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(1):17 Cem Concr Res,1996,26(5):717 (田键，陈坤，潘皇宇，等.钢渣对海洋工程混凝土保护作用 [27]Vieille L,Rousselot I,Leroux F,et al.Hydrocalumite and its 综述.建材世界，2017,38(1)：17) polymer derivatives.1.Reversible thermal behavior of Friedel's [14]Zhang T S,Liu F T,Wang J W,et al.Recent development of salt:a direct observation by means of high-temperature in situ steel slag stability and activating activity.Bull Chin Ceram Soc, powder X-ray diffraction.Chem Mater,2003,15(23):4361 2007,26(5):980 [28]Yue Y F,Wang JJ.Basheer PA M,et al.Raman spectroscopic (张同生，刘福田，王建伟，等.钢渣安定性与活性激发的研 investigation of Friedel's salt.Cem Concr Compos,2018,86: 究进展.硅酸盐通报，2007,26(5)：980) 306 [15]Shi C J.Steel slag-its production,processing,characteristics, [29]Birnin-Yauri U A,Glasser F P.Friedel's salt,Ca,Al(OH) and cementitious properties.J Mater Cir Eng,2004,16(3): (Cl,OH).2H20:its solid solutions and their role in chloride 230 binding.Cem Concr Res,1998.28(12):1713 [16]Wang Q,Yan P Y,Yang J W,et al.Influence of steel slag on [30]Qin L Q,Huang Z X,Zhang L M,et al.Flame-retardant mech- mechanical properties and durability of concrete.Constr Build anism of magnesium oxychloride in epoxy resin.Wuhan Unin Mater,2013,47:1414 Technol-Mater Sci Ed.2009.24(1):127 [17]Cui X W,Ni W.Effect of steel slag powder addition on proper- [31]Pane I,Hansen W.Investigation of blended cement hydration by ties of high strength tailings concrete.Met Mine,2014(9):177 isothermal calorimetry and thermal analysis.Cem Concr Res, (崔孝炜，倪文.钢渣粉掺入对高强尾矿混凝土性能的影响. 2005,35(6):1155 金属矿山，2014(9)：177) [32]Wang S P.Peng X Q,Geng J,et al.Synthesis of calcium sili- [18]Shi H S,Huang K S,Wu K,et al.Research advance on activa- cate hydrate based on steel slag with various alkalinitie.I Wuhan tion and mechanism of steel slag activity.Fly Ash Comprehens Unir Technol-Mater Sci Ed,2014,29(4):789 Uriliz,2011(1):48 [33]Black L,Garbev K,Beuchle G,et al.X-ray Photoelectron spec- (施惠生，黄昆生，吴凯，等.钢渣活性激发及其机理的研究 troscopic investigation of nanocrystalline calcium silicate hydrates 进展.粉煤灰综合利用，2011(1)：48) synthsised by reactive milling.Cem Coner Res,2006,36(6): [19]Tian J,Guo HQ.Research on water contamination treatment by 1023 hydrocalumite.Enriron Chem,2013,32(8):1571 [34]Bothe Jr J V,Brown P W.PhreegC modeling of Friedel's salt (天娇，郭清海.水铝钙石类阴离子黏土在水污染处理领域 equilibria at 231 C.Cem Coner Res,2004,34(6):1057工程科学学报,第 40 卷,第 10 期 sources. Yunnan Chem Technol, 2013, 40(6): 1 (朱明松. 老挝钾盐矿资源规模化开发的总体思路. 云南化 工, 2013, 40(6): 1) [9] Ding H X, Wu G P, Miao R T. Study on potash tailings filling technology. Ind Miner Process, 2016(6): 44 (丁红霞, 吴国平, 苗润田. 钾盐矿尾矿充填技术研究. 化工 矿物与加工, 2016(6): 44) [10] Li G Z, Li Y F, Ding P, et al. Backfill test study on oxy鄄chlo鄄 ride magnesium cement and potash tailings. China Mine Eng, 2010, 39(5): 23 (李国政, 李雨峰, 丁鹏, 等. 镁水泥与钾石盐尾矿胶结充填 材料试验研究. 中国矿山工程, 2010, 39(5): 23) [11] Xu X, Zeng B. Study on the tailings backfill technology of potash mine in Laos. Yunnan Chem Technol, 2013, 40(6): 41 (徐翔, 曾波. 老挝钾盐矿尾盐回填工程技术研究. 云南化 工, 2013, 40(6): 41) [12] Yuan H T, Gui Y L, Zhang S Y. Comprehensive utilization of steel鄄making slag. Shanxi Metall, 2016, 39(1): 35 (袁宏涛, 贵永亮, 张顺雨. 钢渣综合利用综述. 山西冶金, 2016, 39(1): 35) [13] Tian J, Chen K, Pan H Y, et al. Review of steel slag on the pro鄄 tection of marine engineering. World Build Mater, 2017, 38 (1): 17 (田键, 陈坤, 潘皇宇, 等. 钢渣对海洋工程混凝土保护作用 综述. 建材世界, 2017, 38(1): 17) [14] Zhang T S, Liu F T, Wang J W, et al. Recent development of steel slag stability and activating activity. Bull Chin Ceram Soc, 2007, 26(5): 980 (张同生, 刘福田, 王建伟, 等. 钢渣安定性与活性激发的研 究进展. 硅酸盐通报, 2007, 26(5): 980) [15] Shi C J. Steel slag—its production, processing, characteristics, and cementitious properties. J Mater Civ Eng, 2004, 16 (3 ): 230 [16] Wang Q, Yan P Y, Yang J W, et al. Influence of steel slag on mechanical properties and durability of concrete. Constr Build Mater, 2013, 47: 1414 [17] Cui X W, Ni W. Effect of steel slag powder addition on proper鄄 ties of high strength tailings concrete. Met Mine, 2014(9): 177 (崔孝炜, 倪文. 钢渣粉掺入对高强尾矿混凝土性能的影响. 金属矿山, 2014(9): 177) [18] Shi H S, Huang K S, Wu K, et al. Research advance on activa鄄 tion and mechanism of steel slag activity. Fly Ash Comprehens Utiliz, 2011(1): 48 (施惠生, 黄昆生, 吴凯, 等. 钢渣活性激发及其机理的研究 进展. 粉煤灰综合利用, 2011(1): 48) [19] Tian J, Guo H Q. Research on water contamination treatment by hydrocalumite. Environ Chem, 2013, 32(8): 1571 (天娇, 郭清海. 水铝钙石类阴离子黏土在水污染处理领域 应用的研究现状. 环境化学, 2013, 32(8): 1571) [20] Huang J L, Tang M L, Shen X D. Effects of chemical admixtures on the morphology of portlandite crystal. Concrete, 2013(8): 91 (黄金龙, 唐明亮, 沈晓冬. 杂质对氢氧化钙晶体形貌影响 的探索研究. 混凝土, 2013(8): 91) [21] Wen X, Yang Z H. Preparation and application of hydrocalumites in PVC. Plast Add, 2015(2): 27 (文星, 杨占红. 水铝钙石的制备及其在 PVC 中的应用. 塑 料助剂, 2015(2): 27) [22] Lea F M. The Chemistry of Cement and Concrete. London: Edward Arnold Ltd, 1970 [23] Grishchenko R O, Emelina A L, Makarov P Y. Thermodynamic properties and thermal behavior of Friedel蒺s salt. Thermochim Ac鄄 ta, 2013, 570: 74 [24] Segni R, Vieille L, Leroux F, et al. Hydrocalumite鄄type materi鄄 als: 1. interest in hazardous waste immobilization. J Phys Chem Solids, 2006, 67(5鄄6): 1037 [25] Houri B, Legrouri A, Barroug A, et al. Removal of chromate ions from water by anionicc clays. J Chim Phys Phys, 1999, 96 (3): 455 [26] Suryavanshi A K, Scantlebury J D, Lyon S B. Mechanism of Friedel蒺s salt formation in cements rich in tri鄄calcium aluminate. Cem Concr Res, 1996, 26(5): 717 [27] Vieille L, Rousselot I, Leroux F, et al. Hydrocalumite and its polymer derivatives. 1. Reversible thermal behavior of Friedel蒺s salt: a direct observation by means of high鄄temperature in situ powder X鄄ray diffraction. Chem Mater, 2003, 15(23): 4361 [28] Yue Y F, Wang J J, Basheer P A M, et al. Raman spectroscopic investigation of Friedel蒺s salt. Cem Concr Compos, 2018, 86: 306 [29] Birnin鄄Yauri U A, Glasser F P. Friedel蒺s salt, Ca2Al ( OH)6 (Cl,OH)·2H2O: its solid solutions and their role in chloride binding. Cem Concr Res, 1998, 28(12): 1713 [30] Qin L Q, Huang Z X, Zhang L M, et al. Flame鄄retardant mech鄄 anism of magnesium oxychloride in epoxy resin. J Wuhan Univ Technol鄄Mater Sci Ed, 2009, 24(1): 127 [31] Pane I, Hansen W. Investigation of blended cement hydration by isothermal calorimetry and thermal analysis. Cem Concr Res, 2005, 35(6): 1155 [32] Wang S P, Peng X Q, Geng J, et al. Synthesis of calcium sili鄄 cate hydrate based on steel slag with various alkalinitie. J Wuhan Univ Technol鄄Mater Sci Ed, 2014, 29(4): 789 [33] Black L, Garbev K, Beuchle G, et al. X鄄ray Photoelectron spec鄄 troscopic investigation of nanocrystalline calcium silicate hydrates synthsised by reactive milling. Cem Concr Res, 2006, 36 (6): 1023 [34] Bothe Jr J V, Brown P W. PhreeqC modeling of Friedel蒺s salt equilibria at 23 依 1 益 . Cem Concr Res, 2004, 34(6): 1057 ·1186·