工程科学学报.第43卷.第3期：332-344.2021年3月 Chinese Journal of Engineering,Vol.43,No.3:332-344,March 2021 https://doi.org/10.13374/j.issn2095-9389.2020.09.25.001;http://cje.ustb.edu.cn 石墨烯基超疏水材料制备及其应用研究进展 王鑫磊，魏世丞，朱晓莹，王博四，郭蕾，王玉江，梁义，徐滨士 陆军装甲兵学院装备再制造技术国防科技重点实验室，北京100072 ☒通信作者，E-mail:wangbobo421@163.com 摘要超疏水表面是具有独特性能的一类表面，本身就具有广泛应用前景.石墨烯材料作为理化性质出众的一类材料，由 于其高电导率、高导热系数、高比表面积、高透光率和有优异的机械性能，广泛应用于航空航天、石油化工、海洋船舶等领 域.目前，基于石墨烯材料构建超疏水表面，是超疏水表面研究中一个较新的方向.本文对超疏水表面的原理进行了概述，重 点总结归纳了石墨烯基超疏水材料制备技术的研究现状，包括表面修饰法、沉积改性法、激光诱导法、涂覆法、层层自组装 法等，简要介绍了石墨烯超疏水材料在自清洁、油水分离、防覆冰、耐腐蚀、抗菌等领域的应用，并对石墨烯超疏水材料的下 一步研究方向进行了展望 关键词石墨烯：超疏水：表面：制备：应用 分类号TB34 Research progress in the preparation and application of graphene-based superhydrophobic materials WANG Xin-lei,WEI Shi-cheng.ZHU Xiao-ying,WANG Bo,GUO Lei,WANG Yu-jiang,LIANG Yi,XU Bin-shi National Key Laboratory for Remanufacturing.Army Academy of Armored Forces,Beijing 100072.China Corresponding author,E-mail:wangbobo421@163.com ABSTRACT Superhydrophobicity in the surface is a phenomenon in which the contact angle between the water and the corresponding surface is greater than 150 and the rolling angle is less than 10.A superhydrophobic surface exhibits unique properties and has a wide range of application prospects in the field of self-cleaning,anti-corrosion,anti-icing,oil-water separation,and antibacterial agents.In addition to its unique self-cleaning properties,it can play a distinctive role in the fields of building maintenance,anti-biological corrosion in ship bodies,medical antibacterial agents,etc.At present,low-surface-energy materials commonly used to construct superhydrophobic materials mainly include alkane compounds,organosilicon compounds,and fluorine-containing compounds.However,these materials generally have problems of high production costs,large environmental pollution,and complex preparation processes,which severely restrict the industrial production and application of superhydrophobic coatings.Graphene is a two-dimensional honeycomb-structured material formed by the covalent bonding of carbon atoms through sphybrid orbitals.It is the basic unit of graphite,and it is the thinnest two-dimensional material found so far.As a class of materials with outstanding physical and chemical properties,graphene materials have always received extensive attention because of its high electrical conductivity,high thermal conductivity,high specific surface area, high light transmittance,and excellent mechanical properties.Therefore,graphene has been considered a promising material in aerospace,petrochemical,marine ships,and other fields.The construction of superhydrophobic surfaces based on graphene is a relatively new direction in the research of superhydrophobic surfaces at present.Although graphene-based superhydrophobic materials 收稿日期：2020-09-25 基金项目：国家自然科学基金资助项目(51905543.51675533和51701238)：国防科技卓越青年科学基金资助项目(2017-JCJQ-ZQ-001):“十 三五”装备预研共用技术资助项目(404010205)：中国博士后科学基金资助项目(2018M643857)石墨烯基超疏水材料制备及其应用研究进展 王鑫磊，魏世丞，朱晓莹，王    博苣，郭    蕾，王玉江，梁    义，徐滨士 陆军装甲兵学院装备再制造技术国防科技重点实验室，北京 100072 苣通信作者，E-mail：wangbobo421@163.com 摘    要    超疏水表面是具有独特性能的一类表面，本身就具有广泛应用前景. 石墨烯材料作为理化性质出众的一类材料，由 于其高电导率、高导热系数、高比表面积、高透光率和有优异的机械性能，广泛应用于航空航天、石油化工、海洋船舶等领 域. 目前，基于石墨烯材料构建超疏水表面，是超疏水表面研究中一个较新的方向. 本文对超疏水表面的原理进行了概述，重 点总结归纳了石墨烯基超疏水材料制备技术的研究现状，包括表面修饰法、沉积改性法、激光诱导法、涂覆法、层层自组装 法等，简要介绍了石墨烯超疏水材料在自清洁、油水分离、防覆冰、耐腐蚀、抗菌等领域的应用，并对石墨烯超疏水材料的下 一步研究方向进行了展望. 关键词    石墨烯；超疏水；表面；制备；应用 分类号    TB34 Research  progress  in  the  preparation  and  application  of  graphene-based superhydrophobic materials WANG Xin-lei，WEI Shi-cheng，ZHU Xiao-ying，WANG Bo苣 ，GUO Lei，WANG Yu-jiang，LIANG Yi，XU Bin-shi National Key Laboratory for Remanufacturing, Army Academy of Armored Forces, Beijing 100072, China 苣 Corresponding author, E-mail: wangbobo421@163.com ABSTRACT    Superhydrophobicity in the surface is a phenomenon in which the contact angle between the water and the corresponding surface is greater than 150° and the rolling angle is less than 10°. A superhydrophobic surface exhibits unique properties and has a wide range of application prospects in the field of self-cleaning, anti-corrosion, anti-icing, oil-water separation, and antibacterial agents. In addition to its unique self-cleaning properties, it can play a distinctive role in the fields of building maintenance, anti-biological corrosion in ship bodies, medical antibacterial agents, etc. At present, low-surface-energy materials commonly used to construct superhydrophobic materials mainly include alkane compounds, organosilicon compounds, and fluorine-containing compounds. However, these materials generally have problems of high production costs, large environmental pollution, and complex preparation processes, which severely restrict the industrial production and application of superhydrophobic coatings. Graphene is a two-dimensional honeycomb-structured material formed by the covalent bonding of carbon atoms through sp2 hybrid orbitals. It is the basic unit of graphite, and it is the thinnest two-dimensional material found so far. As a class of materials with outstanding physical and chemical properties, graphene materials have always received extensive attention because of its high electrical conductivity, high thermal conductivity, high specific surface area, high  light  transmittance,  and  excellent  mechanical  properties.  Therefore,  graphene  has  been  considered  a  promising  material  in aerospace,  petrochemical,  marine  ships,  and  other  fields.  The  construction  of  superhydrophobic  surfaces  based  on  graphene  is  a relatively new direction in the research of superhydrophobic surfaces at present. Although graphene-based superhydrophobic materials 收稿日期: 2020−09−25 基金项目: 国家自然科学基金资助项目（51905543，51675533 和 51701238）；国防科技卓越青年科学基金资助项目（2017-JCJQ-ZQ-001）；“十 三五”装备预研共用技术资助项目（404010205）；中国博士后科学基金资助项目（2018M643857） 工程科学学报，第 43 卷，第 3 期：332−344，2021 年 3 月 Chinese Journal of Engineering, Vol. 43, No. 3: 332−344, March 2021 https://doi.org/10.13374/j.issn2095-9389.2020.09.25.001; http://cje.ustb.edu.cn