杨俊彦等：钨治炼渣综合回收利用的研究进展 ·1475· 和锰.矿产保护与利用，1989(1)：42) using P507 from hydrochloric acid leaching solution of red mud. [26]5.1O.KopoBH.Based on the data of 3P nuclear magnetic reso- Chemosphere,2017,175:365 nance (NMR)and 45Se with Th and TB3KC-TB extracting [36]Zhang P W,Jiang Y H.Zhang L,et al.C1-P350 extract and its scandium from the sulfuric acid solution.Hydrometall China, extraction of scandium.Chin Rare Earths,1990(2):12 1992(1):46 (张平伟，蒋蕴华，张力，等.C-P(350)萃淋树脂及其对 (5.O.KopoBn阻.依据1P和5Sc核磁共振资料用T5中和 钪的萃取.稀土，1990(2)：12) TB3KC-T5Φ从硫酸溶液中萃取钪.湿法治金，1992(1)： [37]Li NN.Membarne Separation:US Patent,3566580.1968-11- 46) 27 [27]Liu H Z,Tang H M.Research on extraction of scandium from [38]Fan W Y,Xu T W.Study on the extraction of scandium with tungsten residue.Shanghai Environ Sci,1990,9(3):11 emulsion liquid membrane ELM).J Hefei Unir Technol Nat (刘慧中，汤惠民.从钨渣中提取钪的研究.上海环境科学， S,1994,17(3):50 1990,9(3):11) (范文元，徐铜文.乳状液膜法提取钪的研究.合肥工业大 [28]Liu C Y,Fu J G.Experimental study on extraction and recovery 学学报（自然科学版），1994,17(3)：50) of scandium from tungsten residue.Rare Met Cem Carbides, [39]Zhang YY,Yu S H,Chang Z Y,et al.Study on extracting 2015,43(5):4 scandium of liquid membrane technology.ShanghaiMet Nonfer- (刘彩云，符剑刚.钨渣中钪的萃取回收实验研究.稀有金 rous Fa.sc,1990,11(2):9 属与硬质合金，2015,43(5)：4) (张月英，余守慧，常增有，等.液膜技术提取钪的研究.上 [29]Ding C,Liu X,Wang X H,et al.N235 TBP preextraction of 海金属（有色分册），1990,11(2)：9) Zr from wolframine residue containing Sc.Metal Mine,2016 [40]XuT W,Fan W Y,Wang S T.Extraction of scandium with e- (9):112 mulsion liquid membrane ELM).J Chem Eng Chin Unir, (丁冲，刘秀，王晓辉，等.含钪黑钨渣酸浸液中锫的N235 1994,8(3):237 +TBP预萃取.金属矿山.2016(9)：112) (徐铜文，范文元，王绍亭.乳状液膜法提取钪.高校化学工 [30]Liu J M.Yang R D,Guo M.Extraction separation of scandium 程学报，1994,8(3)：237) from sulfuric acid aqueous solution and its application.Chin Rare [41]Benvenuti M,Orlando A,Borrini D,et al.Experimental smel- Earths,1997,18(1):6 ting of iron ores from Elba Island (Tuscany,Italy):results and (刘建民，杨汝栋，郭敏.BPMOPD对硫酸介质中钪的萃取 implications for the reconstruction of ancient metallurgical proces- 分离及其应用.稀土，1997,18(1)：6) ses and iron provenance.J Archaeol Sci,2016,70:1 [31]Zhang X Y,Wang X Y.Extraction behavior and mechanism of [42]Jing Q X,Guo H,Wang W.Preparation and performance of por- Sc (Ill)with sec-nonylphenoxy acetic acid.Chin Rare Met, ous ceramic from diatomite with waste tungsten residue.China 2004,28(2):800 Ceram,2017,53(4):52 (张秀英，王秀艳.新型萃取剂仲壬基苯氧基乙酸萃取钪 (靖青秀，郭欢，王魏.硅藻土摻杂钨渣制备多孔陶粒及其 (Ⅲ)的机制研究.稀有金属，2004,28(2)：800) 性能研究.中国陶瓷，2017,53(4)：52) [32]Xu Y B.Niu Y N,Ding H J,et al.Extraction of Se with 1-phe- [43]Choi Y W,Kim Y J,Choi 0,et al.Utilization of tailings from nyl-3-methyl-4-benzoyl-5-pyrazolone from HNO media.Sci tungsten mine waste as a substitution material for cement.Constr Technol Eng,2004.4(7):531 Build Mater,2009.23(7):2481 (徐岩冰，牛雁宁，丁华杰，等.用1苯基3-甲基4苯甲酰 [44]Kim Y J,Kim Y J,Choi Y W.An experimental research on self- 基-5-吡唑啉酮从硝酸介质中萃取钪.科学技术与工程， consolidating concrete using tungsten mine tailings.KSCE Civil 2004,4(7):531) Eng,2016,20(4):1404 [33]Zhou YY.Ion exchange separates scandium.Jiangxi Nonferrous [45]Liu WZ,Wu T,Li Z,et al.Preparation and characterization of Md,1991(4):23 ceramic substrate from tungsten mine tailings.Constr Build Ma (周永益.离子交换分离钪.江西有色金属，1991(4)：23) ter,2015,77:139 [34]Yatsenko S P,Pyagai I N.Red mud pulp carbonization with [46]Li B Q,Guo Y P,Dang H F,et al.Effect of crystallization tem scandium extraction during alumina production.Theor Found perature on crystallization properties of glass ceramics from tung Chem Eng,2010,44(4):563 sten tailings.China Ceram,2017,53(11):63 [35]Zhu X B.Li W.Tang S,et al.Selective recovery of vanadium (李保庆，郭艳平，党海峰，等.品化温度对钨尾矿微品玻璃 and scandium by ion exchange with D201 and solvent extraction 析品性能的影响.中国陶瓷，2017.，53(11)：63)杨俊彦等: 钨冶炼渣综合回收利用的研究进展 和锰. 矿产保护与利用, 1989(1): 42) [26] 丌. 乩. 噩剜剽剜赜刳剡. Based on the data of 31 P nuclear magnetic reso鄄 nance (NMR) and 45 Sc with 卮丌囟 and 卮兀乜噩爻鄄 卮丌囟 extracting scandium from the sulfuric acid solution. Hydrometall China, 1992(1): 46 (丌. 乩. 噩剜剽剜赜刳剡. 依据31 P 和45 Sc 核磁共振资料用 卮丌囟 和 卮兀乜噩爻鄄卮丌囟 从硫酸溶液中萃取钪. 湿法冶金, 1992 (1 ): 46) [27] Liu H Z, Tang H M. Research on extraction of scandium from tungsten residue. Shanghai Environ Sci, 1990, 9(3): 11 (刘慧中, 汤惠民. 从钨渣中提取钪的研究. 上海环境科学, 1990, 9(3): 11) [28] Liu C Y, Fu J G. Experimental study on extraction and recovery of scandium from tungsten residue. Rare Met Cem Carbides, 2015, 43(5): 4 (刘彩云, 符剑刚. 钨渣中钪的萃取回收实验研究. 稀有金 属与硬质合金, 2015, 43(5): 4) [29] Ding C, Liu X, Wang X H, et al. N235 + TBP preextraction of Zr from wolframine residue containing Sc. Metal Mine, 2016 (9): 112 (丁冲, 刘秀, 王晓辉, 等. 含钪黑钨渣酸浸液中锆的 N235 + TBP 预萃取. 金属矿山, 2016(9): 112) [30] Liu J M, Yang R D, Guo M. Extraction separation of scandium from sulfuric acid aqueous solution and its application. Chin Rare Earths, 1997, 18(1): 6 (刘建民, 杨汝栋, 郭敏. BPMOPD 对硫酸介质中钪的萃取 分离及其应用. 稀土, 1997, 18(1): 6) [31] Zhang X Y, Wang X Y. Extraction behavior and mechanism of Sc (芋) with sec鄄nonylphenoxy acetic acid. Chin J Rare Met, 2004, 28(2): 800 (张秀英, 王秀艳. 新型萃取剂仲壬基苯氧基乙酸萃取钪 (芋)的机制研究. 稀有金属, 2004, 28(2): 800) [32] Xu Y B, Niu Y N, Ding H J, et al. Extraction of Sc with 1鄄phe鄄 nyl鄄3鄄methyl鄄4鄄benzoyl鄄5鄄pyrazolone from HNO3 media. Sci Technol Eng, 2004, 4(7): 531 (徐岩冰, 牛雁宁, 丁华杰, 等. 用 1鄄苯基鄄3鄄甲基鄄4鄄苯甲酰 基鄄5鄄吡唑啉酮从硝酸介质中萃取钪. 科学技术与工程, 2004, 4(7): 531) [33] Zhou Y Y. Ion exchange separates scandium. Jiangxi Nonferrous Met, 1991(4): 23 (周永益. 离子交换分离钪. 江西有色金属, 1991(4): 23) [34] Yatsenko S P, Pyagai I N. Red mud pulp carbonization with scandium extraction during alumina production. Theor Found Chem Eng, 2010, 44(4): 563 [35] Zhu X B, Li W, Tang S, et al. Selective recovery of vanadium and scandium by ion exchange with D201 and solvent extraction using P507 from hydrochloric acid leaching solution of red mud. Chemosphere, 2017, 175: 365 [36] Zhang P W, Jiang Y H, Zhang L, et al. C1鄄鄄P350 extract and its extraction of scandium. Chin Rare Earths, 1990(2): 12 (张平伟, 蒋蕴华, 张力, 等. Cl鄄鄄 P_(350)萃淋树脂及其对 钪的萃取. 稀土, 1990(2): 12) [37] Li N N. Membarne Separation: US Patent, 3566580. 1968鄄鄄11鄄鄄 27 [38] Fan W Y, Xu T W. Study on the extraction of scandium with emulsion liquid membrane ( ELM). J Hefei Univ Technol Nat Sci, 1994, 17(3): 50 (范文元, 徐铜文. 乳状液膜法提取钪的研究. 合肥工业大 学学报(自然科学版), 1994, 17(3): 50) [39] Zhang Y Y, Yu S H, Chang Z Y, et al. Study on extracting scandium of liquid membrane technology. ShanghaiMet Nonfer鄄 rous Fasc, 1990, 11(2): 9 (张月英, 余守慧, 常增有, 等. 液膜技术提取钪的研究. 上 海金属(有色分册), 1990, 11(2): 9) [40] Xu T W, Fan W Y, Wang S T. Extraction of scandium with e鄄 mulsion liquid membrane ( ELM). J Chem Eng Chin Univ, 1994, 8(3): 237 (徐铜文, 范文元, 王绍亭. 乳状液膜法提取钪. 高校化学工 程学报, 1994, 8(3): 237) [41] Benvenuti M, Orlando A, Borrini D, et al. Experimental smel鄄 ting of iron ores from Elba Island (Tuscany, Italy): results and implications for the reconstruction of ancient metallurgical proces鄄 ses and iron provenance. J Archaeol Sci, 2016, 70: 1 [42] Jing Q X, Guo H, Wang W. Preparation and performance of por鄄 ous ceramic from diatomite with waste tungsten residue. China Ceram, 2017, 53(4): 52 (靖青秀, 郭欢, 王魏. 硅藻土掺杂钨渣制备多孔陶粒及其 性能研究. 中国陶瓷, 2017, 53(4): 52) [43] Choi Y W, Kim Y J, Choi O, et al. Utilization of tailings from tungsten mine waste as a substitution material for cement. Constr Build Mater, 2009, 23(7): 2481 [44] Kim Y J, Kim Y J, Choi Y W. An experimental research on self鄄 consolidating concrete using tungsten mine tailings. KSCE J Civil Eng, 2016, 20(4): 1404 [45] Liu W Z, Wu T, Li Z, et al. Preparation and characterization of ceramic substrate from tungsten mine tailings. Constr Build Ma鄄 ter, 2015, 77: 139 [46] Li B Q, Guo Y P, Dang H F, et al. Effect of crystallization tem鄄 perature on crystallization properties of glass ceramics from tung鄄 sten tailings. China Ceram, 2017, 53(11): 63 (李保庆, 郭艳平, 党海峰, 等. 晶化温度对钨尾矿微晶玻璃 析晶性能的影响. 中国陶瓷, 2017, 53(11): 63) ·1475·