·160 工程科学学报，第44卷.第1期 表6NaOH不同梯度生物油成分分析（质量分数） Table 6 Composition analysis of bio-oil with different gradients of NaOH Peak area/% No. Retention time /min Composition 0% 1% 3% 5% 8%10% 3.521 2.2-dimethoxybutane 1.19 7.22 4245 3-diethyl-2,4-azacyclobutanedione 0.37 一 1.82 3 5.229 Trione trioxide 7.72 0.55 0.59 9.238 butyl methyl phenyl ester 1.97 1.75 2.86 1.89 2.01 1.66 9.843 2-phenylpentan-3-isopropyl-alcohol 一 1.22 一 6 12.484 Methyl carbamate 1.97 2.23 7 15.693 Tri butyl acrylonitrile 7.12 2.9 05 2.03 1.73 16.689 Amino propanol 250 9 17.169 Dihydromannitol 2.12 1.92 2.46 10 17.665 1,6-dicarboxylic acid-pyrido imidazole 7 11 18.296 4-ethyl-Phenol 1.20 3.12 2.21 1.50 12 20.066 1-isocyano-2-methyl-benzene 1.12 2.28 3 23.105 5-methyl-indole 6.19 77 9.09 126 2.35 14 25.472 alanine 7.12 5g1 15 25.599 1,4-anhydrous-mannitol 3.12 3.84 16 26.076 2-acrylic acid,3-methylamino-ester 17 27.035 isopropyl-3-phenylpropanamide 1.29 1.32 18 28.355 Syringol 7.21 2.91 4.38 9 29.266 2,7-dimethyl-indolizine 218 20 30.191 N-dinitrophenyl-1-tryptophan 2.96 21 32.682 6-ethyl-2,3-dimethyl pyridine 一 200 22 32.69 2triazine-3-keone 2.37 一 23 38.203 1,4-dionePyrrolo pyrazine 2.87 38.29 2,5-dione,3,6-diisopropyl piperazin 2.12 54 542 3.76 1.72 25 39.089 1-methyl-indole 19.71 9.2 7.93 9.21 哈 40.711 2,5-piperazinodione,3,6-bis(2-methylpropyl- 9.32 3.52 3.46 27 41.719 1-methyl-indole 5.10 28 42.291 6-methyl-octadecane 11.49 29 44.006 Deoxyspermidine guanidin 42 30 44.239 1-heptyne-alcohol 12.56 44.791 Cyclopentanone,oxime 6.06 1329 1308 21.76 16.54 32 45.724 9.12-octadecadienoic acid 一 13.08 33 45.755 linoleic acid 7.21 9.40 34 45.758 1-alcohol-tetradece 0.87 14.18 35 48.679 2-amino-imidazole 2.12 5.75 9.46 36 48.731 1-octadecylamine 0.72 一 12.53 37 49.495 Cyclo-(1-leucyl-I-phenylalanyl) 11.21 20.98 5.01 38 50.581 1-alcohol-pentadecadiene 0.02 4.05 14.89 3.51 2.2.4生物油元素分析 剂，在260℃下，停留时间为135mim,催化产生的 表7列出了添加梯度NaCO3和NaOH催化 生物油的元素分析的结果.与不加催化剂相比，生表 6  NaOH 不同梯度生物油成分分析 （质量分数） Table 6   Composition analysis of bio-oil with different gradients of NaOH No. Retention time /min Composition Peak area/% 0% 1% 3% 5% 8% 10% 1 3.521 2,2-dimethoxybutane 1.19 7.22 — — — — 2 4.245 3-diethyl-2,4-azacyclobutanedione — — — 0.37 — 1.82 3 5.229 Trione trioxide 7.72 0.55 — — — 0.59 4 9.238 butyl methyl phenyl ester 1.97 1.75 2.86 1.89 2.01 1.66 5 9.843 2-phenylpentan-3-isopropyl-alcohol — 1.22 — — — — 6 12.484 Methyl carbamate 1.97 2.23 — — — — 7 15.693 Tri butyl acrylonitrile 7.12 2.91 5.17 2.95 2.03 1.73 8 16.689 Amino propanol — — — 2.50 — — 9 17.169 Dihydromannitol 2.12 — — — 1.92 2.46 10 17.665 1,6-dicarboxylic acid-pyrido imidazole — — — 0.76 — — 11 18.296 4-ethyl-Phenol 1.20 1.93 — 3.12 2.21 1.50 12 20.066 1-isocyano-2-methyl-benzene 1.12 — 6.08 — — 2.28 13 23.105 5-methyl-indole 6.19 2.75 3.60 9.09 1.26 2.35 14 25.472 alanine 7.12 — — 5.91 — — 15 25.599 1,4-anhydrous-mannitol 3.12 — — — — 3.84 16 26.076 2-acrylic acid,3-methylamino-ester — 3.24 4.68 — — — 17 27.035 isopropyl-3-phenylpropanamide — 1.28 — 2.28 1.29 1.32 18 28.355 Syringol 7.21 — — 0.93 2.91 4.38 19 29.266 2,7-dimethyl-indolizine — — — 2.18 — — 20 30.191 N-dinitrophenyl-l-tryptophan — — — — — 2.96 21 32.682 6-ethyl-2,3-dimethyl pyridine — — — 3.99 — — 22 32.69 2triazine-3-keone — — — — 2.37 — 23 38.203 1,4-dionePyrrolo pyrazine — — — — — 2.87 24 38.29 2,5-dione,3,6-diisopropyl piperazin 2.12 5.45 3.27 5.42 3.76 1.72 25 39.089 1-methyl-indole 19.71 9.22 6.82 7.10 7.93 9.21 26 40.711 2,5-piperazinodione, 3,6-bis (2-methylpropyl- 9.32 — 9.61 4.88 3.52 3.46 27 41.719 1-methyl-indole — — — — 5.10 — 28 42.291 6-methyl-octadecane — — — — — 11.49 29 44.006 Deoxyspermidine guanidin — — 10.98 4.72 — — 30 44.239 1-heptyne-alcohol — — — — — 12.56 31 44.791 Cyclopentanone, oxime 6.06 13.29 11.77 13.08 21.76 16.54 32 45.724 9,12-octadecadienoic acid — — — — 13.08 — 33 45.755 linoleic acid 7.21 — — 9.40 — — 34 45.758 1-alcohol-tetradece 0.87 — 14.18 — — — 35 48.679 2-amino-imidazole 2.12 5.75 — 9.46 — — 36 48.731 1-octadecylamine 0.72 — — — 12.53 — 37 49.495 Cyclo-(1-leucyl-l-phenylalanyl) — 11.21 20.98 5.01 — — 38 50.581 1-alcohol-pentadecadiene 0.02 — — 4.05 14.89 3.51 2.2.4    生物油元素分析 表 7 列出了添加梯度 Na2CO3 和 NaOH 催化 剂，在 260 ℃ 下，停留时间为 135 min，催化产生的 生物油的元素分析的结果. 与不加催化剂相比，生 · 160 · 工程科学学报，第 44 卷，第 1 期