5.7 Enthalpy Changes in Chlorination 5.8 Kinetics and the Rate Equation 5.9 Activation Energy and the Temperature Dependence of Rates 5.10 Transition States 5.11 Rates of Multistep Reactions 5.12 Temperature Dependence of Halogenation 5.13 Selectivity in Halogenation 5.14 The Hammond Postulate 5.15 Radical Inhibitors 5.16 Reactive Intermediates 教学要求： 掌握以下教学内容：Reactions:Addition,.Elimination,Substitution,Rearrangement;Mechanisms Radical,Polar,Nucleophile and electrophile,Transition states and intermediates (六)Chapter6 Stereochemistry4学时 主要内容： 6.1 Introduction 6.2 Chirality 6.3(R)and(S)Nomenclature of Asymmetric Carbon Atoms 6.4 Optical Activity 6.5 Biological Discrimination of Enantiomers 6.6 Racemic Mixtures 6.7 Enantiomeric Excess and Optical Purity 6.8 Chirality of Conformationally Mobile Systems 6.9 Chiral Compounds without Asymmetric Atoms 6.10 Fischer Projections 6.11 Diastereomers 6.12 Stereochemistry of Molecules with Two or More Asymmetric Carbons 6.13 Meso Compounds 6.14Absolute and Relative Configuration 6.15 Physical Properties of Diastereomers 6.16 Resolution of Enantiomers 教学要求： 掌握以下教学内容：Stereochemistry,Chiral enantiomers,Chirality center,,Optical activity,.Optical rotations,Racemic mixture configuration,R and S of the Cahn-Ingold-Prelog notational system,5.7 Enthalpy Changes in Chlorination 5.8 Kinetics and the Rate Equation 5.9 Activation Energy and the Temperature Dependence of Rates 5.10 Transition States 5.11 Rates of Multistep Reactions 5.12 Temperature Dependence of Halogenation 5.13 Selectivity in Halogenation 5.14 The Hammond Postulate 5.15 Radical Inhibitors 5.16 Reactive Intermediates 教学要求： 掌握以下教学内容：Reactions: Addition, Elimination, Substitution, Rearrangement; Mechanisms: Radical,Polar, Nucleophile and electrophile, Transition states and intermediates （六）Chapter 6 Stereochemistry 4 学时 主要内容： 6.1 Introduction 6.2 Chirality 6.3 (R) and (S) Nomenclature of Asymmetric Carbon Atoms 6.4 Optical Activity 6.5 Biological Discrimination of Enantiomers 6.6 Racemic Mixtures 6.7 Enantiomeric Excess and Optical Purity 6.8 Chirality of Conformationally Mobile Systems 6.9 Chiral Compounds without Asymmetric Atoms 6.10 Fischer Projections 6.11 Diastereomers 6.12 Stereochemistry of Molecules with Two or More Asymmetric Carbons 6.13 Meso Compounds 6.14 Absolute and Relative Configuration 6.15 Physical Properties of Diastereomers 6.16 Resolution of Enantiomers 教学要求： 掌握以下教学内容：Stereochemistry, Chiral enantiomers, Chirality center, Optical activity, Optical rotations, Racemic mixture configuration, R and S of the Cahn–Ingold–Prelog notational system