.814. 工程科学学报，第40卷，第7期 仑尼乌斯公式计算出来的活化能为42.22k· [8]Chen S Q,Shi J,Shi Z,et al.Progresses on solvent extraction of mol-1,说明白云母和CaCL,的氯化过程的确受界面 rubidium and cesium from brines.J Salt ChemChem Ind,2017 46(6):45 化学反应控制. (陈尚清，石健，史振，等.溶剂萃取法从卤水中提取物，铯研 参考文献 究进展.盐科学与化工，2017,46(6)：45) [9]Bao A M,Qian Z Q,Zheng H,et al.Progress of separation and [1]Tan Y N.Liu Y.Properties and research progress of rubidium and extraction methods for rare alkali metals rubidium and cesium.Ap- its compounds.Chin J Nonferrous Met,2017,27(2):272 pl Chem Ind,2017,46(7):1377 (谭彦妮，刘咏.铆及含铷材料的性能与应用研究进展.中国 (宝阿敏，钱志强，郑红，等.蜘、铯的分离提取方法及其研究 有色金属学报，2017,27(2)：272) 进展.应用化工，2017,46(7)：1377) [2]Wang C X.Analysis ofdevelopment and utilization of rubidium ce- [10]Huang P.Li J,Kang J,et al.Experiment on leaching of rubidi- sium resources.Xinjiang Nonferrous Met,2017(6):55 um from low-grade rubidium ore.Nonferrous Met (Extr Metall), (王晨雪.铷铯资源开发利用浅析.新疆有色金属，2017(6)： 2017(7):23 55) (黄鹏，李健，康健，等.低品位物矿浸出试验.有色金属 [3]Xiong Y W.Research onmineralogy for an altered basalt type ru- (治炼部分)，2017(7)：23) bidium and cesium ore in Yunnan.Multipurp Utiliz Miner Resour, [11]Zhou L B,Yuan T H,Li R D,et al.Extraction of rubidium from 2017(2):75 kaolin clay waste:process study.Hydrometallurgy,2015,158: (熊玉旺.云南某地蚀变玄武岩型御艳矿工艺矿物学研究.矿 61 产综合利用，2017(2)：75) [12]Liu J.Liu J H,Wu B W,et al.Comparison on the solid-state [4]Li X Y,Shan Y,Zeng MQ,et al.Experimental research on flota- desilication kineties of silicon manganese powder by microwave tion of low grade rubidium in mica-feldspar ore.Nonferrous Met heating and conventional heating.Chin J Eng,2017,39(2): Miner Process Sect),2017(3):55 208 (李向益，单勇，曾茂青，等.某低品位云母-长石型物矿浮选 (刘建，刘建华，吴博威，等.微波加热与常规加热硅锰粉固 试验研究.有色金属（选矿部分），2017(3)：55) 相脱硅动力学比较.工程科学学报，2017,39(2)：208) [5]Meng L Y,Yang F,Li R Q,et al.Experiments on comprehensive [13] Wang G.Xue Q G,Shen Y F,et al.Carbothermic reduction ki- utilization of potassium-rich brine in Jiangling Depression,Jing- netics of boron-bearing iron concentrate.Chin /Eng,2017,38 zhou,Hubei.Geol Chem Miner,2017,39(1):46 (5):623 (孟令阳，杨飞，李瑞琴，等.湖北荆州江陵凹陷富钾肉水综 (王广，薛庆国，沈颖峰，等.硼铁精矿的碳热还原动力学 合利用工艺实验研究.化工矿产地质，2017,39(1)：46) 工程科学学报，2017,38(5)：623) [6]Unknown.Found a large rubidium mine base in Jiangxi Province. [14]Tian L,Liu Y,Zhang TA,et al.Kinetics of indium dissolution China Mine Eng,2017,46(3):75 from sphalerite with high indium content in pressure acid leac- (佚名.江西发现一处超大型御矿基地。中国矿山工程， hing.Rare Met,2017,36(1):69 2017,46(3):75) [15]Wang R C,Zhai Y C.Ning Z Q.Thermodynamics and kinetics [7]Zheng S L,Li P,Tian L,et al.A chlorination roasting process to of alumina extraction from fly ash using an ammonium hydrogen extract rubidium from distinctive kaolin ore with alterative chlori- sulfate roasting method.Int J Miner Metall Mater,2014,21 nating reagent.Int J Miner Process,2016,157:21 (2):144工程科学学报,第 40 卷,第 7 期 仑尼 乌 斯 公 式 计 算 出 来 的 活 化 能 为 42郾 22 kJ· mol - 1 ,说明白云母和 CaCl 2的氯化过程的确受界面 化学反应控制. 参 考 文 献 [1] Tan Y N, Liu Y. Properties and research progress of rubidium and its compounds. Chin J Nonferrous Met, 2017, 27(2): 272 (谭彦妮, 刘咏. 铷及含铷材料的性能与应用研究进展. 中国 有色金属学报, 2017, 27(2): 272) [2] Wang C X. Analysis ofdevelopment and utilization of rubidium ce鄄 sium resources. Xinjiang Nonferrous Met, 2017(6): 55 (王晨雪. 铷铯资源开发利用浅析. 新疆有色金属, 2017(6): 55) [3] Xiong Y W. Research onmineralogy for an altered basalt type ru鄄 bidium and cesium ore in Yunnan. Multipurp Utiliz Miner Resour, 2017(2): 75 (熊玉旺. 云南某地蚀变玄武岩型铷铯矿工艺矿物学研究. 矿 产综合利用, 2017(2): 75) [4] Li X Y, Shan Y, Zeng M Q, et al. Experimental research on flota鄄 tion of low grade rubidium in mica鄄feldspar ore. Nonferrous Met (Miner Process Sect), 2017(3): 55 (李向益, 单勇, 曾茂青, 等. 某低品位云母鄄鄄长石型铷矿浮选 试验研究. 有色金属(选矿部分), 2017(3): 55) [5] Meng L Y, Yang F, Li R Q, et al. Experiments on comprehensive utilization of potassium鄄rich brine in Jiangling Depression, Jing鄄 zhou, Hubei. Geol Chem Miner, 2017, 39(1): 46 (孟令阳, 杨飞, 李瑞琴, 等. 湖北荆州江陵凹陷富钾卤水综 合利用工艺实验研究. 化工矿产地质, 2017, 39(1): 46) [6] Unknown. Found a large rubidium mine base in Jiangxi Province. China Mine Eng, 2017, 46(3): 75 (佚名. 江西发现一处超大型铷矿基地. 中国矿山工程, 2017, 46(3): 75) [7] Zheng S L, Li P, Tian L, et al. A chlorination roasting process to extract rubidium from distinctive kaolin ore with alternative chlori鄄 nating reagent. Int J Miner Process, 2016, 157: 21 [8] Chen S Q, Shi J, Shi Z, et al. Progresses on solvent extraction of rubidium and cesium from brines. J Salt Chem Chem Ind, 2017, 46(6): 45 (陈尚清, 石健, 史振, 等. 溶剂萃取法从卤水中提取铷、铯研 究进展. 盐科学与化工, 2017, 46(6): 45) [9] Bao A M, Qian Z Q, Zheng H, et al. Progress of separation and extraction methods for rare alkali metals rubidium and cesium. Ap鄄 pl Chem Ind, 2017, 46(7): 1377 (宝阿敏, 钱志强, 郑红, 等. 铷、铯的分离提取方法及其研究 进展. 应用化工, 2017, 46(7): 1377) [10] Huang P, Li J, Kang J, et al. Experiment on leaching of rubidi鄄 um from low鄄grade rubidium ore. Nonferrous Met (Extr Metall), 2017(7): 23 (黄鹏, 李健, 康健, 等. 低品位铷矿浸出试验. 有色金属 (冶炼部分), 2017(7): 23) [11] Zhou L B, Yuan T H, Li R D, et al. Extraction of rubidium from kaolin clay waste: process study. Hydrometallurgy, 2015, 158: 61 [12] Liu J, Liu J H, Wu B W, et al. Comparison on the solid鄄state desilication kinetics of silicon manganese powder by microwave heating and conventional heating. Chin J Eng, 2017, 39 (2 ): 208 (刘建, 刘建华, 吴博威, 等. 微波加热与常规加热硅锰粉固 相脱硅动力学比较. 工程科学学报, 2017, 39(2): 208) [13] Wang G, Xue Q G, Shen Y F, et al. Carbothermic reduction ki鄄 netics of boron鄄bearing iron concentrate. Chin J Eng, 2017, 38 (5): 623 (王广, 薛庆国, 沈颖峰, 等. 硼铁精矿的碳热还原动力学. 工程科学学报, 2017, 38(5): 623) [14] Tian L, Liu Y, Zhang T A, et al. Kinetics of indium dissolution from sphalerite with high indium content in pressure acid leac鄄 hing. Rare Met, 2017, 36(1): 69 [15] Wang R C, Zhai Y C, Ning Z Q. Thermodynamics and kinetics of alumina extraction from fly ash using an ammonium hydrogen sulfate roasting method. Int J Miner Metall Mater, 2014, 21 (2): 144 ·814·