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·1834 工程科学学报,第39卷,第12期 212(4):903 4结论 [12]Chen H,Jie J C,Fu Y,et al.Grain refinement of pure alumi- (1)经表面脉冲电磁场处理后的凝固组织由晶粒 num by direct current pulsed magnetic field and inoculation.T Nonferr Met Soc China,2014,24(5)1295 粗大的玫瑰状结构转变为晶粒细小且圆整的球状结 [13]Ferreira P J,Liu H B,Vander Sande J B.A model for the tex- 构,铸锭心部及边部晶粒尺寸分别下降了22.7%和 ture development of high-Te superconductors under an elevated 14.2%,强度及塑性均有提高. magnetic field.J Mater Res,1999,14(7):2751 (2)电磁能降低了均匀形核所需的临界吉布斯自 14] Gong YY,Luo J,Jing J X,et al.Structure refinement of pure aluminum by pulse magneto-oscillation.Mater Sci Eng A,2008, 由能△G,使体系更容易形核.磁能渗入有利于过冷 497(12):147 度较小的熔体心部区域克服剩余临界形核界面能. [15]Chen Y S,Zhang L,Liu W C,et al.Preparation of Mg-Nd-Zn- (3)对脉冲电磁场下初生一A]的运动情况进行分 (Zr)alloys semisolid slury by electromagnetic stirring.Mater De- 析,电磁脉冲导致晶核的势能增加,促使初生α一A1颗粒 gn,2016,95:398 [16]Li C J.Investigation of Nucleation and Growth of Metals in High 优先到达稳定位置,并最终决定其在基体中的分布状态. Magnetic Fields by Differential Thermal Analysis [Dissertation] 参考文献 Shanghai:Shanghai University,2011 (李传军.磁场下金属凝固过程形核与生长的差热分析研究 1]Qi JC,Wang JZ,Du H L,et al.Heredity of aluminum melt by [学位论文].上海:上海大学,2011) electric pulse modification (II).J Iron Steel Res Int,2007,14 [17]Terzieff P,Ltick R.Magnetic investigations in liquid Al-In.J (5):76 4 lloy Compd,2003,360(12):205 2]Dobron P,Chmelik F,Yi S B,et al.Grain size effects on de- [18]Gale W F,Totemeier T C.Smithells Metals Reference Book.8th formation twinning in an extruded magnesium alloy tested in com- Ed.New York:Butterworth-Heinemann,2004 pression.Scripta Mater,2011,65(5):424 19] Gundiiz M,Hunt J D.Solid-iquid surface energy in the Al-Mg 3]Jain A,Duygulu O,Brown D W,et al.Grain size effects on the system.Acta Mater,1989,37(7):1839 tensile properties and deformation mechanisms of a magnesium al- 20] Radjai A,Miwa K,Nishio T.An investigation of the effects loy,AZ31B,sheet.Mater Sci Eng A,2008,486(12)545 caused by electromagnetic vibrations in a hypereutectic Al-Si al- 4]Ghaderi A,Bamett M R.Sensitivity of deformation twinning to loy melt.Metall Mater Trans A,1998,29(5):1477 grain size in titanium and magnesium.Acta Mater,2011,59 1]Jin F W.Influence of A Gradient High Magnetic Field on Solidifi- (20):7824 cation of Al-Si Hypereutectic Alloys [Dissertation].Shanghai: [5]Li N L.Research on Influence of Initial Microstructure and Deform- Shanghai University,2007 ation Conditions on Microstructure and Texture Evolution of Hot-Ex- (晋芳伟.梯度强磁场对铝硅过共品合金凝固的影响[学位 truded AZ31 Magnesium Alloy Dissertation ]Chongqing: 论文].上海:上海大学,2007) Chongqing University,2013 22] Motokawa M,Mogi I,Tagami M,et al.Magnetic levitation experi- (李娜丽.初始组织及变形条件对A☑31镁合金热挤压组织和 ments in Tohoku University.Physica B,1998,256-258:618 织构演变的影响研究[学位论文].重庆:重庆大学,2013) [23]Takagi T,Iwai K,Asai S.Solidified structure of Al alloys by a Qian M,Ramirez A,Das A.Ultrasonic refinement of magnesium local imposition of an electromagnetic oscillationg force.IS//Int, by cavitation:clarifying the role of wall crystals.J Cryst Growth, 2003,43(6):842 2009,311(14):3708 D4]Lou C S.Control of the Motion Behaviors of Particles in Metallic Nakada M,Shiohara Y,Flemings M C.Modification ofsolidifica- Melt by High Magnetic Fields and the Relevant Morphological tion structures by pulse electric discharging.IS//Int,1990,30 Erolution [Dissertation].Shenyang:Northeastem University, (1):27 2010 [8]Spencer D B,Mehrabian R,Flemings M C.Rheological behavior (娄长胜.强磁场下合金熔体中颗粒运动行为控制及其对凝 of Sn-5 pct Pb in the crystallization range.Metall Trans,1972,3 固组织演化的影响[学位论文].沈阳:东北大学,2010) (7):1925 25] Xu Z M,Li T X,Zhou Y H.An in situ surface composite pro- 9]Yin Z X,Gong Y Y,Li B,et al.Refining of pure aluminum cast duced by electromagnetic force.Mater Res Bull,2000,35(14- structure by surface pulsed magneto-oscillation.J Mater Process 15):2331 Teh,2012,212(12):2629 [26]Yasuda H,Ohnaka I,Kawakami 0,et al.Effect of magnetic [10]Zhang Y H,Zhong H G,Zhai Q J.Research progress of grain field on solidification in Cu-Pb monotectic alloys.IS//Int, refinement and homogenization of solidified metal alloys driven by 2003,43(6):942 pulsed electromagnetic fields.J Iron Steel Res,2017,29(4): [27]Lehmann P,Moreau R,Camel D,et al.Modification of inter- 249 dendritic convection in directional solidification by a uniform (张云虎,仲红刚,翟启杰.脉冲电磁场凝固组织细化和均 magnetic field.Acta Mater,1998,46(11):4067 质化技术研究与应用进展.钢铁研究学报,2017,29(4): [28]Sun Z,Guo M,Verhaeghe F,et al.Magnetic interaction between 249) two non-magnetic particles migrating in a conductive fluid in- [11]Li Y J,Tao WZ,Yang Y S.Grain refinement of Al-Cu alloy in duced by a strong magnetic field-n analytical approach.Prog low voltage pulsed magnetic field.J Mater Process Tech,2012, Electromagn Res,2010.103:1工程科学学报,第 39 卷,第 12 期 4 结论 ( 1) 经表面脉冲电磁场处理后的凝固组织由晶粒 粗大的玫瑰状结构转变为晶粒细小且圆整的球状结 构,铸锭心部及边部晶粒尺寸分别下降了 22. 7% 和 14. 2% ,强度及塑性均有提高. ( 2) 电磁能降低了均匀形核所需的临界吉布斯自 由能 ΔG* m ,使体系更容易形核. 磁能渗入有利于过冷 度较小的熔体心部区域克服剩余临界形核界面能. ( 3) 对脉冲电磁场下初生 α--Al 的运动情况进行分 析,电磁脉冲导致晶核的势能增加,促使初生 α--Al 颗粒 优先到达稳定位置,并最终决定其在基体中的分布状态. 参 考 文 献 [1] Qi J G,Wang J Z,Du H L,et al. Heredity of aluminum melt by electric pulse modification ( II) . J Iron Steel Res Int,2007,14 ( 5) : 76 [2] Dobroň P,Chmelík F,Yi S B,et al. Grain size effects on de￾formation twinning in an extruded magnesium alloy tested in com￾pression. Scripta Mater,2011,65( 5) : 424 [3] Jain A,Duygulu O,Brown D W,et al. Grain size effects on the tensile properties and deformation mechanisms of a magnesium al￾loy,AZ31B,sheet. Mater Sci Eng A,2008,486( 1-2) : 545 [4] Ghaderi A,Barnett M R. Sensitivity of deformation twinning to grain size in titanium and magnesium. Acta Mater,2011,59 ( 20) : 7824 [5] Li N L. Research on Influence of Initial Microstructure and Deform￾ation Conditions on Microstructure and Texture Evolution of Hot-Ex￾truded AZ31 Magnesium Alloy [Dissertation]. Chongqing: Chongqing University,2013 ( 李娜丽. 初始组织及变形条件对 AZ31 镁合金热挤压组织和 织构演变的影响研究[学位论文]. 重庆: 重庆大学,2013) [6] Qian M,Ramirez A,Das A. Ultrasonic refinement of magnesium by cavitation: clarifying the role of wall crystals. J Cryst Growth, 2009,311( 14) : 3708 [7] Nakada M,Shiohara Y,Flemings M C. Modification ofsolidifica￾tion structures by pulse electric discharging. ISIJ Int,1990,30 ( 1) : 27 [8] Spencer D B,Mehrabian R,Flemings M C. Rheological behavior of Sn-15 pct Pb in the crystallization range. Metall Trans,1972,3 ( 7) : 1925 [9] Yin Z X,Gong Y Y,Li B,et al. Refining of pure aluminum cast structure by surface pulsed magneto-oscillation. J Mater Process Tech,2012,212( 12) : 2629 [10] Zhang Y H,Zhong H G,Zhai Q J. Research progress of grain refinement and homogenization of solidified metal alloys driven by pulsed electromagnetic fields. J Iron Steel Res,2017,29 ( 4) : 249 ( 张云虎,仲红刚,翟启杰. 脉冲电磁场凝固组织细化和均 质化技术研究与应用进展. 钢铁研究学报,2017,29 ( 4) : 249) [11] Li Y J,Tao W Z,Yang Y S. Grain refinement of Al--Cu alloy in low voltage pulsed magnetic field. J Mater Process Tech,2012, 212( 4) : 903 [12] Chen H,Jie J C,Fu Y,et al. Grain refinement of pure alumi￾num by direct current pulsed magnetic field and inoculation. T Nonferr Met Soc China,2014,24( 5) : 1295 [13] Ferreira P J,Liu H B,Vander Sande J B. A model for the tex￾ture development of high-Tc superconductors under an elevated magnetic field. J Mater Res,1999,14( 7) : 2751 [14] Gong Y Y,Luo J,Jing J X,et al. Structure refinement of pure aluminum by pulse magneto-oscillation. Mater Sci Eng A,2008, 497( 1-2) : 147 [15] Chen Y S,Zhang L,Liu W C,et al. Preparation of Mg--Nd--Zn-- ( Zr) alloys semisolid slurry by electromagnetic stirring. Mater De￾sign,2016,95: 398 [16] Li C J. Investigation of Nucleation and Growth of Metals in High Magnetic Fields by Differential Thermal Analysis [Dissertation]. Shanghai: Shanghai University,2011 ( 李传军. 磁场下金属凝固过程形核与生长的差热分析研究 [学位论文]. 上海: 上海大学,2011) [17] Terzieff P,Lück R. Magnetic investigations in liquid Al--In. J Alloy Compd,2003,360( 1-2) : 205 [18] Gale W F,Totemeier T C. Smithells Metals Reference Book. 8th Ed. New York: Butterworth-Heinemann,2004 [19] Gündüz M,Hunt J D. Solid-liquid surface energy in the Al--Mg system. Acta Mater,1989,37( 7) : 1839 [20] Radjai A,Miwa K,Nishio T. An investigation of the effects caused by electromagnetic vibrations in a hypereutectic Al--Si al￾loy melt. Metall Mater Trans A,1998,29( 5) : 1477 [21] Jin F W. Influence of A Gradient High Magnetic Field on Solidifi￾cation of Al--Si Hypereutectic Alloys [Dissertation]. Shanghai: Shanghai University,2007 ( 晋芳伟. 梯度强磁场对铝硅过共晶合金凝固的影响[学位 论文]. 上海: 上海大学,2007) [22] Motokawa M,Mogi I,Tagami M,et al. Magnetic levitation experi￾ments in Tohoku University. Physica B,1998,256-258: 618 [23] Takagi T,Iwai K,Asai S. Solidified structure of Al alloys by a local imposition of an electromagnetic oscillationg force. ISIJ Int, 2003,43( 6) : 842 [24] Lou C S. Control of the Motion Behaviors of Particles in Metallic Melt by High Magnetic Fields and the Relevant Morphological Evolution [Dissertation]. Shenyang: Northeastern University, 2010 ( 娄长胜. 强磁场下合金熔体中颗粒运动行为控制及其对凝 固组织演化的影响[学位论文]. 沈阳: 东北大学,2010) [25] Xu Z M,Li T X,Zhou Y H. An in situ surface composite pro￾duced by electromagnetic force. Mater Res Bull,2000,35 ( 14- 15) : 2331 [26] Yasuda H,Ohnaka I,Kawakami O,et al. Effect of magnetic field on solidification in Cu-- Pb monotectic alloys. ISIJ Int, 2003,43( 6) : 942 [27] Lehmann P,Moreau R,Camel D,et al. Modification of inter￾dendritic convection in directional solidification by a uniform magnetic field. Acta Mater,1998,46( 11) : 4067 [28] Sun Z,Guo M,Verhaeghe F,et al. Magnetic interaction between two non-magnetic particles migrating in a conductive fluid in￾duced by a strong magnetic field-an analytical approach. Prog Electromagn Res,2010,103: 1 · 4381 ·
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