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。558· 北京科技大学学报 2006年第6期 材料,此结果比较接近于俄罗斯目前研制的密度 【李绍雄朱吕民.聚氨酯树脂。南京:江苏省科学出版社 0.7gcm3,压缩强度70MPa的固体浮力材料. 1992 [可吴舜英徐敬一.泡沫塑料成型。北京化学工业出版杜. 参考文献 1988 [7吕世光.塑料助剂手册.北京:轻工业出版社,1986 【刂俞鸿森,李启聪。固体浮力材料的设计与试验。船工科技 【8高家诚张延楷.发展中的空心微珠材料.材料导报。1990 1986(SuppD):253 (8):26 【习陈先张树华.新型深潜用固体浮力材料.化工新型材料 【9刘伯元江广成。超细玻璃微珠(简称微珠材料)的研究.塑 1999.27(7):15 料加工.2003.38(2):36 【3引张德志.国内外高强度浮力材料的现状.声学与电子工程 【10蒋春华.玻璃微珠的应用.江苏建材,2001,84(4):27 2003,71(3):45 【11李策镭.空心漂珠的应用.电力建设,1995(10):10 李鹏刘德安,杨学忠。微球复合泡沫材料的研究和应用 玻璃钢/复合材料.20007(4):21 High-strength deep-sea buoyancy material made of polymer filled with hollow glass micro-beads SUN Chunbao,XING Yi,WANG Oifeng Civil and Envirommental Engineering Schodl University of Science and Technobgy Beijing.Beijing 100083 China ABSTRACT A material with bw density and high strength was made by filling great amount of hollow glass micro-beads in bulk material epoxy resin.m-phenylenediamine (M PD)and 4,4-diaminodiphe- nylsulfone-(DDS)were chosen as the optimal modifier.The consistence betw een polymer and hollow glass beads and the mixing quantity of hollow glass beads were increased by modifying the surface of hollow glass beads.Through sy stem optimization on all the factors influencing the surface treatment,the deepsea buoy- ancy material w as fabricated with a density of 0.61~0.75g'cm,a compression strength of 40~68.96 M Pa and a less water absorption rate. KEY WORDS high-strength buoyancy material;hollow glass micro-bead;polymer;modifier材料, 此结果比较接近于俄罗斯目前研制的密度 0.7 g·cm -3 ,压缩强度 70 MPa 的固体浮力材料 . 参 考 文 献 [ 1] 俞鸿森, 李启聪.固体浮力材料的设计与试验.船工科技, 1986(Suppl):253 [ 2] 陈先, 张树华.新型深潜用固体浮力材料.化工新型材料, 1999 , 27(7):15 [ 3] 张德志.国内外高强度浮力材料的现状.声学与电子工程, 2003 , 71(3):45 [ 4] 李鹏, 刘德安, 杨学忠.微球复合泡沫材料的研究和应用. 玻璃钢/ 复合材料, 2000 , 7(4):21 [ 5] 李绍雄, 朱吕民.聚氨酯树脂.南京:江苏省科学出版社, 1992 [ 6] 吴舜英, 徐敬一.泡沫塑料成型.北京:化学工业出版杜, 1988 [ 7] 吕世光.塑料助剂手册.北京:轻工业出版社, 1986 [ 8] 高家诚, 张延楷.发展中的空心微珠材料.材料导报, 1990 (8):26 [ 9] 刘伯元, 江广成.超细玻璃微珠(简称微珠材料)的研究.塑 料加工, 2003 , 38(2):36 [ 10] 蒋春华.玻璃微珠的应用.江苏建材, 2001 ,84(4):27 [ 11] 李策镭.空心漂珠的应用.电力建设, 1995(10):10 High-streng th deep-sea buoyancy material made of polymer filled with hollow glass micro-beads S UN Chunbao , X ING Y i , WANG Qifeng Civil and Environmental Engineering School, University of S cience and Technology Beijing , Beijing 100083 , China ABSTRACT A material w ith low density and hig h streng th w as made by filling g reat amount of hollow g lass micro-beads in bulk material epox y resin .m-phenylenediamine (M PD)and 4 , 4′-diaminodiphe￾nylsulfone-(DDS)were chosen as the optimal modifier.The consistence betw een polymer and hollow glass beads and the mixing quantity of hollow glass beads w ere increased by modifying the surface of hollow glass beads .Through sy stem optimization on all the factorsinfluencing the surface treatment , the deep-sea buoy￾ancy material w as fabricated w ith a density of 0.61 ~ 0.75 g·cm -3 , a compression strength of 40 ~ 68.96 M Pa and a less w ater absorption rate. KEY WORDS hig h-strength buoyancy material ;hollow g lass micro-bead ;polymer ;modifier · 558 · 北 京 科 技 大 学 学 报 2006 年第 6 期
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