界面结合力。但是过多的稀土元素,会减弱了界面结2001242174~179 合力并导致复合材料拉伸性能下降。程先华和薛玉 12 Tham ason J L Schoolenberg g E AnInvestigaton of 君研究了sGS(含10%氨基硅烷偶联剂SG glass fber/polypropy lene nter fice strengh& its effect on am2 posite properties Composite 25197~203 S00的酒精溶液)、RES(含稀土元素0B~Q8 13 Scholtens B JR Brackm an JC Paper presen ted at IC 的酒精溶液)和SS/RES(含10%。SG-S100和稀C. V oonfe ren Goteborg Wenden June1994 土元素的酒精溶液)三种表面改性剂处理玻璃纤维 14 Mader Jaoobasch H IGrundke K In fuence of an opt2 的最佳用量及其对玻璃纤维增强PTFE复合材料冲 mized nterphase on the propertes of polypropy bne/ghss fbre cam posites Com posites 199 27A 079 击磨损和拉伸性能的影响,结果发现RES比SGS/ 15 Tham asn JL The nterface regin n ghss fbre- re n2 RES和sGS能够更好地提高玻璃纤维与PIHE之间 roed epay resn com pos ites 1. Sam ple preparaton vod con2 的界面结合力和提高复合材料的摩擦磨损性能,且当 tent and nterfacial strengt Com posites 1995, 26 467-475 稀土元素在表面改性剂中的质量分数为03时复 omu latins on the m echanical prperties of unid irect inal re n2 合材料的拉伸性能最佳 Droed ghss fbre/polyester resn lam nates Mater Sci Lett 4展望 199514942~947 玻璃纤维增强树脂基复合材料的界面研究较为 17周晓东,郭文军,戴干策.接枝改性聚烯烃在玻璃纤 维浸润剂中的应用.玻璃钢厦合材料;2000110~13 成熟,玻璃纤维的改性方法也较多而且己经得到普遍 18张志谦,龙军,刘立洵等.玻璃纤维增强聚丙烯复合 的应用。目前,采用硅烷类偶联剂对玻璃纤维进行表材料界面改性研究.宇航材料工艺,20032(4):28-31 面处理,制得树脂基复合材料其处理效果较好,但是 19易长海,周奇龙,许家瑞等.硅烷偶联剂处理玻璃纤 其利用率低。因此提高硅烷偶联剂与玻璃纤维表面维表面的形态及活化机理荆州师范学院学报,20024(2) 93~96 的键接效率,将成为今后的研究重点。 0 lglesas jG Gonza lez Ben ito I A mara Jet al Effect of 参考文献 glass fber surface tream ents n mechan cal strengh of epoxy 李新中玻璃纤维增强HDE及其硅烷交联改性研 based amos ite m ater a ls Joumal of Collod and Interface S2 究.2006 ence2002250251~260 2刘雄亚,谢怀勤复合材料工艺及设备.武汉:武汉工 21 Tom ozawa Peng Y L Surface relaxat in as a mecha 业大学出版社,1997 nim of static fatgue ofpr stne sil ica glass fibers Joumal ofNon2 3 LiZ F Ruckenste n E Strong adhes ion and smoot con2 Crystall ne Solids 1998 104-109 uctive surface va graft polymer vat on of aniline on a mod 22 W anew. dbenedet b A T. A modified sine tream ent glass fber surface Joumal ofColbi and Inter face Science 2002 superior hydrolytic stab il ity of ghss re nforced campos ites Joumal of A, 1998 68(3-4): 183- 201 4 Gmzalez b I Base ba I Amar A J Microstructural 23陈育如铝锆偶联剂的应用.塑料工业,200129(6) wettab ility sudy of surface pretreated ghss fbres Joumal ofM 44~46 rials Processng Technobgy 1999, 92-93 129- 134 24 Rohchoon Park Jyongsk Jang a sudy of the mpact 5柳华实,葛曷一,王冬至等玻璃纤维表面处理对玻璃 propertes of campos ites cons stng of surfaceamod ified glass fbers 纤维石膏复合材料力学性能的影响.山东建材,200425(5): n viyl ester resn Campos ires Scence and Technobgy1998 34~36 58979~985 6孙文强,曾辉,牛兰刚等.耐高温复合材料用玻璃纤维 25 Lee Gw, leen I j ang j etal Effects of surface m od2 表面处理研究(1)酸碱刻蚀处理的研究.玻璃钢厦合材料 ficat Dn on the resn2 transfer moulding (rIM)of ghss fbre/ur2 2000(1):33~35 saturated molester camposites Camposites Science and Technolo 7 Tom ao V, souffiA M DenoyeR Infuence of tme and tem pera ure of hydrothemal treament on ghss fibe rs surface g 2002 629-16 26 Laura D M, Keskku b H, Barlow Jw et al E fect of glass Jaurnal of Chroma g raphy A 199&- 376 fiber surface cham st ry n the m echan ical propertes of ghss fber 8 PleddeInam ann E P Silne Coupling A gepts Plenum re nbrced rubber2toughened nylon 6 Polm er 2002 4: 4 673-4 687 27 Cech V, PrikryIR Bakova R et al Plasma su 9 Ish da h. a rev iew of recent progress n the stud ies of treament and mod ifcatin of ghss fibers Camposites Part A molecular and m icostrucu re of coupling agents and he ir func 2002331367~1372 tons n campos ites coatings and athens Ne pnts Polmer Con2 李志军,程光旭,韦玮.离子体处理在玻璃纤维增强 pos ites B84 5 101 聚丙烯复合材料中的应用中国塑料,200014(6):45~49 10 Lee G W, Lee n I Jang v J et al E fects of sur fice φ程先华,薛玉君,谢超英稀土元素表面处理对玻璃 m od ifca tion on the res transfer mou ding of glass fber//msM2纤维填充金属塑料多层复合材料冲击磨损性能的影响中 a ted2polyester amos ites Cam pos ites Science and Tec 3国稀土学报,200119(4)373~375 2002629~16 30薛玉君,程先华稀土元素表面处理玻璃纤维增强PTFE 1 Park Soo n Jn Joong Seong E fect of silane coup Ing复合材料的拉伸性能中国稀土学报20220(1):4-44 agent on nte phase and perfom ance of glass fbers/unsaturated (编辑吴坚) polester campos ites Joumal of Colbd and Interface Science 宇航材料工艺2009年第1期 )7)界面结合力。但是过多的稀土元素, 会减弱了界面结 合力并导致复合材料拉伸性能下降。程先华和薛玉 君 [ 29~ 30 ]研究了 SGS(含 1. 0%氨基硅烷偶联剂 SG￾Si900的酒精溶液 )、RES(含稀土元素 0. 1% ~ 0. 8% 的酒精溶液 )和 SGS/RES(含 1. 0% SG- Si900 和稀 土元素的酒精溶液 )三种表面改性剂处理玻璃纤维 的最佳用量及其对玻璃纤维增强 PTFE复合材料冲 击磨损和拉伸性能的影响, 结果发现 RES比 SGS/ RES和 SGS能够更好地提高玻璃纤维与 PTFE 之间 的界面结合力和提高复合材料的摩擦磨损性能, 且当 稀土元素在表面改性剂中的质量分数为 0. 3% 时复 合材料的拉伸性能最佳。 4 展望 玻璃纤维增强树脂基复合材料的界面研究较为 成熟, 玻璃纤维的改性方法也较多而且已经得到普遍 的应用。目前, 采用硅烷类偶联剂对玻璃纤维进行表 面处理, 制得树脂基复合材料其处理效果较好, 但是 其利用率低。因此, 提高硅烷偶联剂与玻璃纤维表面 的键接效率, 将成为今后的研究重点。 参考文献 1 李新中. 玻璃纤维增强 HDPE 及其硅烷交联改性研 究. 2006 2 刘雄亚, 谢怀勤. 复合材料工艺及设备. 武汉: 武汉工 业大学出版社, 1997 3 L i Z F, Ruckenste in E. 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