880 工程科学学报,第43卷,第7期 浸金试剂,但无论是在酸性还是碱性体系中,硫脲 refractory gold concentrate with a two-stage chemical-biological 都不太稳定;在pH值大于2的酸性体系或温度大 approach.Hydrometallurgy,2020,197:105421 于25℃时易分解,导致硫脲消耗高,需要进一步 [11]Wang J,Wang W,Dong K W,et al.Research on leaching of carbonaceous gold ore with copper-ammonia-thiosulfate solutions. 研究硫脲的稳定性,防止二硫甲脒的分解,控制氧 Miner Eng,2019,137:232 化还原电位值,防止硫脲的过度氧化.生物氧化和 [12]Liu X L,Jiang T,Xu B,et al.Thiosulphate leaching of gold in the 两步硫脲浸出工艺药剂消耗低,浸出液中和无需 Cu-NH-S202--H2O system:An updated thermodynamic analy- 额外成本,且环境友好,因此,将两步硫脲法与生 sis using predominance area and species distribution diagrams. 物氧化法相结合是一种值得进一步研究甚至应用 Miner Eng,.2020,151:106336 于工业的方法 [13]Liu X L,Xu B,Yang Y B,et al.Effect of galena on thiosulfate (5)二甲基亚砜是一种非质子极性溶剂,用含 leaching of gold.Hydrometallurgy,2017,171:157 CBr,的二甲基亚砜溶液浸金,浸出液可重复使用 [14]Yang Y B,Gao W,Xu B,et al.Study on oxygen pressure 且浸金过程中不产生化学污泥.因此,中小型企业 thiosulfate leaching of gold without the catalysis of copper and ammonia.Hydrometallurgy,2019,187:71 可采用此工艺从二次资源中回收金. [15]Nie Y H,Yang L,Wang Q,et al.Connection between gold dissolution in thiosulfate leaching and Cu(Il)complexes during the 参考文献 cathodic process.Electrochimica Acta,2019,328:135079 [1]Reith F,Lengke M,Falconer D,et al.The geomicrobiology of [16]Xu B,Li K,Zhong Q,et al.Study on the oxygen pressure alkaline gold.ISME J,2007:567 leaching of gold with generated thiosulfate from sulfur oxidation. [2]Yu S M,Yu TT,Song W P,et al.Ultrasound-assisted cyanide Hydrometallurgy,2018,177:178 extraction of gold from gold concentrate at low temperature. [17]Jeffrey M I,Watling K,Hope G A,et al.Identification of surface Ultrason Sonochem,2020,64:105039 species that inhibit and passivate thiosulfate leaching of gold. [3] Guo X Y,Zhang L,Tian Q H,et al.Stepwise extraction of gold Miner Eng,2008,21(6)上:443 and silver from refractory gold concentrate calcine by thiourea. [18]Baron J Y,Mirza J,Nicol E A,et al.SERS and electrochemical Hydrometallurgy,2020,194:105330 studies of the gold-electrolyte interface under thiosulfate based [4] Han J H,Li X A,Dai S J.Electrochemical influence of quartz on leaching conditions.Electrochimica Acta,2013,111:390 cyanide leaching of gold.Chem Phys Lett,2020,739:136997 [19]Xu B,Yang Y B,Li Q,et al.Effect of common associated sulfide [5] Wang H J,Feng Y L,Li H R,et al.Simultaneous extraction of minerals on thiosulfate leaching of gold and the role of humic acid gold and zinc from refractory carbonaceous gold ore by additive.Hydrometallurgy,2017,171:44 chlorination roasting process.Trans Nonferrous Met Soc China. [20]Yu H,Zi F T,Hu X Z,et al.The copper-ethanediamine- 2020,30(4):1111 thiosulphate leaching of gold ore containing limonite with [6] Yang TZ,Rao S,Liu W F,et al.A selective process for extracting cetyltrimethyl ammonium bromide as the synergist. antimony from refractory gold ore.Hydrometallurgy,2017,169: Hydrometallurgy,2014,150:178 571 [21]Chandra I,Jeffrey M I.A fundamental study of ferric oxalate for [7]Jia Y J,Wang X H,Cheng W,et al.Research progress on non- dissolving gold in thiosulfate solutions.Hydrometallurgy,2005, cyanide leaching of refractory gold ores.Chin J Eng,2019,41(3): 77(3-4):191 307 [22]Heath J A,Jeffrey M I,Zhang H G,et al.Anaerobic thiosulfate (贾玉娟,王晓辉,程伟,等.难处理金矿非氰浸金研究进展.工 leaching:Development of in situ gold leaching systems.Miner 程科学学学报,2019,41(3):307) Eg,2008,21(6):424 [8]Cao P,Zhang S H.Zheng Y J.Effects of iron,arsenic and carbon [23]Xu B,Li K,Dong Z L,et al.Eco-friendly and economical gold removal from a dust of refractory gold concentrates on cyanide extraction by nickel catalyzed ammoniacal thiosulfate leaching- leaching.ChinJ Nonferrous Met,2020,30(5):1142 resin adsorption recovery.JCleaner Prod,019,233:1475 (曹攀,张霜华,郑雅杰.难治金精矿烟尘中铁砷碳的脱除对氰 [24]Xu B,Yang Y B,Li Q,et al.Stage leaching of a complex 化浸金的影响.中国有色金属学报,2020,30(5):1142) polymetallic sulfide concentrate:Focus on the extraction of Ag and [9]Ren C Y.Study on The Mechanism and Process of Gold Leaching Au.Hydrometallurgy,2016,159:87 by Thiourea in The Acid System of Biological Pre-Oxidation [25]Xu B,Li K,Li Q,et al.Kinetic studies of gold leaching from a Residue of Refractory Gold Ore Containing Arsenic [Dissertation] gold concentrate calcine by thiosulfate with cobalt-ammonia Beijing:General Research Institute for Nonferrous Metals,2020 catalysis and gold recovery by resin adsorption from its pregnant (任传裕.含砷难处理金矿生物预氧化渣酸性体系硫脲浸金机 solution.Sep Purif Technol,2019,213:368 理及工艺研究学位论文].北京:北京有色金属研究总院,2020) [26]Liu X L,Xu B,Yang Y B,et al.Thermodynamic analysis of [10]Wang G H,Liu XX,Wu Y H,et al.Bio-oxidation of a high-sulfur ammoniacal thiosulphate leaching of gold catalysed by Co(IIl)/浸金试剂,但无论是在酸性还是碱性体系中,硫脲 都不太稳定;在 pH 值大于 2 的酸性体系或温度大 于 25 ℃ 时易分解,导致硫脲消耗高,需要进一步 研究硫脲的稳定性,防止二硫甲脒的分解,控制氧 化还原电位值,防止硫脲的过度氧化. 生物氧化和 两步硫脲浸出工艺药剂消耗低,浸出液中和无需 额外成本,且环境友好,因此,将两步硫脲法与生 物氧化法相结合是一种值得进一步研究甚至应用 于工业的方法. (5)二甲基亚砜是一种非质子极性溶剂,用含 CuBr2 的二甲基亚砜溶液浸金,浸出液可重复使用 且浸金过程中不产生化学污泥. 因此,中小型企业 可采用此工艺从二次资源中回收金. 参 考 文 献 Reith F, Lengke M, Falconer D, et al. The geomicrobiology of gold. ISME J, 2007: 567 [1] Yu S M, Yu T T, Song W P, et al. Ultrasound-assisted cyanide extraction of gold from gold concentrate at low temperature. Ultrason Sonochem, 2020, 64: 105039 [2] Guo X Y, Zhang L, Tian Q H, et al. Stepwise extraction of gold and silver from refractory gold concentrate calcine by thiourea. Hydrometallurgy, 2020, 194: 105330 [3] Han J H, Li X A, Dai S J. Electrochemical influence of quartz on cyanide leaching of gold. Chem Phys Lett, 2020, 739: 136997 [4] Wang H J, Feng Y L, Li H R, et al. Simultaneous extraction of gold and zinc from refractory carbonaceous gold ore by chlorination roasting process. Trans Nonferrous Met Soc China, 2020, 30(4): 1111 [5] Yang T Z, Rao S, Liu W F, et al. A selective process for extracting antimony from refractory gold ore. Hydrometallurgy, 2017, 169: 571 [6] Jia Y J, Wang X H, Cheng W, et al. Research progress on noncyanide leaching of refractory gold ores. Chin J Eng, 2019, 41(3): 307 (贾玉娟, 王晓辉, 程伟, 等. 难处理金矿非氰浸金研究进展. 工 程科学学学报, 2019, 41(3):307) [7] Cao P, Zhang S H, Zheng Y J. Effects of iron, arsenic and carbon removal from a dust of refractory gold concentrates on cyanide leaching. Chin J Nonferrous Met, 2020, 30(5): 1142 (曹攀, 张霜华, 郑雅杰. 难冶金精矿烟尘中铁砷碳的脱除对氰 化浸金的影响. 中国有色金属学报, 2020, 30(5):1142) [8] Ren C Y. Study on The Mechanism and Process of Gold Leaching by Thiourea in The Acid System of Biological Pre-Oxidation Residue of Refractory Gold Ore Containing Arsenic [Dissertation]. Beijing: General Research Institute for Nonferrous Metals, 2020 ( 任传裕. 含砷难处理金矿生物预氧化渣酸性体系硫脲浸金机 理及工艺研究[学位论文]. 北京: 北京有色金属研究总院, 2020) [9] [10] Wang G H, Liu X X, Wu Y H, et al. Bio-oxidation of a high-sulfur refractory gold concentrate with a two-stage chemical-biological approach. Hydrometallurgy, 2020, 197: 105421 Wang J, Wang W, Dong K W, et al. Research on leaching of carbonaceous gold ore with copper-ammonia-thiosulfate solutions. Miner Eng, 2019, 137: 232 [11] S2O 2− 3 Liu X L, Jiang T, Xu B, et al. Thiosulphate leaching of gold in the Cu‒NH3‒ ‒H2O system: An updated thermodynamic analysis using predominance area and species distribution diagrams. Miner Eng, 2020, 151: 106336 [12] Liu X L, Xu B, Yang Y B, et al. Effect of galena on thiosulfate leaching of gold. Hydrometallurgy, 2017, 171: 157 [13] Yang Y B, Gao W, Xu B, et al. Study on oxygen pressure thiosulfate leaching of gold without the catalysis of copper and ammonia. Hydrometallurgy, 2019, 187: 71 [14] Nie Y H, Yang L, Wang Q, et al. Connection between gold dissolution in thiosulfate leaching and Cu(II) complexes during the cathodic process. Electrochimica Acta, 2019, 328: 135079 [15] Xu B, Li K, Zhong Q, et al. Study on the oxygen pressure alkaline leaching of gold with generated thiosulfate from sulfur oxidation. Hydrometallurgy, 2018, 177: 178 [16] Jeffrey M I, Watling K, Hope G A, et al. Identification of surface species that inhibit and passivate thiosulfate leaching of gold. Miner Eng, 2008, 21(6): 443 [17] Baron J Y, Mirza J, Nicol E A, et al. SERS and electrochemical studies of the gold-electrolyte interface under thiosulfate based leaching conditions. Electrochimica Acta, 2013, 111: 390 [18] Xu B, Yang Y B, Li Q, et al. Effect of common associated sulfide minerals on thiosulfate leaching of gold and the role of humic acid additive. Hydrometallurgy, 2017, 171: 44 [19] Yu H, Zi F T, Hu X Z, et al. The copper-ethanediaminethiosulphate leaching of gold ore containing limonite with cetyltrimethyl ammonium bromide as the synergist. Hydrometallurgy, 2014, 150: 178 [20] Chandra I, Jeffrey M I. A fundamental study of ferric oxalate for dissolving gold in thiosulfate solutions. Hydrometallurgy, 2005, 77(3− 4): 191 [21] Heath J A, Jeffrey M I, Zhang H G, et al. Anaerobic thiosulfate leaching: Development of in situ gold leaching systems. Miner Eng, 2008, 21(6): 424 [22] Xu B, Li K, Dong Z L, et al. Eco-friendly and economical gold extraction by nickel catalyzed ammoniacal thiosulfate leachingresin adsorption recovery. J Cleaner Prod, 2019, 233: 1475 [23] Xu B, Yang Y B, Li Q, et al. Stage leaching of a complex polymetallic sulfide concentrate: Focus on the extraction of Ag and Au. Hydrometallurgy, 2016, 159: 87 [24] Xu B, Li K, Li Q, et al. Kinetic studies of gold leaching from a gold concentrate calcine by thiosulfate with cobalt-ammonia catalysis and gold recovery by resin adsorption from its pregnant solution. Sep Purif Technol, 2019, 213: 368 [25] Liu X L, Xu B, Yang Y B, et al. Thermodynamic analysis of ammoniacal thiosulphate leaching of gold catalysed by Co(III)/ [26] · 880 · 工程科学学报,第 43 卷,第 7 期