(1)齐格勒-纳塔( Ziegler-Natta)催化剂:Ti+AEts B—H (2)9-BBN ,9-硼二环33.1壬烷 9-borobicyclo[3.3.1]nonane (3)三甲硅基烯醇醚H43C)3S-0cH==cH (4)三苯膦羰基镍: Ph3PNi(CO (5蔡塞( Ziess)盐 H CH K (6)威尔金逊( Wilkinson)催化剂RhCl(PPh) 4、写出下列各反应的主产物: (1)CHLi+ Cuh (2)(CH33B+ChaLi (3)4n C4HLi+ SnCL4 (4)Mn(CO)5+ CH3 Br (5)Ni(CO)4+(CsH)3P NiCLot na 答案 1)2 CH3Li+ Cul ( CH3)2CuLi Lil (2)(CH3)3B +CH3Li (CH3) (3)4n-C4HgLi SnC14 (n-C4Hg)4Sn 4LiCI (4)Mn(CO)5+CH3Br- (5)Ni(CO)4+(c6H5)3P Ni(CO)3PH(C6H5)3+ cO (6) t NiCb NiCI 5、完成下列转化(1)齐格勒-纳塔（Ziegler-Natta）催化剂：Ti + AlEt3 (2)9-BBN: B H ,9-硼二环[3.3.1]壬烷 9-borobicyclo[3.3.1]nonane (3)三甲硅基烯醇醚 (H3C)3Si OCH CH2 (4）三苯膦羰基镍：Ph3PNi(CO)3 (5)蔡塞（Ziess）盐： Cl Pt Cl Cl CH2 CH2 K （6）威尔金逊（Wilkinson）催化剂:RhCl(PPh3) 4、写出下列各反应的主产物： (1) CH3Li +CuI 2:1 (2) (CH3)3B +CH3Li (3)4n -C4H9Li +SnCL4 (4)Mn(CO)5 +CH3Br (5) Ni(CO)4 +(C6H5)3P (6) +NiCL2 +Na 答案： (1) 2 CH3Li + CuI (CH3 )2CuLi + LiI (2)(CH3)3B + CH3Li (CH3)4BLi (3) 4n-C4H9Li + SnCl4 (n-C4H9)4Sn + 4LiCl (4) Mn(CO)5 + CH3Br CH3Mn(CO)5 + Br (5) Ni(CO)4 + (C6H5)3P Ni(CO)3PH(C6H5)3 + CO (6) + NiCl2 + Na NiCl + NaCl 5、完成下列转化：