孙珊等：吡咯/炭黑氧化物复合氧阴极材料的制备及催化性能 ·223· 2014,32:810 doped carbon nanotubes as a bifunctional electrocatalyst synthe- [4]Shao M H.Catalysts for fuel cells /Summary of the 29th Annual sized by oxidative cutting.J Am Chem Soc,2014,136(21 ) Conference of the Chinese Chemical Association.Beijing,2014:48 7551 (邵敏华.燃料电池催化剂/中国化学会第29届学术年会 [11]Fleurier R,Lauret J S,Lopez U,et al.Transmission electron 摘要集.北京，2014：48) microscopy and UV-vis-IR spectroscopy analysis of the diameter [5]Zha QX.Introduction of Electrode Process Kinetics.3rd Ed.Bei- sorting of carbon nanotubes by gradient density ultracentrifuga- jing:Science Press,2002 tion.Adu Funct Mater,2009,19(14):2219 (查全性.电极过程动力学导论.3版.北京：科学出版社， [12]Biesinger M C.Payne B P,Grosvenor A P,et al.Resolving sur- 2002) face chemical states in XPS analysis of first row transition metals, [6]Yang L J,Zhao Y,Chen S,et al.A mini review on carbon-based oxides and hydroxides:Cr,Mn,Fe,Co and Ni.Appl Surf Sci, metal-free electrocatalysts for oxygen reduction reaction.Chin J 2011,257(7):2717 Catal,2013,34(11):1986 [13]Eisenberg D,Stroek W,Geels N J,et al.A simple synthesis of [7]Cheng F Y,Chen J.Metal-air batteries:from oxygen reduction an N-doped carbon ORR catalyst:hierarchical micro/meso/mac- electrochemistry to cathode catalysts.Chem Soc Rev,2012,41 ro porosity and graphitic shells.Chem Eur J,2016,22(2):501 (6):2172 [14]Zhao P,Rusli E.Xia J H,et al.Study of carbon in thermal ox- [8]Holby E F,Choudhury S,Zelenay P.Non-PGM ORR catalyst ac- ide formed on 4H-SiC by XPS.Mater Sci Forum,2005,483- tive-site screening.ECS Meeting Abstracts,2015:1280 485:653 [9]Hummers Jr WS,Offeman R E.Preparation of graphitic oxide.J[15]Pan F M,Stair P C,Fleisch T H.Chemisorption of pyridine and Am Chem Soc,1958,80(6):1339 pyrrole on iron oxide surfaces studied by XPS.Surf Sci,1986 [10]Zhao A Q,Masa J,Xia W,et al.Spinel Mn-Co oxide in N- 177(1):1孙 珊等: 吡咯/ 炭黑氧化物复合氧阴极材料的制备及催化性能 2014, 32: 810 [4] Shao M H. Catalysts for fuel cells / / Summary of the 29th Annual Conference of the Chinese Chemical Association. Beijing, 2014: 48 (邵敏华. 燃料电池催化剂 / / 中国化学会第 29 届学术年会 摘要集. 北京, 2014: 48) [5] Zha Q X. Introduction of Electrode Process Kinetics. 3rd Ed. Bei鄄 jing: Science Press, 2002 (查全性. 电极过程动力学导论. 3 版. 北京: 科学出版社, 2002) [6] Yang L J, Zhao Y, Chen S, et al. A mini review on carbon鄄based metal鄄free electrocatalysts for oxygen reduction reaction. Chin J Catal, 2013, 34(11): 1986 [7] Cheng F Y, Chen J. Metal鄄air batteries: from oxygen reduction electrochemistry to cathode catalysts. Chem Soc Rev, 2012, 41 (6): 2172 [8] Holby E F, Choudhury S, Zelenay P. Non鄄PGM ORR catalyst ac鄄 tive鄄site screening. ECS Meeting Abstracts, 2015: 1280 [9] Hummers Jr W S, Offeman R E. Preparation of graphitic oxide. J Am Chem Soc, 1958, 80(6): 1339 [10] Zhao A Q, Masa J, Xia W, et al. Spinel Mn鄄鄄 Co oxide in N鄄 doped carbon nanotubes as a bifunctional electrocatalyst synthe鄄 sized by oxidative cutting. J Am Chem Soc, 2014, 136 (21 ): 7551 [11] Fleurier R, Lauret J S, Lopez U, et al. Transmission electron microscopy and UV鄄鄄 vis鄄鄄IR spectroscopy analysis of the diameter sorting of carbon nanotubes by gradient density ultracentrifuga鄄 tion. Adv Funct Mater, 2009, 19(14): 2219 [12] Biesinger M C, Payne B P, Grosvenor A P, et al. Resolving sur鄄 face chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl Surf Sci, 2011, 257(7): 2717 [13] Eisenberg D, Stroek W, Geels N J, et al. A simple synthesis of an N鄄doped carbon ORR catalyst: hierarchical micro / meso / mac鄄 ro porosity and graphitic shells. Chem Eur J, 2016, 22(2): 501 [14] Zhao P, Rusli E, Xia J H, et al. Study of carbon in thermal ox鄄 ide formed on 4H鄄鄄 SiC by XPS. Mater Sci Forum, 2005, 483鄄 485: 653 [15] Pan F M, Stair P C, Fleisch T H. Chemisorption of pyridine and pyrrole on iron oxide surfaces studied by XPS. Surf Sci, 1986, 177(1): 1 ·223·