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(责任编辑王琳) o1994-2011ChinaAcademicJournalElectronicPublishinghOuse.Allrightsreservedhttp://www.cnki.net［27］ KAKIUCHI F，MATSUURA Y，KAN S，et al． A ruH2 ( CO) ( PPh3 ) 3 － catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon － hydrogen bond cleavage ［J］． J Am Chem Soc，2005，127( 16) : 5 936 － 5 945． ［28］ OI S，SATO H，SUGAWARA S，et al． Nitrogen － directed ortho － selective homocoupling of aromatic compounds catalyzed by ru￾thenium complexes ［J］． Org Lett，2008，10( 9) : 1 823 － 1 826． ［29］ DENG G，ZHAO L，LI C J． Ruthenium － catalyzed oxidative cross － coupling of chelating arenes and cycloalkanes ［J］． Angew Chem Int Ed，2008，47( 33) : 6 278 － 6 282． ［30］ OI S，FUKITA S，HIRATA N，et al． Ruthenium complex － catalyzed direct ortho arylation and alkenylation of 2 － arylpyridines with organic halides ［J］． Org Lett，2001，3( 16) : 2 579 － 2 581． ［31］ OI S，OGINO Y，FUKITA S，et al． Ruthenium complex catalyzed direct ortho arylation and alkenylation of aromatic imines with organic halides ［J］． Org Lett，2002，4( 10) : 1 783 － 1 785． ［32］ OI S，FUKITA S，INOUE Y． Rhodium － catalysed direct ortho arylation of 2 － arylpyridines with arylstannanes via C—H activa￾tion ［J］． Chem Commun，1998( 22) : 2 439 － 2 440． ［33］ UEURA K，SATOH T，MIURA M． Rhodium － catalyzed arylation using arylboron compounds: efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile ［J］． Org Lett，2005，7( 11) : 2 229 － 2 231． ［34］ MIYAMURA S，TSURUGI H，SATOH T，et al． Rhodium － catalyzed regioselective arylation of phenylazoles and related com￾pounds with arylboron reagents via C—H bond cleavage ［J］． J Organomet Chem，2008，693( 14) : 2 438 － 2 442． ［35］ VOGLER T，STUDER A． Oxidative coupling of arylboronic acids with arenes via Rh － catalyzed direct C—H arylation［J］． Org Lett，2008，10( 1) : 129． ［36］ BEDFORD R B，COLES S J，HURSTHOUSE M B，et al． The catalytic intermolecular orthoarylation of phenols ［J］． Angew Chem Int Ed，2003，42( 1) : 112 － 114． ［37］ PROCH S，KEMPE R． An efficient bimetallic rhodium catalyst for the direct arylation of unactivated arenes ［J］． Angew Chem Int Ed，2007，46( 17) : 3 135 － 3 138． ［38］ ZHAO X，YU Z． Rhodium － catalyzed regioselective C—H functionalization via decarbonylation of acid chlorides and C—H bond activation under phosphine － free conditions ［J］． J Am Chem Soc，2008，130( 26) : 8 136 － 8 137． ［39］ JIN W，YU Z，HE W，et al． Efficient Rh( I) － catalyzed cirect arylation and alkenylation of arene C—H bonds via decarbonyla￾tion of benzoic and cinnamic anhydrides ［J］． Org Lett，2009，11( 6) : 1 317 － 1 320． ［40］ DO H Q，KASHIF KHAN R M，DAUGULIS O． A general method for copper － catalyzed arylation of arene C—H bonds ［J］． J Am Chem Soc，2008，130( 45) : 15 185 － 15 192． ［41］ PHIPPS R J，GRIMSTER N P，GAUNT M J． Cu( Ⅱ) － catalyzed cirect and site － selective arylation of indoles under mild condi￾tions ［J］． J Am Chem Soc，2008，130( 26) : 8 172 － 8 174． ［42］ PHIPPS R J，GAUNT M J． A meta － selective copper － catalyzed C—H bond arylation［J］． Science，2009，323( 5921) ，1 593 － 1 597． ［43］ CAVINET J，YAMAGUCHI J，BAN I，ITAMI K． Nickel － catalyzed biaryl coupling of heteroarenes and aryl halides/triflates ［J］． Org Lett，2009，11( 8) : 1 733 － 1 736． ［44］ HACHIYA H，HIRANO K，SATOH T，et al． Nickel － catalyzed direct arylation of azoles with aryl bromides［J］． Org Lett，2009， 11( 8) : 1 737 － 1 740． ［45］ KOBAYASHI O，URAGUCHI D，YAMAKAWA T． Cp2Ni － KOt － Bu － BEt3 ( or PPh3 ) catalyst system for direct C—H arylation of benzene，naphthalene，and pyridine ［J］． Org Lett，2009，11( 12) : 2 679 － 2 682． ［46］ PLIETKER B． Iron catalysis in organic chemistry［M］． Weinheim: Wiley － VCH，2008． ［47］ NORINDER J，MATSUMOTO A，YOSHIKAI N，et al． Iron － catalyzed direct arylation through directed C—H bond activation ［J］． J Am Chem Soc，2008，130( 18) : 5 858 － 5 859． ［48］ WEN J，ZHANG J，CHEN S Y，et al． Iron － Mediated Direct Arylation of Unactivated Arenes［J］． Angew Chem Int Ed，2008， 47( 1) : 8 897 － 8 900． ( 责任编辑 王 琳) 326 云南民族大学学报( 自然科学版) 第 20 卷