xiv DETAILED CONTENTS 17.5 Alkylation of Enolate lons 17.6 Carbonyl Condensations:The Aldol Reaction 620 17-7 Dehydration of Aldol Products 623 17-8 Intramolecular Aldol Reactions 17-9 The Claisen Condensation Reaction 62 17-10 Intramolecular Claisen Condensations:The Dieckmann Cyclization 9 17.11 Conjugate Carbonyl Additions:The Michael Reaction 17-12 Carbonyl Condensations with Enamines:The Stork Reactior 634 17-13 Biological Carbonyl Condensation Reactions 637 SOMETHING EXTRA Barbiturates 63g 8 Amines and Heterocycles 644 18-1 Naming Amines 18-2 Properties of Amines 18-3 Basicity of Amines 649 18-4 Basicity of Arylamines 18-5 Biological Amines and the Henderson-Hasselbalch Equation 18-6 Synthesis of Amines 6 18-7 Reactions of Amines 18-8 Heterocyclic Amines 65 18-9 Fused-Ring Heterocycles 18-10 Spectroscopy of Amines SOMETHING EXTRA Green Chemistry 614 19 Biomolecules:Amino Acids. Peptides,and Proteins 678 19-1 Structures of Amino Acids 679 19-2 Amino Acids and the Henderson-Hasselbalch Equation: Isoelectric Points 6 193 Synthesis of Amino Acids 6 19.4 Peptides and Proteins 195 Amino Acid Analysis of Peptides 691 19-6 Peptide Sequencing:The Edman Degradation 693 19-7 Peptide Synthesis 696 xiv DetaileD Contents 17-5 alkylation of Enolate ions 610 17-6 carbonyl condensations: the aldol Reaction 620 17-7 Dehydration of aldol products 623 17-8 intramolecular aldol Reactions 626 17-9 the claisen condensation Reaction 627 17-10 intramolecular claisen condensations: the Dieckmann cyclization 629 17-11 conjugate carbonyl additions: the Michael Reaction 632 17-12 carbonyl condensations with Enamines: the stork Reaction 634 17-13 Biological carbonyl condensation Reactions 637 soMetHinG eXtra Barbiturates 639 18 amines and Heterocycles | 644 18-1 naming amines 645 18-2 properties of amines 647 18-3 Basicity of amines 649 18-4 Basicity of arylamines 652 18-5 Biological amines and the henderson–hasselbalch Equation 653 18-6 synthesis of amines 654 18-7 Reactions of amines 659 18-8 heterocyclic amines 665 18-9 Fused-Ring heterocycles 669 18-10 spectroscopy of amines 672 soMetHinG eXtra green chemistry 674 19 Biomolecules: amino acids, Peptides, and Proteins | 678 19-1 structures of amino acids 679 19-2 amino acids and the henderson–hasselbalch Equation: isoelectric points 684 19-3 synthesis of amino acids 687 19-4 peptides and proteins 689 19-5 amino acid analysis of peptides 691 19-6 peptide sequencing: the Edman Degradation 693 19-7 peptide synthesis 696 42912_00_FM_i-xxiv.indd 14 1/16/14 3:00 PM Copyright 2015 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s). Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it