·820· 工程科学学报，第39卷，第6期 alumina-modified silica aerogels.J Non-Cryst Solids,1995, 热复合材料的力学性能.硅酸盐学报，2009,37(1)：1) 186:113 B2] Yang H L,Ni W,LiangT,et al.Preparation and characteriza- [18]Li X W,Duan YY,Wang X D.Impacts of structural changes of tion of nanoporous super insulation materials reinforced with alu- SiO,aerogel under high temperature on its insulation perform- minum silicate fiber.J Mater Eng,2007 (7):63 ance.J Therm Sci Technol,2011,10(3):189 (杨海龙，倪文，梁涛，等。硅酸铝纤维增强纳米孔绝热材料 (李雄威，段远源，王晓东.SO2气凝胶高温结构变化及其 的制备与表征.材料工程，2007(7)：63) 对隔热性能的影响.热科学与技术，2011,10(3)：189) B3]Guo YC,Ma Y W,Shi DQ,et al.Mechanical property tests of 09] Komameni S,Roy R,Selvaraj U,et al.Nanocomposite aero- mullite fiber-reinforced Si aerogel composites. Acta Mater gels:the Si02-Al2O3 system.J Mater Res,1993,8(12):3163 Compositae Sinica,2016,33(6):1297 20]Aravind P R,Mukundan P,Pillai P K,et al.Mesoporous silica- (郭玉超，马寅魏，石多奇，等.莫来石纤维增强S0,气凝 alumina aerogels with high thermal pore stability through hybrid 胶复合材料的力学性能试验.复合材料学报，2016,33(6)： sol-gel route followed by suberitical drying.Microporous Meso- 1297) porous Mater,2006,96(13):14 34]He J,Li X L,Su D,et al.High-strength mullite fibers rein- 21]Levin 1,Brandon D.Metastable alumina polymorphs:crystal forced Zr02-Si0,aerogels fabricated by rapid gel method.J Ma- structures and transition sequences.J Am Ceram Soc,1998,81 ter Sci,2015,50(22):7488 (8):1995 B5]Yang J M,Wu H J,Zhong Z K,et al.Calculation and optimiza- [22]Zu G Q,Shen J,Wei X Q,et al.Preparation and characteriza- tion of thermal conductivity of fused silica fiber/aerogel compos- tion of monolithic alumina aerogels.Non-Cryst Solids,2011, ites.Mater Rev,2016,30(5):139 357(15):2903 (杨建明，吴会军，钟支葵，等.石英玻璃纤维/气凝胶复合 [23]Keysar S,Shter G E,Hazan Y D,et al.Heat treatment of alu- 材料的热导率计算及优化.材料导报，2016,30(5)：139) mina acrogels.Chem Mater,1997,9(11):2464 B6] Sheng C,Yu Y,Yu Y,et al.Microstructure and thermal char- 24]Mizushima Y,Hori M.Preparation of heat-resistant alumina aer- acterization of multilayer insulation materials based on silica aero- ogels.J Mater Res,1993,8(11):2993 gels.J Inarg Mater,2013,28(7):790 25]Li Z P.Preparation of Al0-Si0,-Zr0,Composite by Sol-Gel B7]Yang H L.Ni W,Chen D P,et al.Effect of preparation condi- Method [Dissertation].Beijing:Beijing University of Chemical tion on the thermal conductivity of xonotlitesilica aerogel nanopo- Technology,2014 rous super insulation materials.I Uni Sci Technol Beijing, (李智鹏.氧化铝一氧化硅一氧化铅三元复合气凝胶的制备和 2008,30(1):57 表征[学位论文].北京：北京化工大学，2014) (杨海龙，倪文，陈德平，等.制备条件对硅酸钙复合纳米孔 26]Wang Q P.Li X L,Fen W P,et al.Synthesis of crack-free 超级绝热材料热导率的影响.北京科技大学学报，2008,30 monolithic Zr2,aerogel modified by Si.J Porous Mater, (1):57) 2014,21(2):127 B8] Wei G S,Zhang XX,Yu F.Effective thermal conductivity anal- 27]Zou W B.Shen J,Zu GQ,et al.Preparation and characteriza- ysis of xonotlite-erogel composite insulation material.I Therm tion of heat-resistant zirconia/silica composite aerogel.Nanjing Sci,2009,18(2):142 Tech Univ Nat Sci Ed,2016,38(2):42 B9]Parmenter K E,Milstein F.Mechanical properties of silica aero- (邹文兵，沈军，祖国庆，等.耐高温Z02/SiO2复合气凝胶 gels.JNon-Cryst Solids,1998.223(3):179 的制备及表征.南京工业大学学报（自科版），2016,38(2)： [40]Liao Y D,Wu H J,Ding Y F,et al.Engineering thermal and 42) mechanical properties of flexible fiber-reinforced aerogel compos- 28]Zhu J Y,Chen H,Liu R X,et al.Preparation and thermal sta- ites.J Sol-Gel Sci Technol,2012,63(3):445 bility of Zr-Si0 composite aerogels.Ade Ceram,2016,37 [41]Nelson R T.Effects of Pressure,Temperature and Gel Thickness (1):47 on the Kinetics of Supereritical CO Drying of Silica Aleogel [Dis- (朱俊阳，陈恒，刘瑞样，等.Z02SiO2复合气凝胶的制备 sertation].Massachusetts:Tufts University,2014 及其热稳定性研究.现代技术陶瓷，2016,37(1)：47) [42]Yorov K E,Sipyagina NA,Baranchikov A E,et al.Si0,-TiO 9]Lian Y,Shen J,Zu CQ,et al.Preparation and characterization binary aerogels:synthesis in new supercritical fluids and study of of Zr-AlO composite aerogels.J Chin Ceram Soc,2015,43 thermal stability.Russian J /norg Chem,2016,61 (11):1339 (11):1656 [43]Widipedia.Critical Point (thermaodynamics),[2017-02-24]. (连娅，沈军，祖国庆，等.Z02一A山203复合气凝胶的制备 https://en.wikipedia.org/wiki/Critical point% 与表征.硅酸盐学报，2015,43(11)：1656) 28thermodynamics%29 0]White S,Rasky D.Herlth P.Tough,lightweight,superinsulat- 44]Rao A V,Pajonk G M,Bhagat S D,et al.Comparative studies ing aerogel/tile composites have potential industrial applications. on the surface chemical modification of silica aerogels based on Mater Technol,1999,14(1):13 various organosilane compounds of the type R.SiX.J Non- B31]Gao Q F,Feng J.Zhang C R,et al.Mechanical properties of Cryst Solids,2004,350:216 ceramic fiber-reinforced silica aerogel insulation composites.J [45]Land V D,Harris T M,Teeters D C.Processing of low-density Chin Ceram Soc,2009,37(1):1 silica gel by critical point drying or ambient pressure drying.J (高庆福，冯坚，张长瑞，等.陶瓷纤维增强氧化硅气凝胶隔 Non-Cryst Solids,2001,283(13)11工程科学学报，第 39 卷，第 6 期 alumina-modified silica aerogels． J Non-Cryst Solids，1995， 186: 113 ［18］ Li X W，Duan Y Y，Wang X D． Impacts of structural changes of SiO2 aerogel under high temperature on its insulation perform￾ance． J Therm Sci Technol，2011，10( 3) : 189 ( 李雄威，段远源，王晓东． SiO2 气凝胶高温结构变化及其 对隔热性能的影响． 热科学与技术，2011，10( 3) : 189) ［19］ Komarneni S，Ｒoy Ｒ，Selvaraj U，et al． Nanocomposite aero￾gels: the SiO2--Al2O3 system． J Mater Ｒes，1993，8( 12) : 3163 ［20］ Aravind P Ｒ，Mukundan P，Pillai P K，et al． Mesoporous silica￾alumina aerogels with high thermal pore stability through hybrid sol--gel route followed by subcritical drying． Microporous Meso￾porous Mater，2006，96( 1-3) : 14 ［21］ Levin I，Brandon D． Metastable alumina polymorphs: crystal structures and transition sequences． J Am Ceram Soc，1998，81 ( 8) : 1995 ［22］ Zu G Q，Shen J，Wei X Q，et al． Preparation and characteriza￾tion of monolithic alumina aerogels． J Non-Cryst Solids，2011， 357( 15) : 2903 ［23］ Keysar S，Shter G E，Hazan Y D，et al． Heat treatment of alu￾mina aerogels． Chem Mater，1997，9( 11) : 2464 ［24］ Mizushima Y，Hori M． Preparation of heat-resistant alumina aer￾ogels． J Mater Ｒes，1993，8( 11) : 2993 ［25］ Li Z P． Preparation of Al2O3 --SiO2--ZrO2 Composite by Sol-Gel Method ［Dissertation］． Beijing: Beijing University of Chemical Technology，2014 ( 李智鹏． 氧化铝--氧化硅--氧化锆三元复合气凝胶的制备和 表征［学位论文］． 北京: 北京化工大学，2014) ［26］ Wang Q P，Li X L，Fen W P，et al． Synthesis of crack-free monolithic ZrO2，aerogel modified by SiO2 ． J Porous Mater， 2014，21( 2) : 127 ［27］ Zou W B，Shen J，Zu G Q，et al． Preparation and characteriza￾tion of heat-resistant zirconia / silica composite aerogel． J Nanjing Tech Univ Nat Sci Ed，2016，38( 2) : 42 ( 邹文兵，沈军，祖国庆，等． 耐高温 ZrO2 / SiO2 复合气凝胶 的制备及表征． 南京工业大学学报( 自科版) ，2016，38( 2) : 42) ［28］ Zhu J Y，Chen H，Liu Ｒ X，et al． Preparation and thermal sta￾bility of ZrO2--SiO2 composite aerogels． Adv Ceram，2016，37 ( 1) : 47 ( 朱俊阳，陈恒，刘瑞祥，等． ZrO2--SiO2 复合气凝胶的制备 及其热稳定性研究． 现代技术陶瓷，2016，37( 1) : 47) ［29］ Lian Y，Shen J，Zu G Q，et al． Preparation and characterization of ZrO2--Al2O3 composite aerogels． J Chin Ceram Soc，2015，43 ( 11) : 1656 ( 连娅，沈军，祖国庆，等． ZrO2--Al2O3 复合气凝胶的制备 与表征． 硅酸盐学报，2015，43( 11) : 1656) ［30］ White S，Ｒasky D，Herlth P． Tough，lightweight，superinsulat￾ing aerogel /tile composites have potential industrial applications． Mater Technol，1999，14( 1) : 13 ［31］ Gao Q F，Feng J，Zhang C Ｒ，et al． Mechanical properties of ceramic fiber-reinforced silica aerogel insulation composites． J Chin Ceram Soc，2009，37( 1) : 1 ( 高庆福，冯坚，张长瑞，等． 陶瓷纤维增强氧化硅气凝胶隔 热复合材料的力学性能． 硅酸盐学报，2009，37( 1) : 1) ［32］ Yang H L，Ni W，Liang T，et al． Preparation and characteriza￾tion of nanoporous super insulation materials reinforced with alu￾minum silicate fiber． J Mater Eng，2007( 7) : 63 ( 杨海龙，倪文，梁涛，等． 硅酸铝纤维增强纳米孔绝热材料 的制备与表征． 材料工程，2007( 7) : 63) ［33］ Guo Y C，Ma Y W，Shi D Q，et al． Mechanical property tests of mullite fiber-reinforced SiO2 aerogel composites． Acta Mater Compositae Sinica，2016，33( 6) : 1297 ( 郭玉超，马寅魏，石多奇，等． 莫来石纤维增强 SiO2 气凝 胶复合材料的力学性能试验． 复合材料学报，2016，33( 6) : 1297) ［34］ He J，Li X L，Su D，et al． High-strength mullite fibers rein￾forced ZrO2--SiO2 aerogels fabricated by rapid gel method． J Ma￾ter Sci，2015，50( 22) : 7488 ［35］ Yang J M，Wu H J，Zhong Z K，et al． Calculation and optimiza￾tion of thermal conductivity of fused silica fiber /aerogel compos￾ites． Mater Ｒev，2016，30( 5) : 139 ( 杨建明，吴会军，钟支葵，等． 石英玻璃纤维/气凝胶复合 材料的热导率计算及优化． 材料导报，2016，30( 5) : 139) ［36］ Sheng C，Yu Y，Yu Y，et al． Microstructure and thermal char￾acterization of multilayer insulation materials based on silica aero￾gels． J Inorg Mater，2013，28( 7) : 790 ［37］ Yang H L，Ni W，Chen D P，et al． Effect of preparation condi￾tion on the thermal conductivity of xonotlite-silica aerogel nanopo￾rous super insulation materials． J Univ Sci Technol Beijing， 2008，30( 1) : 57 ( 杨海龙，倪文，陈德平，等． 制备条件对硅酸钙复合纳米孔 超级绝热材料热导率的影响． 北京科技大学学报，2008，30 ( 1) : 57) ［38］ Wei G S，Zhang X X，Yu F． Effective thermal conductivity anal￾ysis of xonotlite-aerogel composite insulation material． J Therm Sci，2009，18( 2) : 142 ［39］ Parmenter K E，Milstein F． Mechanical properties of silica aero￾gels． J Non-Cryst Solids，1998，223( 3) : 179 ［40］ Liao Y D，Wu H J，Ding Y F，et al． Engineering thermal and mechanical properties of flexible fiber-reinforced aerogel compos￾ites． J Sol-Gel Sci Technol，2012，63( 3) : 445 ［41］ Nelson Ｒ T． Effects of Pressure，Temperature and Gel Thickness on the Kinetics of Supercritical CO2 Drying of Silica Alcogel［Dis￾sertation］． Massachusetts: Tufts University，2014 ［42］ Yorov K E，Sipyagina N A，Baranchikov A E，et al． SiO2--TiO2 binary aerogels: synthesis in new supercritical fluids and study of thermal stability． Ｒussian J Inorg Chem，2016，61( 11) : 1339 ［43］ Widipedia． Critical Point ( thermaodynamics) ，［2017--02--24］． https: / /en． wikipedia． org /wiki /Critical _ point _% 28thermodynamics% 29 ［44］ Ｒao A V，Pajonk G M，Bhagat S D，et al． Comparative studies on the surface chemical modification of silica aerogels based on various organosilane compounds of the type Ｒn SiX4 － n ． J Non￾Cryst Solids，2004，350: 216 ［45］ Land V D，Harris T M，Teeters D C． Processing of low-density silica gel by critical point drying or ambient pressure drying． J Non-Cryst Solids，2001，283( 1-3) : 11 · 028 ·