张勇等：类松果状NiMoO,/MnO,复合材料的合成及超级电容性能 ·651· 学与技术，2016,5(6)：800) pacitor electrodes.Ceram Int,2016,42(16):18058 [2]Zhao X,Qiu P D.Jiang H J,et al.Latest research progress of [14]Zhao X,Wang H E,Chen XX,et al.Tubular MoO2 organized electrode materials for supercapacitor.Electr Comp Mater,2015, by 2D assemblies for fast and durable alkali-ion storage.Energy 34(1):1 Storage Mater,2018,11:161 (赵雪，邱平达，姜海静，等.超级电容器电极材料研究最新 [15]Li Y F,Jian J M,Fan Y,et al.Facile one-pot synthesis of a Ni- 进展.电子元件与材料，2015,34(1)：1) Mo0/reduced graphene oxide composite as a pseudocapacitor [3]Oudghiri-Hassani H,Al Wadaani F.Preparation,characterization with superior performance.RSC Adv,2016,6(73):69627 and catalytic activity of nickel molybdate NiMoO.nanoparti- [16]Gao H L,Wang L Z,Zhang Y,et al.Synthesis and electro- cles.Molecules,2018,23(2):273. chemical performances of Li FeSi0/C composite materials.J [4]Fang L X,Wang F,Zhai TL,et al.Hierarchical CoMoO nanon- Chin Ceramic Soc,2014,42(4):528 eedle electrodes for advanced supercapacitors and electrocatalytic (高海丽，王力臻，张勇，等.i2FSi0/C复合材料的制备 oxygen evolution.Electrochim Acta,2018,259:552 及电化学性能.硅酸盐学报，2014,42(4)：528) [5]Li M G,Yang WW,Huang Y R,et al.Hierarchical mesoporous [17]Wang XX,Zhang B Q,Yu M X,et al.Enhanced microwave Co0@ZnCoO hybrid nanowire arrays supported on Ni foam for absorption capacity of hierarchical structural MnO,@NiMoO high-performance asymmetric supereapacitors.Sci China Mater, composites.RSC Adv,2016,6(43):36484 2018,61(9):1167 [18]Cai D P,Wang DD,Liu B,et al.Three-dimensional Co0@ [6]Lee G H,Lee S,Kim JC,et al.MnMo0 eleetrocatalysts for su- NiMoO core/shell nanowire arrays on Ni foam for electrochemical perior long-life and high-rate lithium-oxygen batteries.Ade Energy energy storage.ACS Appl Mater Interfaces,2014,6(7):5050 Mater,2017,7(6):1601741 [19]Pang M J,Jiang S.Ji Y,et al.Comparison of a-NiMoO nano [7]Deng T.Investigations of Co-based Electrode Materials for Superca- rods and hierarchical a-NiMo0,@8-Mn0,core-shell hybrid pacitors and the Atomic-Level Energy Storage Mechanism [Disserta- nanorod/nanosheet aligned on Ni foam for supercapacitors.JAl- tion].Changchun:Jilin University,2017 loys Compd,2017,708:14 (邓霆.超级电容器钻基电极材料制备及其储能机理的研究 [20]Ma X J,Zhang W B,Kong L B,et al.NiMoO-modified MnO2 [学位论文].长春：吉林大学，2017) hybrid nanostructures on nickel foam:electrochemical perform- [8]Zhang Y,Feng H,Wu X B,et al.Progress of electrochemical ca- ance and supercapacitor applications.Nen J Chem,2015,39 pacitor electrode materials:a review.Int Hydrogen Energy, (8):6207 2009,34(11):4889 [21]Sun W.The Preparation of Nanometer Nickel (Cobalt)Hydroxide [9]Lii J L,Miura H,Yang M.A novel mesoporous NiMoO@rGO Electrode Materials and Their Electrchemical Properties Disserta- nanostructure for supercapacitor applications.Mater Lett,2017, tion).Harbin:Harbin Engineering University,2012 194:94 (孙薇.纳米氢氧化镍（钴）电极材料的制备及其电化学性能 [10]Zhou D,Cheng PP,Luo JX,et al.Facile synthesis of graphene 研究[学位论文].哈尔滨：哈尔滨工程大学，2012) NiMoO nanosheet arrays on Ni foam for a high-performance [22]Wang X H,Xia H Y,Gao J,et al.Enhanced cycle performance asymmetric supercapacitor.J Mater Sci,2017,52(24):13909 of ultraflexible asymmetric supercapacitors based on a hierarchical [11]Zhang Z,Liu Y D,Huang Z Y,et al.Facile hydrothermal syn- Mn0@NiMoO core-shell nanostructure and porous carbon.J thesis of NiMoO@CoMoO hierarchical nanospheres for superca- Mater Chem A,2016,4(46):18181 pacitor applications.Phys Chem Chem Phys,2015,17 (32): [23]Kazemi S H,Bahmani F,Kazemi H,et al.Binder-free elec- 20795 trodes of NiMoO/graphene oxide nanosheets:synthesis,charac- [12]Cao M L,Bu Y,Lii X W,et al.Three-dimensional Ti02 terization and supercapacitive behavior.RSC Ade,2016,6 nanowire@NiMoO,ultrathin nanosheet core-shell arrays for lithi- (112):111170 um ion batteries.Appl Surf Sci,2018,435:641 [24]Lin J H,Liang H Y,Jia H N,et al.Hierarchical CuCo2O@ [13]Chen H,Yu L,Zhang J M,et al.Construction of hierarchical NiMoO,core-shell hybrid arrays as a battery-like electrode for su- NiMoO@MnO,nanosheet arrays on titanium mesh for superca- percapacitors.Inorg Chem Front,2017,4(9):1575张 勇等: 类松果状 NiMoO4 / MnO2 复合材料的合成及超级电容性能 学与技术, 2016, 5(6): 800) [2] Zhao X, Qiu P D, Jiang H J, et al. Latest research progress of electrode materials for supercapacitor. Electr Comp Mater, 2015, 34(1): 1 (赵雪, 邱平达, 姜海静, 等. 超级电容器电极材料研究最新 进展. 电子元件与材料, 2015, 34(1): 1) [3] Oudghiri鄄Hassani H, Al Wadaani F. Preparation, characterization and catalytic activity of nickel molybdate ( NiMoO4 ) nanoparti鄄 cles. Molecules, 2018, 23(2): 273. [4] Fang L X, Wang F, Zhai T L, et al. Hierarchical CoMoO4 nanon鄄 eedle electrodes for advanced supercapacitors and electrocatalytic oxygen evolution. Electrochim Acta, 2018, 259: 552 [5] Li M G, Yang W W, Huang Y R, et al. Hierarchical mesoporous Co3O4@ ZnCo2O4 hybrid nanowire arrays supported on Ni foam for high鄄performance asymmetric supercapacitors. Sci China Mater, 2018, 61(9): 1167 [6] Lee G H, Lee S, Kim J C, et al. MnMoO4 electrocatalysts for su鄄 perior long鄄life and high鄄rate lithium鄄oxygen batteries. Adv Energy Mater, 2017, 7(6): 1601741 [7] Deng T. Investigations of Co鄄based Electrode Materials for Superca鄄 pacitors and the Atomic鄄Level Energy Storage Mechanism [Disserta鄄 tion]. Changchun: Jilin University, 2017 (邓霆. 超级电容器钴基电极材料制备及其储能机理的研究 [学位论文]. 长春: 吉林大学, 2017) [8] Zhang Y, Feng H, Wu X B, et al. Progress of electrochemical ca鄄 pacitor electrode materials: a review. Int J Hydrogen Energy, 2009, 34(11): 4889 [9] L俟 J L, Miura H, Yang M. A novel mesoporous NiMoO4 @ rGO nanostructure for supercapacitor applications. Mater Lett, 2017, 194: 94 [10] Zhou D, Cheng P P, Luo J X, et al. Facile synthesis of graphene @ NiMoO4 nanosheet arrays on Ni foam for a high鄄performance asymmetric supercapacitor. J Mater Sci, 2017, 52(24): 13909 [11] Zhang Z, Liu Y D, Huang Z Y, et al. Facile hydrothermal syn鄄 thesis of NiMoO4@ CoMoO4 hierarchical nanospheres for superca鄄 pacitor applications. Phys Chem Chem Phys, 2015, 17 ( 32 ): 20795 [12] Cao M L, Bu Y, L俟 X W, et al. Three鄄dimensional TiO2 nanowire@ NiMoO4 ultrathin nanosheet core鄄shell arrays for lithi鄄 um ion batteries. Appl Surf Sci, 2018, 435: 641 [13] Chen H, Yu L, Zhang J M, et al. Construction of hierarchical NiMoO4@ MnO2 nanosheet arrays on titanium mesh for superca鄄 pacitor electrodes. Ceram Int, 2016, 42(16): 18058 [14] Zhao X, Wang H E, Chen X X, et al. Tubular MoO2 organized by 2D assemblies for fast and durable alkali鄄ion storage. Energy Storage Mater, 2018, 11: 161 [15] Li Y F, Jian J M, Fan Y, et al. Facile one鄄pot synthesis of a Ni鄄 MoO4 / reduced graphene oxide composite as a pseudocapacitor with superior performance. RSC Adv, 2016, 6(73): 69627 [16] Gao H L, Wang L Z, Zhang Y, et al. Synthesis and electro鄄 chemical performances of Li2 FeSiO4 / C composite materials. J Chin Ceramic Soc, 2014, 42(4): 528 (高海丽, 王力臻, 张勇, 等. Li2 FeSiO4 / C 复合材料的制备 及电化学性能. 硅酸盐学报, 2014, 42(4): 528) [17] Wang X X, Zhang B Q, Yu M X, et al. Enhanced microwave absorption capacity of hierarchical structural MnO2 @ NiMoO4 composites. RSC Adv, 2016, 6(43): 36484 [18] Cai D P, Wang D D, Liu B, et al. Three鄄dimensional Co3O4@ NiMoO4 core / shell nanowire arrays on Ni foam for electrochemical energy storage. ACS Appl Mater Interfaces, 2014, 6(7): 5050 [19] Pang M J, Jiang S, Ji Y, et al. Comparison of 琢鄄NiMoO4 nano鄄 rods and hierarchical 琢鄄NiMoO4 @ 啄鄄MnO2 core鄄shell hybrid nanorod / nanosheet aligned on Ni foam for supercapacitors. J Al鄄 loys Compd, 2017, 708: 14 [20] Ma X J, Zhang W B, Kong L B, et al. NiMoO4 鄄modified MnO2 hybrid nanostructures on nickel foam: electrochemical perform鄄 ance and supercapacitor applications. New J Chem, 2015, 39 (8): 6207 [21] Sun W. The Preparation of Nanometer Nickel (Cobalt) Hydroxide Electrode Materials and Their Electrchemical Properties [Disserta鄄 tion]. Harbin: Harbin Engineering University, 2012 (孙薇. 纳米氢氧化镍(钴)电极材料的制备及其电化学性能 研究[学位论文]. 哈尔滨: 哈尔滨工程大学, 2012) [22] Wang X H, Xia H Y, Gao J, et al. Enhanced cycle performance of ultraflexible asymmetric supercapacitors based on a hierarchical MnO2 @ NiMoO4 core鄄shell nanostructure and porous carbon. J Mater Chem A, 2016, 4(46): 18181 [23] Kazemi S H, Bahmani F, Kazemi H, et al. Binder鄄free elec鄄 trodes of NiMoO4 / graphene oxide nanosheets: synthesis, charac鄄 terization and supercapacitive behavior. RSC Adv, 2016, 6 (112): 111170 [24] Lin J H, Liang H Y, Jia H N, et al. Hierarchical CuCo2O4 @ NiMoO4 core鄄shell hybrid arrays as a battery鄄like electrode for su鄄 percapacitors. Inorg Chem Front, 2017, 4(9): 1575 ·651·