 ✟☎✠KMnO4 OH CH3 OH (
 ✡☞☛✍✌✏✎✒✑✍✓✔✌✖✕ 1 ) 2 ) H2O2 ,OH CH3 OH 1 )Hg(OAc)2 ,H2O 2 ) NaBH4 CH3 1 ) O3 2 ) Zn,H2O O CH3C(CH2 )6CHO Br2 / ✗✙✘ Br 1 )H2SO4 2 ) H2O CH3 OH CH3 Br + + CH3 OH OH + OH CH3 + CH2Br 10-2 1✚✜✛✣✢ ✤ 1 ✥ CH2=CCH2CH3 Cl (2 ) CH3CCH2CH3 Cl Cl (3) CH=CHCH2CH3 Br Br (4 ) CHBr2CBr2CH2CH3 (5 ) CH2=CHCH2CH3 (6 ) CH3CH2CH2CH3 (7 )CH2=CHCH2CH3 (9 ) AgC CCH2CH3 (10) CH3CCH2CH3 O (8 ) CH3CH2C CCH2CH3 (11 ) CH3CH2COOH + CO2