第6期 徐立昊等：入口气组分对质子交换膜燃料电池柴油水蒸气重整制氢流程的影响 ·717· [5]Dae HK,Jung S K,Yun JL,et al.Steam reforming of n-hexade- improving catalyst stability over Pt/ceria during ethanol steam re- cane over noble metal-modified Ni-based catalysts.Catal Today, forming:Sn addition and CO,co-feeding.Appl Catal B,2010, 2008,136(314):228 96(3/4):387 6]Sehested J,Gelten J A P,Remediakis I N,et al.Sintering of [20]Arena F,Trunfio G,Alongi E,et al.Modelling the activity-sta- nickel steam-reforming catalysts:effects of temperature and steam bility pattem of Ni/Mgo catalysts in the pre-reforming of n-hex- and hydrogen pressures.J Catal,2004,223(2):432 ane.Appl Catal A,2004,266(2):155 Pema A.Hydrogen from ethanol:theoretical optimization of a 1]Gong J,Su QQ.Mi W L,et al.Effect of inlet gas composition PEMFC system integrated with a steam reforming processor.IntJ on working temperature of natural gas steam reforming.J Chem Hydrogen Energy,2007,32(12):1811 Ind Eng China,2008,59 (3):687 [8]Alvarez-Galvan M C,Navarro R M,Rosa F,et al.Performance of (龚娟，苏庆泉，米万良，等.入口气体组成对天然气重整工 La,Ce-modified alumina-supported P and Ni catalysts for the ox 作温度的影响.化工学报，2008,59(3)：687) dative reforming of diesel hydrocarbons.Int J Hydrogen Energy, [2]Mi W L,Sun D J,Gong J,et al.CO water-gas-shift reaction 2008,33(2):652 character over Cu-Zn catalyst.J Unir Sci Technol Beijing,2010, 9]Parmar R D,Kundu A,Karan K.Thermodynamic analysis of 32(2):224 diesel reforming process:mapping of carbon formation boundary (米万良，孙丹杰，龚娟，等.Cu一Zm催化剂的C0水汽变换反 and representative independent reactions.Power Sources,2009, 应特性.北京科技大学学报，2010,32(2)：224) 194(2):1007 [23]Li Z Y,Mi W L,Gong J,et al.CO removal by two-stage metha- [10]Sharma S,Deshpande P A,Hedge M S,et al Nondeactivating nation for polymer electrolyte fuel cell.J Nat Gas Chem,2008, nanosized ionic catalysts for water-gas shift reaction.Ind Eng 17(4):359 Chem Res,2009,48(14):6535 24 Hernandez L,Kafarov V.Thermodynamic evaluation of hydrogen [11]Choudhury M B I,Ahmed S,Shalabi M A,et al.Preferential production for fuel cells by using bio-ethanol steam reforming: methanation of CO in a syngas involving CO2 at lower temperature effect of carrier gas addition.J Power Sources,2009,192 (1): range.Appl Catal A,2006,314(1)47 195 [12]Xu L H.Mi W L,Su QQ.Hydrogen production through diesel D5]Batista M S,Santiago E I,Assaf E M,et al.Evaluation of the steam reforming over rare-earth promoted Ni/y-l2O:catalysts. water-gas shift and CO methanation processes for purification of Nat Gas Chem,2011,20(3):287 reformate gases and the coupling to a PEM fuel cell system. [13]Christensen TS.Adiabatic prereforming of hydrocarbons:an im- Powcer Sources,2005,145(1)50 portant step in syngas production.Appl Catal A,1996,138(2): [26个 Laosiripojana N,Sutthisripok W,Charojrochkul S,et al.Steam 285 reforming of IPG over Ni and Rh supported on Gd-CeO and [14]Cromarty B J,Hooper C W.Increasing the throughput of an ex- Al2:effect of support and feed composition.Fuel,2011,90 isting hydrogen plant.Int J Hydrogen Energy,1997,22(1):17 (1):136 [15]Armor J N.The multiple roles for catalysis in the production of [27]Xie C,Chen Y S,Li Y,et al.Influence of sulfur on the carbon H2.Appl Catal A,1999,176(2):159 deposition in steam reforming of liquid hydrocarbons over Ce0- [16]Peters R,Riensche E,Cremer P.Pre-reforming of natural gas in Al.O3 supported Ni and Rh catalysts.Appl Catal A,2011,394 solid oxide fuel-cell systems.J Power Sources,2000,86(1/2): (1/2):32 432 [28] Zheng J,Strohm JJ,Song C S.Steam reforming of liquid hydro- [17]Laosiripojana N,Assabumrungrat S.Catalytic steam reforming of carbon fuels for micro-fuel cells:pre-reforming of model jet fuels ethanol over high surface area Ce02:the role of Ce02 as an inter- over supported metal catalysts.Fuel Process Technol,2008,89 nal pre-teforming catalyst.Appl Catal B,2006,16(1/2):29 (4):440 [18]Chen FZ,Zha S W,Dong J,et al.Pre-reforming of propane for 129]Li Z Y,Mi WL,Su QQ.Deep removal of CO in reformate.J low-emperature SOFCs.Solid State lonics,2004,166(3/4): Univ Sci Technol Beijing,2010,32(1)100 269 (李志远，米万良，苏庆泉.重整气中C0深度去除方法.北 [19]de Lima S M,da Silva A M,Jacobs G,et al.New approaches to 京科技大学学报，2010,32(1)：100)第 6 期 徐立昊等: 入口气组分对质子交换膜燃料电池柴油水蒸气重整制氢流程的影响 ［5］ Dae H K，Jung S K，Yun J L，et al． Steam reforming of n-hexade￾cane over noble metal-modified Ni-based catalysts． Catal Today， 2008，136( 3 /4) : 228 ［6］ Sehested J，Gelten J A P，Remediakis I N，et al． Sintering of nickel steam-reforming catalysts: effects of temperature and steam and hydrogen pressures． J Catal，2004，223( 2) : 432 ［7］ Perna A． Hydrogen from ethanol: theoretical optimization of a PEMFC system integrated with a steam reforming processor． Int J Hydrogen Energy，2007，32( 12) : 1811 ［8］ Alvarez-Galvan M C，Navarro R M，Rosa F，et al． Performance of La，Ce-modified alumina-supported Pt and Ni catalysts for the oxi￾dative reforming of diesel hydrocarbons． Int J Hydrogen Energy， 2008，33( 2) : 652 ［9］ Parmar R D，Kundu A，Karan K． Thermodynamic analysis of diesel reforming process: mapping of carbon formation boundary and representative independent reactions． J Power Sources，2009， 194( 2) : 1007 ［10］ Sharma S，Deshpande P A，Hedge M S，et al Nondeactivating nanosized ionic catalysts for water-gas shift reaction． Ind Eng Chem Res，2009，48( 14) : 6535 ［11］ Choudhury M B I，Ahmed S，Shalabi M A，et al． Preferential methanation of CO in a syngas involving CO2 at lower temperature range． Appl Catal A，2006，314( 1) : 47 ［12］ Xu L H，Mi W L，Su Q Q． Hydrogen production through diesel steam reforming over rare-earth promoted Ni /γ-Al2O3 catalysts． J Nat Gas Chem，2011，20( 3) : 287 ［13］ Christensen T S． Adiabatic prereforming of hydrocarbons: an im￾portant step in syngas production． Appl Catal A，1996，138( 2) : 285 ［14］ Cromarty B J，Hooper C W． Increasing the throughput of an ex￾isting hydrogen plant． Int J Hydrogen Energy，1997，22( 1) : 17 ［15］ Armor J N． The multiple roles for catalysis in the production of H2 ． Appl Catal A，1999，176( 2) : 159 ［16］ Peters R，Riensche E，Cremer P． Pre-reforming of natural gas in solid oxide fuel-cell systems． J Power Sources，2000，86( 1 /2) : 432 ［17］ Laosiripojana N，Assabumrungrat S． Catalytic steam reforming of ethanol over high surface area CeO2 : the role of CeO2 as an inter￾nal pre-reforming catalyst． Appl Catal B，2006，16( 1 /2) : 29 ［18］ Chen F Z，Zha S W，Dong J，et al． Pre-reforming of propane for low-temperature SOFCs． Solid State Ionics，2004，166 ( 3 /4 ) : 269 ［19］ de Lima S M，da Silva A M，Jacobs G，et al． New approaches to improving catalyst stability over Pt /ceria during ethanol steam re￾forming: Sn addition and CO2 co-feeding． Appl Catal B，2010， 96( 3 /4) : 387 ［20］ Arena F，Trunfio G，Alongi E，et al． Modelling the activity-sta￾bility pattern of Ni /MgO catalysts in the pre-reforming of n-hex￾ane． Appl Catal A，2004，266( 2) : 155 ［21］ Gong J，Su Q Q，Mi W L，et al． Effect of inlet gas composition on working temperature of natural gas steam reforming． J Chem Ind Eng China，2008，59( 3) : 687 ( 龚娟，苏庆泉，米万良，等． 入口气体组成对天然气重整工 作温度的影响． 化工学报，2008，59( 3) : 687) ［22］ Mi W L，Sun D J，Gong J，et al． CO water-gas-shift reaction character over Cu-Zn catalyst． J Univ Sci Technol Beijing，2010， 32( 2) : 224 ( 米万良，孙丹杰，龚娟，等． Cu--Zn 催化剂的 CO 水汽变换反 应特性． 北京科技大学学报，2010，32( 2) : 224) ［23］ Li Z Y，Mi W L，Gong J，et al． CO removal by two-stage metha￾nation for polymer electrolyte fuel cell． J Nat Gas Chem，2008， 17( 4) : 359 ［24］ Hernndez L，Kafarov V． Thermodynamic evaluation of hydrogen production for fuel cells by using bio-ethanol steam reforming: effect of carrier gas addition． J Power Sources，2009，192( 1) : 195 ［25］ Batista M S，Santiago E I，Assaf E M，et al． Evaluation of the water-gas shift and CO methanation processes for purification of reformate gases and the coupling to a PEM fuel cell system． J Power Sources，2005，145( 1) : 50 ［26］ Laosiripojana N，Sutthisripok W，Charojrochkul S，et al． Steam reforming of LPG over Ni and Rh supported on Gd-CeO2 and Al2O3 : effect of support and feed composition． Fuel，2011，90 ( 1) : 136 ［27］ Xie C，Chen Y S，Li Y，et al． Influence of sulfur on the carbon deposition in steam reforming of liquid hydrocarbons over CeO2 - Al2O3 supported Ni and Rh catalysts． Appl Catal A，2011，394 ( 1 /2) : 32 ［28］ Zheng J，Strohm J J，Song C S． Steam reforming of liquid hydro￾carbon fuels for micro-fuel cells: pre-reforming of model jet fuels over supported metal catalysts． Fuel Process Technol，2008，89 ( 4) : 440 ［29］ Li Z Y，Mi W L，Su Q Q． Deep removal of CO in reformate． J Univ Sci Technol Beijing，2010，32( 1) : 100 ( 李志远，米万良，苏庆泉． 重整气中 CO 深度去除方法． 北 京科技大学学报，2010，32( 1) : 100) ·717·