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KmnO4, H CO,+Ho+ B2h6 H2O2, OH 10) 3.如何实现下列转变?用方程式表示 (I)CH3 CHCH3- CH3 CH2CH2BI (2)CH, CHCH CHz CH, CH,OH (3)CH3CH=CH2 CH,CHCH2 答案 HaSO HBr ()CH3CHCH CH.CHB ROOR OH KOH (2)CH3 CHCH Etoh CH3 CH2CH,OH Br Br2/CCI (3)CH3CH=CH2 CH2CHCH 500℃ 4.化合物A、B、C均为庚烯的异构体。A、B、C经溴氧化,锌粉还原水解分别得到CH3CHO CH3CH CH2CH2CHO, H3 CH3 H3CH2C-C-CH3 CH;CHO H3CH2C-C-CH2CH3 试推断A、B、C的构造式或构型式。(7) KmnO4,H+ △ CO2+H2O+ O (8) B2H6 B 3 H2O2,OH￾HO (9) Br Br HBr Br -Br (10) O OH O O 3. 如何实现下列转变?用方程式表示。 CH3CHCH3 OH CH3CH2CH2Br CH3CHCH3 Br CH3CH2CH2OH CH3CH CH2 CH2CHCH2 Cl Br Br (1) (2) (3) 答案: CH3CHCH3 OH CH3CH2CH2Br CH3CHCH3 Br CH3CH2CH2OH CH3CH CH2 CH2CHCH2 Cl Br Br (1) (2) (3) H2SO4 △ HBr ROOR KOH EtOH 1) B2H6 2) H2O2 OH￾Cl2 500℃ Br2/CCl4 4. 化合物A、B、C均为庚烯的异构体。A、B、C经溴氧化,锌粉还原水解分别得到CH3CHO CH3CH2CH2CH2CHO H3C C CH3 O ; H3CH2C C CH3 O CH3CHO H3CH2C C CH2CH3 O ; ; ; . 试推断 A、B、C 的构造式或构型式
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