刘召波等：钙硅氧化物的质量比对10%A120,高炉渣一尾矿一粉煤灰微品玻璃性能的影响 ·763· (3)从动力学析晶活化能E,和Avrami系数变化 [10]Erol M,Kiicukbayrak S,Ersoy-Mericboyu A.The application of 角度解释了“随着钙硅氧化物质量比增大，S一0四面 differential thermal analysis to the study of isothermal and non- 体连接强度下降，质点移动加强，各组开始析晶温度 isothermal crystallization kinetics of coal fly ash based glasses.I Non Cryst Solids,2009,355(9):569 T和晶化温度T逐渐减小”原因：析晶方式由整体析 [11]Kim J M,Kim H S.Processing and properties of a glass-ceramic 晶向表面析晶转变，但以表面析晶为主的析晶规律 from coal fly ash from a thermal power plant through an economic (4)随着钙硅氧化物质量比增大，主晶相由透辉 process.J Eur Ceram Soc,2004,24(9):2825 石向普通辉石再向镁黄长石转变，并且当样品中含一 [12]Leroy C,Ferro M,Monteiro R,et al.Production of glass- 定量的铁辉石晶相时，玻璃样品的力学性能通常较好 ceramics from coal ashes.J Eur Ceram Soc,2001,21(2):195 当提高热处理析晶温度时，玻璃样品主晶相将发生转 [13]Yoon S D,Lee J U,Lee J H,et al.Characterization of wollas- tonite glass-ceramics made from waste glass and coal fly ash.J 变，但晶相种类基本不变：适当提高析晶温度有利于微 Mater Sci Technol,2013,29 (2):149 晶玻璃样品力学性能的提高：析晶温度过高时则易引 [14]Zhao T,Li B W,Gao Z Y,et al.The utilization of rare earth 起“过烧”现象 tailing for the production of glass-ceramics.Mater Sci Eng B, 2010,170(1-3):22 参。考文献 [15]Shao H,Liang K,Peng F,et al.Production and properties of Wang YL,Ni W,Li K Q,et al.Preparation of glass-ceramics by cordierite-based glass-ceramics from gold tailings.Miner Eng, the slag of iron melt-reduction from unwieldy hematite.J Unie Sci 2005,18(6):635 Technol Beijing,2008,29(2):1032 016]Das S K,Kumar S,Ramachandrarao P.Exploitation of iron ore (王亚利，倪文，李克庆，等.难选赤铁矿熔融还原炼铁及熔 tailing for the development of ceramie tiles.Waste Manage, 渣制备微晶玻璃.北京科技大学学报，2008,29(2)：1032) 2000,20(8):725 Li F,Liu X D.Effects of Ti0,on the microstructure transforma- [17]Cheng J S,Li H,Tang L Y,et al.Glass-ceramics.Beijing: tion of glass ceramics prepared by fly ash and quarts sand.JUnir Chemical Industry Press,2006 Sci Technol Beijing,2012,34(8):921 (程金树，李宏，汤李缨，等.微品玻璃.北京：化学工业出版 (李蜂，刘向东.T0,对粉煤灰及石英砂制备微品玻璃组织转 社，2006) 变的影响.北京科技大学学报，2012,34(8)：921) 08] Bemardo E,Andreola F,Barbieri L,et al.Sintered glass-ce- Fan Y,Li Y,Cang DQ,et al.Synergistie preparation of glass ramics and glass-ceramic matrix composites from CRT panel ceramics from sewage sludge incineration ash and blast furmnace glass.J Am Ceram Soc,2005,88 (7)1886 slag.J Univ Sci Technol Beijing,2013,35(7):901 9] Kim E S,Yeo W J.Thermal properties of CaMgSi2 glass- (樊涌，李宇，苍大强，等.污泥和高炉渣协同制备微晶玻璃 ceramics with Al203.Ceram Int,2012,38 (Suppl 1):S547 北京科技大学学报，2013,35(7)：901) 20]Ercenk E.Sen U.Yilmaz S.The effect of SiC addition on the [4]Das K,Raha S,Chakraborty D,et al.Effect of nucleating agents crystallization kinetics of atmospheric plasma-sprayed basalt- on the crystallization and microstructural characteristics of blast based coatings.Ceram Int,2012,38(8):6549 furnace slag derived glass-ceramics.Trans Indian Ceram Soc, 21]Ewais E M,Grathwohl G,Ahmed Y M.Crystallization of mixer 2012,71(3):137 slag-derived glass-ceramic composites.J Am Ceram Soc,2010, 5]Francis AA.Conversion of blast furace slag into new glass-ce- 93(3):671 ramic material.J Eur Ceram Soc,2004,24(9):2819 22]Karamanov A,Pelino M.Crystallization phenomena in iron-ich [6]Liu H Y,Lu HX,Chen DL,et al.Preparation and properties of glasses.J Non Cryst Solids,2001,281(1)139 glass-ceramics derived from blast-furnace slag by a ceramic- 23]Augis J,Bennett J.Calculation of the Avrami parameters for het- sintering process.Ceram Int,2009,35(8):3181 erogeneous solid state reactions using a modification of the Kissin- ]Pacurariu C.Laziu I.Non-isothermal crystallization kineties of ger method.J Therm Anal Calorim,1978,13(2):283 some glass-ceramics with pyroxene structure.J Non Cryst Solids, 241 Karamanov A,Avramov I,Arrizza L,et al.Variation of Avrami 2012,358(23):3332 parameter during non-isothermal surface crystallization of glass [8]Wang Z J,Ni W,Jia Y,et al.Crystallization behavior of glass powders with different sizes.J Non Cryst Solids,2012,358 ceramics prepared from the mixture of nickel slag,blast furnace (12):1486 slag and quartz sand.J Non Cryst Solids,2010,356(31-32): 5]Clupper D.Hench L Crystallization kinetics of tape cast bioac- 1554 tive glass 45S5.J Non Cryst Solids,2003,318(1)43 9]Erol M,Kucukbayrak S,Ersoy-Mericboyu A.Comparison of the 6]Wang S H,Zhou H P,Luo L H.Sintering and crystallization of properties of glass,glass-ceramic and ceramic materials produced cordierite glass ceramics for high frequency multilayer chip induc- from coal fly ash.J Hazard Mater,2008,153(1-2)418 tors.Mater Res Bull,2003,38(8):1367刘召波等: 钙硅氧化物的质量比对 10% Al2O3高炉渣--尾矿--粉煤灰微晶玻璃性能的影响 (3) 从动力学析晶活化能 Ea和 Avrami 系数变化 角度解释了“随着钙硅氧化物质量比增大，Si—O 四面 体连接强度下降，质点移动加强，各组开始析晶温度 Tc和晶化温度 Tp逐渐减小”原因;析晶方式由整体析 晶向表面析晶转变，但以表面析晶为主的析晶规律． (4) 随着钙硅氧化物质量比增大，主晶相由透辉 石向普通辉石再向镁黄长石转变，并且当样品中含一 定量的铁辉石晶相时，玻璃样品的力学性能通常较好． 当提高热处理析晶温度时，玻璃样品主晶相将发生转 变，但晶相种类基本不变;适当提高析晶温度有利于微 晶玻璃样品力学性能的提高;析晶温度过高时则易引 起“过烧”现象． 参 考 文 献 ［1］ Wang Y L，Ni W，Li K Q，et al． Preparation of glass-ceramics by the slag of iron melt-reduction from unwieldy hematite． J Univ Sci Technol Beijing，2008，29(2): 1032 (王亚利，倪文，李克庆，等． 难选赤铁矿熔融还原炼铁及熔 渣制备微晶玻璃． 北京科技大学学报，2008，29(2): 1032) ［2］ Li F，Liu X D． Effects of TiO2 on the microstructure transforma￾tion of glass ceramics prepared by fly ash and quarts sand． J Univ Sci Technol Beijing，2012，34(8): 921 (李峰，刘向东． TiO2对粉煤灰及石英砂制备微晶玻璃组织转 变的影响． 北京科技大学学报，2012，34(8): 921) ［3］ Fan Y，Li Y，Cang D Q，et al． Synergistic preparation of glass ceramics from sewage sludge incineration ash and blast furnace slag． J Univ Sci Technol Beijing，2013，35(7): 901 (樊涌，李宇，苍大强，等． 污泥和高炉渣协同制备微晶玻璃． 北京科技大学学报，2013，35(7): 901) ［4］ Das K，Raha S，Chakraborty D，et al． Effect of nucleating agents on the crystallization and microstructural characteristics of blast furnace slag derived glass-ceramics． Trans Indian Ceram Soc， 2012，71(3): 137 ［5］ Francis A A． Conversion of blast furnace slag into new glass-ce￾ramic material． J Eur Ceram Soc，2004，24(9): 2819 ［6］ Liu H Y，Lu HX，Chen DL，et al． Preparation and properties of glass-ceramics derived from blast-furnace slag by a ceramic￾sintering process． Ceram Int，2009，35(8): 3181 ［7］ Pcurariu C，Lazu I． Non-isothermal crystallization kinetics of some glass-ceramics with pyroxene structure． J Non Cryst Solids， 2012，358(23): 3332 ［8］ Wang Z J，Ni W，Jia Y，et al． Crystallization behavior of glass ceramics prepared from the mixture of nickel slag，blast furnace slag and quartz sand． J Non Cryst Solids，2010，356(31 － 32): 1554 ［9］ Erol M，Kucukbayrak S，Ersoy-Mericboyu A． Comparison of the properties of glass，glass-ceramic and ceramic materials produced from coal fly ash． J Hazard Mater，2008，153(1--2): 418 ［10］ Erol M，Küükbayrak S，Ersoy-Meriboyu A． The application of differential thermal analysis to the study of isothermal and non￾isothermal crystallization kinetics of coal fly ash based glasses． J Non Cryst Solids，2009，355(9): 569 ［11］ Kim J M，Kim H S． Processing and properties of a glass-ceramic from coal fly ash from a thermal power plant through an economic process． J Eur Ceram Soc，2004，24(9): 2825 ［12］ Leroy C，Ferro M，Monteiro R，et al． Production of glass￾ceramics from coal ashes． J Eur Ceram Soc，2001，21(2): 195 ［13］ Yoon S D，Lee J U，Lee J H，et al． Characterization of wollas￾tonite glass-ceramics made from waste glass and coal fly ash． J Mater Sci Technol，2013，29(2): 149 ［14］ Zhao T，Li B W，Gao Z Y，et al． The utilization of rare earth tailing for the production of glass-ceramics． Mater Sci Eng B， 2010，170(1 － 3): 22 ［15］ Shao H，Liang K，Peng F，et al． Production and properties of cordierite-based glass-ceramics from gold tailings． Miner Eng， 2005，18(6): 635 ［16］ Das S K，Kumar S，Ramachandrarao P． Exploitation of iron ore tailing for the development of ceramic tiles． Waste Manage， 2000，20(8): 725 ［17］ Cheng J S，Li H，Tang L Y，et al． Glass-ceramics． Beijing: Chemical Industry Press，2006 (程金树，李宏，汤李缨，等． 微晶玻璃． 北京:化学工业出版 社，2006) ［18］ Bernardo E，Andreola F，Barbieri L，et al． Sintered glass-ce￾ramics and glass-ceramic matrix composites from CRT panel glass． J Am Ceram Soc，2005，88(7): 1886 ［19］ Kim E S，Yeo W J． Thermal properties of CaMgSi2O6 glass￾ceramics with Al2O3 ． Ceram Int，2012，38(Suppl 1):S547 ［20］ Ercenk E，Sen U，Yilmaz S． The effect of SiC addition on the crystallization kinetics of atmospheric plasma-sprayed basalt￾based coatings． Ceram Int，2012，38(8): 6549 ［21］ Ewais E M，Grathwohl G，Ahmed Y M． Crystallization of mixer slag-derived glass-ceramic composites． J Am Ceram Soc，2010， 93(3): 671 ［22］ Karamanov A，Pelino M． Crystallization phenomena in iron-rich glasses． J Non Cryst Solids，2001，281(1): 139 ［23］ Augis J，Bennett J． Calculation of the Avrami parameters for het￾erogeneous solid state reactions using a modification of the Kissin￾ger method． J Therm Anal Calorim，1978，13(2): 283 ［24］ Karamanov A，Avramov I，Arrizza L，et al． Variation of Avrami parameter during non-isothermal surface crystallization of glass powders with different sizes． J Non Cryst Solids，2012，358 (12): 1486 ［25］ Clupper D，Hench L． Crystallization kinetics of tape cast bioac￾tive glass 45S5． J Non Cryst Solids，2003，318(1): 43 ［26］ Wang S H，Zhou H P，Luo L H． Sintering and crystallization of cordierite glass ceramics for high frequency multilayer chip induc￾tors． Mater Res Bull，2003，38(8): 1367 ·763·