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江羽等:高温相变储能微胶囊研究进展 ·117· 1991:92 and Its Preparation Method:China Patent,CN201810202184.8. [29]ShiTJ,Hu P.Wang JT.Preparation of polyurea microcapsules 2018-08-10 containing phase change materials using microfluidics.Chem (张美杰,韩藏娟,顾华志,等.致密氧化铝壳层高温相变蓄热微 Select,,2020,5(7):2342 胶囊及其制备方法:中国专利,CN201810202184.8.2018-08-10) [30]Feng L,Dong S P,Zhou H.n-Dodecanol nanocapsules with [43]Zhang F,Lin J,Yang X,et al.The Invention Relates to a Method supramolecular lock shell layer for thermal energy storage.Chem for Preparing Metal Coated High-Temperature Phase Change EmgJ2020,389:124483 Thermal Storage Microcapsule and the Thermal Storage Micro- [31]Xu R,Xia X M,Wang W,et al.Infrared camouflage fabric capsule Obtained Therefrom:China Patent,CN201811197058.4. prepared by paraffin phase change microcapsule with Good 2019-02-12 thermal insulting properties.Colloids Surf,2020,591:124591 (张锋,林俊,杨旭,等,一种制备金属包壳高温相变储热微胶囊 [32]Sahan N,Paksoy H.Designing behenic acid microcapsules as 的方法以及由此得到的储热微胶囊:中国专利,CN201811197058. novel phase change material for thermal energy storage 4.2019-02-12) applications at medium temperature.InJ Energy Res,2020, [44]Yang Z.Z,Zhang X.Wang Q.Metal and Alloy Phase Change 44(5):3922 Energy Storage Microcapsules and Their Preparation Methods. [33]Wang X G,Chen Z F,Xu W,et al.Capric acid phase change China Patent,.CN201710129236.9.2017-07-04 microcapsules modified with graphene oxide for energy storage./ (杨振忠,张行,王倩,金属及合金相变储能微胶囊及其制备方 Mater Sci,2019,54(24):14834 法:中国专利,CN201710129236.9.2017-07-04) [34]Zhang H Z,Wang X D,Wu D Z.Silica encapsulation of n- [45]Li J F,Lu W,Luo Z P,et al.Thermal stability of sodium nitrate octadecane via sol-gel process:a novel microencapsulated phase- microcapsules for high-temperature thermal energy storage.Sol change material with enhanced thermal conductivity and Energy Mater Sol Cells,2017,171:106 performance.J Colloid Interf Sci,2010,343(1):246 [46]Takai-Yamashita C,Shinkai I,Fuji M,et al.Effect of water [35]Liu Z F,Chen Z H,Yu F.Preparation and characterization of soluble polymers on formation of Na2SO4 contained SiOz microencapsulated phase change materials containing inorganic microcapsules by W/O emulsion for latent heat storage.Adv hydrated salt with silica shell for thermal energy storage.Sol Powder Technol,2016,27(5):2032 Energy Mater Sol Cells,2019,200:art.No.110004 [47]Li J F,Lu W,Luo Z P,et al.Synthesis and thermal properties of [36]He F.Wang X D.Wu DZ.New approach for sol-gel synthesis of novel sodium nitrate microcapsules for high-temperature thermal microencapsulated n-octadecane phase change material with silica energy storage.Sol Energy Mater Sol Cells,2017,159:440 wall using sodium silicate precursor.Energy,2014,67:223 [48]Li J F,Luo Z P,Sun LL.The Invention Relates to an Inorganic [37]Li F N,Wang X D,Wu D Z.Fabrication of multifunctional Salt High-Temperature Phase Change Microcapsule and A microcapsules containing n-eicosane core and zinc oxide shell for Preparation Method Thereof:China Patent,CN201811091919.0. low-temperature energy storage,photocatalysis,and antibiosis. 2018-12-21 Energy Convers Manage,2015,106:873 (李俊峰,罗正平,孙理理.一种无机盐高温相变微胶囊及其制 [38]Sakai H,Sheng N,Kumiawan A,et al.Fabrication of heat storage 备方法:中国专利,CN201811091919.0.2018-12-21) pellets composed of microencapsulated phase change material for [49]Li J F,Luo Z P,Wang M,et al.The Imvention Relates to A Phase high-temperature applications.App/Energ,2020,265:114673 Change Thermal Control Coating and A Preparation Method [39]Nomura T,Sheng N,Zhu C Y,et al.Microencapsulated phase Thereof:China Patent,CN201910569905.3.2019-11-05 change materials with high heat capacity and high cyclic durability (李俊峰,罗正平,王萌,等。一种相变热控涂层及其制备方法: for high-temperature thermal energy storage and transportation. 中国专利,CN201910569905.3.2019-11-05) 4 opl Energ,2017,188:9 [50]Liu J,Li J F,Luo Z P,et al.A novel multiwalled LiF@GO@SiO, [40]He F,Chao S,He X D,et al.Inorganic microencapsulated core/ microcapsule with high phase change temperature.Sol Energy shell structure of Al-Si alloy micro-particles with silane coupling Mater Sol Cells,2019,203:art.No.110188 agent.Ceram Int,2014,40(5):6865 [51]Zhang Q Y,Liu J,Liu Y B,et al.A Kind of High Temperature and [41]Nomura T,Zhu C Y,Sheng N,et al.Microencapsulation of metal- High Enthalpy Phase Change Material Multi-Wall Microcapsule based phase change material for high-temperature thermal energy and Its Preparation Method:China Patent,CN201910483692.2. storage.Sci Rep,2015,5:9117 2019-08-16 [42]Zhang M J,Han Z J,Gu H Z,et al.High Temperature Phase (张秋禹,刘锦,刘毅彬,等.一种高温高常值相变材料多壁结构微 Change Thermal Storage Microcapsule of Dense Alumina Shell 胶囊及制备方法:中国专利,CN201910483692.2.2019-08-16)1991: 92 Shi T J, Hu P, Wang J T. Preparation of polyurea microcapsules containing  phase  change  materials  using  microfluidics. Chem Select, 2020, 5(7): 2342 [29] Feng  L,  Dong  S  P,  Zhou  H.  n-Dodecanol  nanocapsules  with supramolecular lock shell layer for thermal energy storage. Chem Eng J, 2020, 389: 124483 [30] Xu  R,  Xia  X  M,  Wang  W,  et  al.  Infrared  camouflage  fabric prepared  by  paraffin  phase  change  microcapsule  with  Good thermal insulting properties. Colloids Surf A, 2020, 591: 124591 [31] Sahan  N,  Paksoy  H.  Designing  behenic  acid  microcapsules  as novel  phase  change  material  for  thermal  energy  storage applications  at  medium  temperature. Int J Energy Res,  2020, 44(5): 3922 [32] Wang  X  G,  Chen  Z  F,  Xu  W,  et  al.  Capric  acid  phase  change microcapsules modified with graphene oxide for energy storage. J Mater Sci, 2019, 54(24): 14834 [33] Zhang  H  Z,  Wang  X  D,  Wu  D  Z.  Silica  encapsulation  of  n￾octadecane via sol-gel process: a novel microencapsulated phase￾change  material  with  enhanced  thermal  conductivity  and performance. J Colloid Interf Sci, 2010, 343(1): 246 [34] Liu  Z  F,  Chen  Z  H,  Yu  F.  Preparation  and  characterization  of microencapsulated  phase  change  materials  containing  inorganic hydrated  salt  with  silica  shell  for  thermal  energy  storage. Sol Energy Mater Sol Cells, 2019, 200: art. No. 110004 [35] He F, Wang X D, Wu D Z. New approach for sol-gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor. Energy, 2014, 67: 223 [36] Li  F  N,  Wang  X  D,  Wu  D  Z.  Fabrication  of  multifunctional microcapsules containing n-eicosane core and zinc oxide shell for low-temperature  energy  storage,  photocatalysis,  and  antibiosis. Energy Convers Manage, 2015, 106: 873 [37] Sakai H, Sheng N, Kurniawan A, et al. Fabrication of heat storage pellets composed of microencapsulated phase change material for high-temperature applications. Appl Energ, 2020, 265: 114673 [38] Nomura  T,  Sheng  N,  Zhu  C  Y,  et  al.  Microencapsulated  phase change materials with high heat capacity and high cyclic durability for  high-temperature  thermal  energy  storage  and  transportation. Appl Energ, 2017, 188: 9 [39] He  F,  Chao  S,  He  X  D,  et  al.  Inorganic  microencapsulated  core/ shell structure of Al−Si alloy micro-particles with silane coupling agent. Ceram Int, 2014, 40(5): 6865 [40] Nomura T, Zhu C Y, Sheng N, et al. Microencapsulation of metal￾based phase change material for high-temperature thermal energy storage. Sci Rep, 2015, 5: 9117 [41] Zhang  M  J,  Han  Z  J,  Gu  H  Z,  et  al. High Temperature Phase Change Thermal Storage Microcapsule of Dense Alumina Shell [42] and Its Preparation Method:  China  Patent,  CN201810202184.8. 2018-08-10 (张美杰, 韩藏娟, 顾华志, 等. 致密氧化铝壳层高温相变蓄热微 胶囊及其制备方法: 中国专利, CN201810202184.8. 2018-08-10) Zhang F, Lin J, Yang X, et al. The Invention Relates to a Method for Preparing Metal Coated High-Temperature Phase Change Thermal Storage Microcapsule and the Thermal Storage Micro￾capsule Obtained Therefrom:  China  Patent,  CN201811197058.4. 2019-02-12 (张锋, 林俊, 杨旭, 等. 一种制备金属包壳高温相变储热微胶囊 的方法以及由此得到的储热微胶囊: 中国专利, CN201811197058. 4. 2019-02-12) [43] Yang  Z  Z,  Zhang  X,  Wang  Q. Metal and Alloy Phase Change Energy Storage Microcapsules and Their Preparation Methods: China Patent, CN201710129236.9. 2017-07-04 (杨振忠, 张行, 王倩. 金属及合金相变储能微胶囊及其制备方 法: 中国专利, CN201710129236.9. 2017-07-04) [44] Li J F, Lu W, Luo Z P, et al. Thermal stability of sodium nitrate microcapsules  for  high-temperature  thermal  energy  storage. Sol Energy Mater Sol Cells, 2017, 171: 106 [45] Takai-Yamashita  C,  Shinkai  I,  Fuji  M,  et  al.  Effect  of  water soluble  polymers  on  formation  of  Na2SO4 contained  SiO2 microcapsules  by  W/O  emulsion  for  latent  heat  storage. Adv Powder Technol, 2016, 27(5): 2032 [46] Li J F, Lu W, Luo Z P, et al. Synthesis and thermal properties of novel  sodium  nitrate  microcapsules  for  high-temperature  thermal energy storage. Sol Energy Mater Sol Cells, 2017, 159: 440 [47] Li J F, Luo Z P, Sun L L. The Invention Relates to an Inorganic Salt High-Temperature Phase Change Microcapsule and A Preparation Method Thereof:  China  Patent,  CN201811091919.0. 2018-12-21 (李俊峰, 罗正平, 孙理理. 一种无机盐高温相变微胶囊及其制 备方法: 中国专利, CN201811091919.0. 2018-12-21) [48] Li J F, Luo Z P, Wang M, et al. The Invention Relates to A Phase Change Thermal Control Coating and A Preparation Method Thereof: China Patent, CN201910569905.3. 2019-11-05 (李俊峰, 罗正平, 王萌, 等. 一种相变热控涂层及其制备方法: 中国专利, CN201910569905.3. 2019-11-05) [49] Liu J, Li J F, Luo Z P, et al. A novel multiwalled LiF@GO@SiO2 microcapsule  with  high  phase  change  temperature. Sol Energy Mater Sol Cells, 2019, 203: art. No. 110188 [50] Zhang Q Y, Liu J, Liu Y B, et al. A Kind of High Temperature and High Enthalpy Phase Change Material Multi-Wall Microcapsule and Its Preparation Method:  China  Patent,  CN201910483692.2. 2019-08-16 (张秋禹, 刘锦, 刘毅彬, 等. 一种高温高焓值相变材料多壁结构微 胶囊及制备方法: 中国专利, CN201910483692.2. 2019-08-16) [51] 江    羽等: 高温相变储能微胶囊研究进展 · 117 ·
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