APPENDIX 1 TABLE B Selected Physical erties of Representative Organic Halogen Compounds Alkyl Halides Compound Structural Boiling point, C(1 atm Density,g/mL(20°g formula Fluoride Chloride bromide lodide chloride bromide lodide Halomethane CHaX 3 2458 38 1.4601933 0.8901.3531.739 CH3)2 CHX 913101.714 2CH2X 71.2761.615 2-Halobutane 0.873 1.26 1.597 1-Halo-2-methylpropane ( CH3)2CHCH2X 911210.8781.2641.603 2-Halo-2-methylpropane ( CH3)3CX 184 0.847 1.220 CH3(CH2)3CH2X 1.2161.516 CH3(CH2)4CH2x 0.879 1751439 1-Halooctane CH3(CH2)6CH2X 143 0.892 1.1181.336 Halocyclopentane 138 1.3881.694 Halocyclohexane 14 167 1920.9771.3241.626 Aryl Halides Halogen substituent (X)* Fluorine chlorine Bromin -45 132 .Cs HaX2 7-C5H4X2 173 1,3,5-C6H3X 271 CsX 230 327 *All boiling points and melting points cited are in degrees Celsius. Forward Main Menu TOC Study Guide Toc Student OLCMHHE WebsiteAPPENDIX 1 A-3 Boiling point, °C (1 atm) Density, g/mL (20°C) Fluoride 78 32 3 11 16 65 92 143 Chloride 24 12 47 35 78 68 68 51 108 134 183 114 142 Bromide 3 38 71 59 102 91 91 73 129 155 202 138 167 Iodide 42 72 103 90 130 120 121 99 157 180 226 166 192 Chloride 0.903 0.890 0.859 0.887 0.873 0.878 0.847 0.884 0.879 0.892 1.005 0.977 Bromide 1.460 1.353 1.310 1.276 1.261 1.264 1.220 1.216 1.175 1.118 1.388 1.324 Iodide 2.279 1.933 1.739 1.714 1.615 1.597 1.603 1.570 1.516 1.439 1.336 1.626 1.694 Structural formula CH3X CH3CH2X CH3CH2CH2X (CH3)2CHX CH3CH2CH2CH2X CH3CHCH2CH3 (CH3)2CHCH2X (CH3)3CX CH3(CH2)3CH2X CH3(CH2)4CH2X CH3(CH2)6CH2X X X W X Compound name Alkyl Halides Halomethane Haloethane 1-Halopropane 2-Halopropane 1-Halobutane 2-Halobutane 1-Halo-2-methylpropane 2-Halo-2-methylpropane 1-Halopentane 1-Halohexane 1-Halooctane Halocyclopentane Halocyclohexane Compound Aryl Halides C6H5X o-C6H4X2 m-C6H4X2 p-C6H4X2 1,3,5-C6H3X3 C6X6 Halogen substituent (X)* Fluorine Chlorine Bromine Iodine mp 41 34 59 13 5 5 bp 85 91 83 89 76 80 mp 45 17 25 53 63 230 bp 132 180 173 174 208 322 mp 31 7 7 87 121 327 bp 156 225 218 218 271 mp 31 27 35 129 184 350 bp 188 286 285 285 *All boiling points and melting points cited are in degrees Celsius. TABLE B Selected Physical Properties of Representative Organic Halogen Compounds