NH(过量) CHC—NH2+CH3 COONH4 2 CH COOH CH CH- CH CH OH CHa COOCH, CH, CH,+ CH3COOH CH2 CsHg AICI COCH,+CH COOH C2HNH2(过量) CH3Co-NHC2Hs CH3 C Hs NH (tt) H,N-C-CH2 CH, COONHA HO O ←HoOC-CH,CH2COOH CH-C CHCHCHOH HOOC-CH,- CH2 COoCH2 CH, CH CH-C' CsHB AICI COCH2 CH2 COOH C2HNH2(过量) C2H5NHCOCH2 CH2 COONH3C2Hg 07写出丙酸乙酯与下列试剂作用的产物 (1)H3OH2O(2)OH,HO(3)1-辛醇(4)CHNH2(5)LAH然后加H3OH2O(6.) C2 Hs MgBr,然后加H3OH2O HO H CHa CH, COOH+ C2H5OH HO, H,O CHCH cOo -+ C,HoH 1辛稀 HCI CH, CH, COOCH(c CH. +CH, cH OH CH3, COOC2 H CHNH CH3 CH, CONHC H5 C2H5OH LiAH HO:: H0 -CH3CH2 CH2 OH + C,H.OH ( CH3 CH2)3COH C,HOH 10.8写出丙酰胺与下列各试剂作用的产物。 (1)HO,H2O(2)OH,H2O(3)P2O5,加热 H3o, H2o CH CH, COOH+ NH+ HO, Ho CH3CH2 C-NH2 CH CH CO0+ NH PO CH3 CH2-CN+C O O C O CH2 CH2 NH3 CH3 C O NH CH3COONH4 2 CH3COOH CH3COOCH2CH2CH3 CH3COOH COCH3 CH3COOH CH3CO NHC2H5 CH3COONH3C2H5 C O O C O CH2 CH2 H2O CH3CH2CH2OH C6H6,AlCl3 C2H5NH2 NH3 H2O CH3CH2CH2OH C6H6,AlCl3 C2H5NH2 H2N C O CH2CH2COONH4 HOOC CH2 CH2 COOH HOOC CH2 CH2 COOCH2CH2CH3 COCH2CH2COOH C2H5NHCOCH2CH2COONH3C2H5 （过量 ） + 2 + + + (过量) (过量) (过量) 10.7 写出丙酸乙酯与下列试剂作用的产物 (1)H3O+ ,H2O (2)OH- ,H2O （3）1-辛醇 (4)CH3NH2（5）LiAlH;然后加 H3O+ ,H2O（6.） C2H5MgBr;然后加 H3O+ ,H2O 答： CH3CH2COOC2H5 H3O+ H2O CH3CH2COOH C2H5OH HO H2O CH3CH2COO C2H5OH HCl CH3CH2COOCH2(CH2) 6CH3 CH3CH2OH CH3NH2 LiAlH4 H3O + H2O CH3CH2CONHC2H5 C2H5OH CH3CH2CH2OH C2H5OH (CH3CH2) 3COH C2H5OH , + + 1-辛稀 + , , 再加入 , + + + 10.8 写出丙酰胺与下列各试剂作用的产物。 (1)H3O+ ,H2O (2)OH- ,H2O（3） P2O5,加热 答： CH3CH2C O NH2 H3O+ H2O HO H2O P2O5 CH3CH2COOH CH3CH2COO CH3CH2 CN H2O NH3 NH4 , , △ + + + +