习题 15.1写出正丁酸与下列试剂反应的主要产物。 (1)NaHCOs (2)S0C1,△ (3)(CHC0)0,△ (4)C,HOH,少量浓H,SO,△ (5)NH,△ (6)LiAIHa. F醚然后H,0 (7)BH-THF,然后H,O (8)HgO,Br2,△ (9)催化量P,C,△ (10)PBra,△ (11)P,05.△ (12)Pb (OCOCHs)4.KBr.A 15.2写出荣甲酸与下列试剂反应的主要产物，不发生反应的，则注明无反应 (1)NaOH.HO (2)Na CO3.H2O (3)NaHCO3,H2O (4)Ca (OH)2,H2O (5)NH·H,0 (6)NH,高温 (7)CH,CH,CH,OH,少量浓H,SO,△ (8)(CH,C0)0,△ (9)P,Os,△ (10)LiA1H,干醚，然后H:O1 (11)NaBHa,CHsOH (12)热KMnO4溶液 (13)PB,△ (14)PC15,△ (15)s0C,△ (16)Br2,Fe,△ (17)浓HNO-浓HSO4,△ (18)HS04·S0,△ (19)CH-CH-CI AICh (20)CH.C0C1.A1C1 15.3写出丙酰氯与下列试剂反应的主要产物。 (1)H0,△ (2)CH,OH,△ (3)CH,OH,△ (4)CHNH2,△ (5)CH.NH..A (6)H..Pd (7)H,Pd/BaSO,S-喹 (8)2CH,CH.MgBr,干醚，然后HO (9)(C,H)Cd (10)(CH:CH,CH,)CuLi, (1I)CH,COONa,△ (12)1f2NaO2 15.4写出丁二酸酐与下列试剂反应的主要产物 (1)H0.A (2)CHOH,浓HSO4△ (3)NH,然后H+ (4)NH,300℃ (5)n-C,HoMgBr,干醚，低温，然后HO (6)2 C.HsMgI,.干醚，然后H0 15.5写出丙酸乙酯与下列试剂反应的主要产物， (1)H0,H,△ (2)H,0,H0,△，然后H (3)过量CH,OH,浓HSO4,△ (4)CH,CH2NH2,△ (5)NH,OH·HC1 (6)H,CwCr催化剂，△，加压 (7)LiAIH,乙醚，然后H,O (8)Na.CH,OH.△ (9)CH:Mgl,干张，然后HO (10)n-C,HLi,然后HO (1I)HCOOC2H5,CH,ONa,CHOH,然后H,0 (12)500C (13)C2H;OCOOC2H,C.HsONa,C.H.OH,然后HO 14)CH,COCH,NaH,然后H0 (15)(COOC2Hs)2,C:HsONa,C.HsOH,然后HO (16)CH,CO0CH,CH,ONa,C2H,OH.然后HO 15.6写出苯甲酰胺与下列试剂反应的主要产物。
15.1 ￾✂✁☎✄✝✆✟✞✡✠✟☛✝☞✍✌✡✎✑✏✍✒✔✓☎✕✗✖✗✘✗✙✛✚ ✜ 1 ✢ NaHCO3 ✜ 2 ✢ SOCl2 ✣✥✤ ✜ 3 ✢ ✜ CH3CO ✢ 2O ✣✦✤ ✜ 4 ✢ C2H5OH ✣✥✧✍★✝✩ H2SO4 ✣✥✤ ✜ 5 ✢ NH3 ✣✥✤ ✜ 6 ✢ LiAlH4 ✣☎✪✗✫✔✣☎✬✝✭ H3O + ✜ 7 ✢ B2H6-THF ✣✮✬✝✭ H2O ✜ 8 ✢ HgO ✣ Br2 ✣✦✤ ✜ 9 ✢✰✯✡✱★ P ✣ Cl2 ✣✥✤ ✜ 10 ✢ PBr3 ✣✥✤ ✜ 11 ✢ P2O5 ✣✥✤ ✜ 12 ✢ Pb ✜ OCOCH3 ✢ 4 ✣ KBr ✣✦✤ 15.2 ￾✂✁✳✲✵✴✶✞✡✠✟☛✝☞✍✌✡✎✑✏✍✒✔✓☎✕✗✖✗✘✗✙ ✣✮✷✝✸✝✹✏✍✒✔✓ ✣✮✺✟✻✽✼✿✾✏✍✒✽✚ ✜ 1 ✢ NaOH ✣ H2O ✜ 2 ✢ Na2CO3 ✣ H2O ✜ 3 ✢ NaHCO3 ✣ H2O ✜ 4 ✢ Ca ✜ OH ✢ 2 ✣ H2O ✜ 5 ✢ NH3 ❀ H2O ✜ 6 ✢ NH3 ✣✦❁✥❂ ✜ 7 ✢ CH3CH2CH2OH ✣✮✧✍★✝✩ H2SO4 ✣✥✤ ✜ 8 ✢ ✜ CH3CO ✢ 2O ✣✦✤ ✜ 9 ✢ P2O5 ✣✦✤ ✜ 10 ✢ LiAlH4 ✣☎✪✗✫✔✣☎✬✝✭ H3O + ✜ 11 ✢ NaBH4 ✣ C2H5OH ✜ 12 ✢❄❃ KMnO4 ❅✗❆ ✜ 13 ✢ PBr3 ✣✦✤ ✜ 14 ✢ PCl5 ✣✦✤ ✜ 15 ✢ SOCl2 ✣✥✤ ✜ 16 ✢ Br2 ✣ Fe ✣✦✤ ✜ 17 ✢ ✩ HNO3-✩ H2SO4 ✣✦✤ ✜ 18 ✢ H2SO4 ❀ SO3 ✣✥✤ ✜ 19 ✢ CH3CH2Cl ✣ AlCl3 ✜ 20 ✢ CH3COCl ✣ AlCl3 15.3 ￾✂✁☎❇✗❈✝❉✝✠✟☛✝☞✍✌✡✎✑✏✍✒✔✓☎✕✗✖✗✘✗✙✛✚ ✜ 1 ✢ H2O ✣✥✤ ✜ 2 ✢ C2H5OH ✣✥✤ ✜ 3 ✢ C6H5OH ✣✥✤ ✜ 4 ✢ CH3NH2 ✣✥✤ ✜ 5 ✢ C6H5NH2 ✣✥✤ ✜ 6 ✢ H2 ✣ Pd ✜ 7 ✢ H2 ✣ Pd/BaSO4 ✣ S-❊✗❋ ✜ 8 ✢ 2CH3CH2MgBr ✣✳✪✝✫✂✣✮✬✗✭ H3O + ✜ 9 ✢ ✜ C2H5 ✢ 2Cd ✜ 10 ✢ ✜ CH3CH2CH2 ✢ 2CuLi ✣✝●☎✫ ✜ 11 ✢ CH3COONa ✣✦✤ ✜ 12 ✢ 1/2 Na2O2 15.4 ￾✂✁☎✆✝❍✟✞✝■✝✠✗☛✗☞✍✌✑✎✑✏✦✒✽✓✳✕✝✖✟✘✝✙✽✚ ✜ 1 ✢ H2O ✣✥✤ ✜ 2 ✢ C2H5OH ✣✳✩ H2SO4 ✤ ✜ 3 ✢ NH3 ✣☎✬✝✭ H+ ✜ 4 ✢ NH3 ✣ 300❏ ✜ 5 ✢ n-C4H9MgBr ✣☎✪✗✫✂✣☎❑✗❂✔✣✮✬✗✭ H3O + ✜ 6 ✢ 2C2H5MgI ✣☎✪✗✫✔✣☎✬✝✭ H3O + 15.5 ￾✂✁☎❇✗✞●✮▲✠✗☛✗☞✍✌✑✎✑✏✦✒✽✓✳✕✝✖✟✘✝✙✽✚ ✜ 1 ✢ H2O ✣ H + ✣✦✤ ✜ 2 ✢ H2O ✣ HO - ✣✥✤ ✣☎✬✝✭ H + ✜ 3 ✢❄▼★ CH3OH ✣☎✩ H2SO4 ✣✥✤ ✜ 4 ✢ CH3CH2NH2 ✣✥✤ ✜ 5 ✢ NH2OH ❀ HCl ✜ 6 ✢ H2 ✣ Cu/Cr ✯✝✱✎ ✣✦✤◆✣✮❖✝P ✜ 7 ✢ LiAlH4 ✣✗●☎✫✂✣✮✬✗✭ H3O + ✜ 8 ✢ Na ✣ C2H5OH ✣✦✤ ✜ 9 ✢ CH3MgI ✣☎✪✝✫✂✣✮✬✗✭ H3O + ✜ 10 ✢ n-C4H9Li ✣✮✬✝✭ H3O + ✜ 11 ✢ HCOOC2H5 ✣ C2H5ONa ✣ C2H5OH ✣✮✬✗✭ H3O + ✜ 12 ✢ 500❏ ✜ 13 ✢ C2H5OCOOC2H5 ✣ C2H5ONa ✣ C2H5OH ✣✮✬✗✭ H3O + ✜ 14 ✢ CH3COCH3 ✣ NaH ✣✮✬✗✭ H3O + ✜ 15 ✢ ✜ COOC2H5 ✢ 2 ✣ C2H5ONa ✣ C2H5OH ✣☎✬✝✭ H3O + ✜ 16 ✢ C6H5COOC2H5 ✣ C2H5ONa ✣ C2H5OH ✣☎✬✝✭ H3O + 15.6 ￾✂✁✳✲✵✴✶❈✗◗✡✠✗☛✗☞✍✌✑✎✑✏✦✒✽✓✳✕✝✖✟✘✝✙✽✚