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Equilibrium Amounts For aldehydes and ketones,the keto form is greatly favored at equilibrium. An enantiomer with an enolizable hydrogen can form a racemic mixture. enolizable hydrogens CH3 CH3 H+orOH H a carbons (R)configuration enol (achiral) (S)configuration Chapter 22 7=>Chapter 22 7 Equilibrium Amounts • For aldehydes and ketones, the keto form is greatly favored at equilibrium. • An enantiomer with an enolizable hydrogen can form a racemic mixture. =>
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