3期 闫少羽等:黄皮属植物生物碱的研究进展 Continued Name RS RRR References clausamineg OMe COOMe CH=CHC (OH)(CH3) 55 2172dihydroxy232formyL212(32 DMA OH CHO OH met hy 2 butenyl)carbazole 62metho xyheptaphylline DMA OH CHO OMe 2 72metho xy heptap hyaline DMA OH CHO OMe DH CHO heptazine DMA OH CHO CHCH(OH) OH CHO C(OH)(CH3)2 clausing CHO OMe OH CHCH(OH) OH CHO O C(CH3)2OH 2DMA OH CHO DMA①:H2CH=C(CH3)2 2DMA:-CH2CH=C(CH3)CHCH CH=C(CH3) 吡喃或去氢吡喃并咔唑类 R2 64 grinimihine:R=R2=CH,,R=R=H 65 murrayacine: R=CH3, R2=CHO, R=R=H 66 mupamine: R=R'=CH,, R=H, R=OMe 「29 67 mahanimibine: R=CH, CH,CH=C(CH32, R=CH,, R=R=H [6,11] 69 clauszoline-G: R=CH,, R'=CHO, R=H, R=OH [12] 70 heptazolicine: R=R=R=H, R=OH 6」 71 clausine-W:R=OH. R=trans-OH, R=OH, R=H 72 clausine-T: R=OH. R2=H, R=OH, R-H 73 clauszoline-E:R=OH, R=R=H. R-OH 74 clauszoline-A: R=CH,CH=C(CH ) 2, R=OH, R=CHo [12] 77 clausamine-A R=H(13, 17 75 clauszoline-B R=H. R2OH. R=CHO [12] 78 clausamine-B R=CH, [13, I7 76 clauszoline-H: R=H. R2-0CH, R=CH 79 clausevatine-D R=R2=H 7,18 80 clausevatine-E: R'=H, R'=cis_OH [18] 0 81 clausevatine-F: R=H, R=trans-OH [18) 82 clausamine-C: R=OCH,, R=H [13, 17] 83 clausevatine-G [18 其他咔唑类 CHO 85 clausenalene [20 86 furoclausine-A (21] o1995-2005 Tsinghua Tongfang Optical Disc Co, Ltd. Al rights reserved.Continued Table 1 No. Name R 1 R 2 R 3 R 4 R 5 R 6 R 7 R 8 References 54 clausamine2G OMe COOMe CH CHC (OH) (CH3 ) 2 13 55 2172dihydroxy232formyl212(3′2 methyl22′2butenyl) carbazole DMA ① OH CHO OH 14 56 62methoxyheptaphylline DMA ① OH CHO OMe 2 57 72methoxyheptaphylline DMA ① OH CHO OMe 6 58 clausine2B OH CHO OMe OMe 5 ,7 59 heptazoline DMA ① OH CHO OH 5 ,6 60 clauszoline2D CH2CH(OH) C(OH) (CH3 ) 2 OH CHO OH 12 61 clausine2J OH CHO OMe OH 11 62 clausine2U CH2CH(OH) C(CH3 ) 2OH OH CHO OH 7 63 clauszoline2F 2DMA ② OH CHO OH 6 ,12 DMA ①: —CH2CH C(CH3 ) 2 2DMA ②: —CH2CH C(CH3 ) CH2CH2CH C(CH3 ) 2 吡喃或去氢吡喃并咔唑类 : 第 3 期 闫少羽等 :黄皮属植物生物碱的研究进展 181 © 1995-2005 Tsinghua Tongfang Optical Disc Co., Ltd. All rights reserved