鞠靓辰等：CaF,-SiO2型硅传感器辅助电极的制备及其定硅性能 ·483· 2008,50(26):575 量.北京科技大学学报，1993,15(6)：643) [13]Iwase M.Developments in zirconia sensors during the 1980s:la- [16]Xu Y S,Zou Y X,Liu F L.A study of the equilibrium between boratory and in-plant applications in iron and steelmaking//IN- HF-H2O gas and slags of the CaO-CaF2 and Cao-SiO2-CaF2 FAC0N6,1992:49 system.Acta Metall Sin,1964,7(1)24 4]Iwase M.Rapid determination of silicon activities in hot metal by (徐元森，邹元媛，刘辅连.Ca0-CaF2和Ca0-SiO2-Caf2 means of solid state electrochemical sensors equipped with an 系熔渣和HF-H,0气体间的平衡研究.金属学报，1964,7 auxiliary electrode.Scand J Metall,1988,17 (2):50 (1):24) [15]Huang K Q,Wu W J,Liu QG.A new electrochemical sensor [17]Qi Q J,Liu JZ,Qin K F,et al.Stability of CaF2 at high tem- for rapid determination of silicon content in carbon saturated iron. perature.Environ Sci,2002,23(3)111 J Univ Sci Technol Beijing,1993,15(6):643 (齐庆杰，刘建忠，芩可法，等.CF2高温分解特性试验研 (黄克勒，吴卫江，刘庆国.电化学法快速测定铁水中的硅 究.环境科学，2002,23(3)：111)鞠靓辰等: CaF2 --SiO2型硅传感器辅助电极的制备及其定硅性能 2008，50( 2-6) : 575 ［13］ Iwase M． Developments in zirconia sensors during the 1980＇s: la￾boratory and in-plant applications in iron and steelmaking / / IN￾FACON 6，1992: 49 ［14］ Iwase M． Ｒapid determination of silicon activities in hot metal by means of solid state electrochemical sensors equipped with an auxiliary electrode． Scand J Metall，1988，17( 2) : 50 ［15］ Huang K Q，Wu W J，Liu Q G． A new electrochemical sensor for rapid determination of silicon content in carbon saturated iron． J Univ Sci Technol Beijing，1993，15( 6) : 643 ( 黄克勤，吴卫江，刘庆国． 电化学法快速测定铁水中的硅 量． 北京科技大学学报，1993，15( 6) : 643) ［16］ Xu Y S，Zou Y X，Liu F L． A study of the equilibrium between HF--H2O gas and slags of the CaO--CaF2 and CaO--SiO2 --CaF2 system． Acta Metall Sin，1964，7( 1) : 24 ( 徐元森，邹元燨，刘辅连． CaO--CaF2 和 CaO--SiO2 --CaF2 系熔渣和 HF--H2O 气体间的平衡研究． 金属学报，1964，7 ( 1) : 24) ［17］ Qi Q J，Liu J Z，Qin K F，et al． Stability of CaF2 at high tem￾perature． Environ Sci，2002，23( 3) : 111 ( 齐庆杰，刘建忠，芩可法，等． CaF2 高温分解特性试验研 究． 环境科学，2002，23( 3) : 111) · 384 ·