Pk#RT Areat Library/ID Ref# CAS# Qual 1 1.24 13.60 C:\DATABASE\WILEY275.L 1-Propene,1-chloro-2-methyl-$s P 4325000513-37-170 1-Butene, 3-chloro-(CAS)Ss 3-Chl 4315000563-52-050 2-Buten-1-ol (CAS)$2-Butenol $ 1385006117-91-550 2 1.25 23.88 C:\DATABASE\WILEY275.L 1-Butene,3-chloro-(CAS)$$3-Chl 4315000563-52-091 1-Propene, 1-chloro-2-methyl-$$P 4325000513-37-183 1-Propene,3-chloro-2-methyl-(CAS 4330 000563-47-376 3 1.51 4.53 C:\DATABASE\WILEY275.L Bicyclobutane ss Bicyclo[1.1.0]but 369000157-33-542 2-Propyn-1-o1,propionate $Propa 10463001932-92-938 1-methy1-2-propenyl methanoate $s 6537111515-61-838 D:\HPCHEM\1\DATA\2011\DJX-20.DMon Jun 27 10:15:16 2011 Page 1 图S6保留时间1.25min的样品离子碎片图库检索为CB Figure S6 Mass spectrum of CB(retention time in 1.25 min)is compared with standard mass spectrum map 4 1.54 49.34 C:\DATABASE\WILEY275.L 1-Propene,3-chloro-2-methy1-(CAS 4328000563-47-395 1-Butene. 3-chloro- (CAS)ss 3-chl 4315000563-52-091 2-Butene,2-chloro- (CAS)ss 2-ch1 4323004461-41-087 5 2.04 3.66 C:\DATABASE\WILEY275.L CIS-1-METHOXY-2-BUTENE 3434010034-14-778 1,3-Butadiene (CAS)S$Divinyl $ 364000106=99=064 2-Methy1-2-vinyloxirane 2847001838-94-453 6 2.07 2.16 C:\DATABASE\WILEY275.L ETHER,DI-3-BUTEN-2-YL S$1-Butene 17986006925-74-236 2-Propyn-1-o1 (CAS)SS Propargyl a 409000107-19-74 Cyclopentane,1-ethyi-3-methyi-, 11114002613-66-3 7 2.29 0.76 C:\DATABASE\WILEY275.L ETHER,DI-3-BUTEN-2-YL $1-Butene 17986006925-74-283 Orthoformic acid,tri-2-butenyl es 112246 014503-57-2 12 1-Butanethiol,3-methyl- (CAS)Ss 82B8 000541-31-1 8 4.04 2.07 C:\DATABASE\WILEY275.L 1-Butene,3-(2-butenyloxy)-(CAS) 17985001476-05-790 Bis(but-2-enyl)ether 17984000000-00-050 orthoformic acid,tri-2-butenyl es 112246 014503-57-225 D:\HPCHEM\1\DATA\2011\DJX-20.DMon Jun 27 10:15:17 2011 Page 2 图s7保留时间1.54min的样品离子碎片图库检索为CC Figure S7 Mass spectrum of CC(retention time in 1.54 min)is compared with standard mass spectrum map S5S5 图 S6 保留时间 1.25 min 的样品离子碎片图库检索为 CB Figure S6 Mass spectrum of CB (retention time in 1.25 min) is compared with standard mass spectrum map 图 S7 保留时间 1.54 min 的样品离子碎片图库检索为 CC Figure S7 Mass spectrum of CC (retention time in 1.54 min) is compared with standard mass spectrum map