Fischer projection,Diastereomers meso forms,Prochiral and prochirality,Resolution of enantiomers ()Chapter 7 Alkyl Halides:Nucleophilic Substitution and Elimination 4 主要内容: 7.1 Introduction 7.2 Nomenclature of Alkyl Halides 7.3 Common Uses of Alkyl Halides 7.4 Structure of Alkyl Halides 7.5 Physical Properties of Alkyl Halides 7.6 Preparation of Alkyl Halides 7.7 Reactions of Alkyl Halides:Substitution and Elimination 7.8 Second-Order Nucleophilic Substitution:The SN2 Reaction 7.9 Generality of the SN2 Reaction 7.10 Factors Affecting SN2 Reactions:Strength of the Nucleophile 7.11 Reactivity of the Substrate in SN2 Reactions 7.12 Stereochemistry of the SN2 Reaction 7.13 First-Order Nucleophilic Substitution:The SN1 Reaction 7.14 Stereochemistry of the SNI Reaction 7.15 Rearrangements in SN1 Reactions 7.16 Comparison of SN1 and SN2 Reactions 7.17 First-Order Elimination:The E1 Reaction 7.18 Positional Orientation of Elimination:Zaitsev's Rule 7.19 Second-Order Elimination:The E2 Reaction 7.20 Stereochemistry of the E2 Reaction 7.21 Comparison of El and E2 Elimination Mechanisms 教学要求: 掌握以下教学内容:SN1 reactions governed by electronic factors,.the relative stabilities of carbocation intermediates,SN2 reactions governed by steric factors,the relative ease of approach of the nucleophile to the site of reaction,E2 mechanism,E1 mechanism,carbocation rearrangements (八)Chapter8 Structure and synthesis of Alkenes2学时 主要内容: 8.1 Introduction 8.2 The Orbital Description of the Alkene Double Bond Fischer projection, Diastereomers meso forms, Prochiral and prochirality, Resolution of enantiomers (七)Chapter 7 Alkyl Halides: Nucleophilic Substitution and Elimination 4 学时 主要内容: 7.1 Introduction 7.2 Nomenclature of Alkyl Halides 7.3 Common Uses of Alkyl Halides 7.4 Structure of Alkyl Halides 7.5 Physical Properties of Alkyl Halides 7.6 Preparation of Alkyl Halides 7.7 Reactions of Alkyl Halides: Substitution and Elimination 7.8 Second-Order Nucleophilic Substitution: The SN2 Reaction 7.9 Generality of the SN2 Reaction 7.10 Factors Affecting SN2 Reactions: Strength of the Nucleophile 7.11 Reactivity of the Substrate in SN2 Reactions 7.12 Stereochemistry of the SN2 Reaction 7.13 First-Order Nucleophilic Substitution: The SN1 Reaction 7.14 Stereochemistry of the SNl Reaction 7.15 Rearrangements in SN1 Reactions 7.16 Comparison of SN1 and SN2 Reactions 7.17 First-Order Elimination: The E1 Reaction 7.18 Positional Orientation of Elimination: Zaitsev’s Rule 7.19 Second-Order Elimination: The E2 Reaction 7.20 Stereochemistry of the E2 Reaction 7.21 Comparison of El and E2 Elimination Mechanisms 教学要求: 掌握以下教学内容:SN1 reactions governed by electronic factors, the relative stabilities of carbocation intermediates, SN2 reactions governed by steric factors, the relative ease of approach of the nucleophile to the site of reaction, E2 mechanism, E1 mechanism, carbocation rearrangements (八)Chapter 8 Structure and synthesis of Alkenes 2 学时 主要内容: 8.1 Introduction 8.2 The Orbital Description of the Alkene Double Bond