第36卷第4期 北京科技大学学报 Vol.36 No.4 2014年4月 Journal of University of Science and Technology Beijing Apr.2014 伪半固态触变成形制备SiCp/Al电子封装材料的组织 与性能 郭明海,刘俊友”,贾成厂”,果世驹”,李艳霞》,周洪宇 1)北京科技大学材料科学与工程学院,北京1000832)北华航天工业学院材料系,廊坊065000 ☒通信作者,E-mail:qifeng_guo(@126.com 摘要采用伪半固态触变成形工艺制备了40%、56%和63%三种不同SiC体积分数颗粒增强A1基电子封装材料,并借助 光学显微镜和扫描电镜分析了材料中A!和Si汇的形态分布及其断口形貌,测定了材料的密度、致密度、热导率、热膨胀系数、 抗压强度和抗弯强度.结果表明,通过伪半固态触变成形工艺可制备出的不同SC体积分数A!基电子封装材料,其致密度 高,热膨胀系数可控,材料中A1基体相互连接构成网状,SC颗粒均匀镶嵌分布于A1基体中.随着SC颗粒体积分数的增加, 电子封装材料密度和室温下的热导率稍有增加,热膨胀系数逐渐减小,室温下的抗压强度和抗弯强度逐渐增加.SC/A1电子 封装材料的断裂方式为SiC的脆性断裂,同时伴随着A!基体的韧性断裂. 关键词电子封装;颗粒增强复合材料:触变成形;热导率;热膨胀:材料强度 分类号TN405 Microstructure and properties of SiCp/Al electronic packaging materials fabricated by pseudo-semi-solid thixoforming GUO Ming-hai,LIU Jun-you,JIA Cheng-chang",GUO Shi-ju,LI Yan-xia,ZHOU Hong-yu) 1)School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China 2)Department of Materials,North China Institute of Aerospace Engineering,Langfang 065000,China Corresponding author,E-mail:qifeng_guo@126.com ABSTRACT SiC particles reinforced Al matrix composites with three different SiC volume fractions of 40%,56%and 63%for elec- tronic packaging were prepared by pseudo-semi-solid thixoforming.The Al and SiC distribution and the fractographs of the SiCp/Al electronic packaging materials were examined by optical microscopy and scanning electron microscopy.The density,relative density, thermal conductivity (TC),coefficient of thermal expansion (CTE),compressive strength and bending strength of the SiCp/Al elec- tronic packaging materials were tested.It is found that the SiCp/Al electronic packaging materials have controllable coefficients of ther- mal expansion and high relative density.The Al matrix is connected into a network,and SiC particles are uniformly distributed in the Al matrix.When the SiC volume fraction increases,the density and thermal conductivity at room temperature lightly increase,the coef- ficient of thermal expansion gradually decreases,and the compressive strength and bending strength increase.The main fracture mode of the SiC/Al electronic packaging materials is brittle fracture of SiC particles accompanied by ductile fracture of the Al matrix at the same time. KEY WORDS electronic packaging:particle reinforced composites:thixoforming:thermal conductivity:thermal expansion:strength of materials 半导体集成电路的速度和集成度提高,导致芯元件的失效率与其工作温度呈指数关系,功能则与 片发热率增加,电路工作温度上升.实验证明,单个 其成反比口,因而如何提高芯片的散热效率,使得 收稿日期:201304-一17 DOI:10.13374/j.issn1001-053x.2014.04.011:http:/jourals.ustb.edu.cn第 36 卷 第 4 期 2014 年 4 月 北京科技大学学报 Journal of University of Science and Technology Beijing Vol. 36 No. 4 Apr. 2014 伪半固态触变成形制备 SiCp /Al 电子封装材料的组织 与性能 郭明海1) ,刘俊友1) ,贾成厂1) ,果世驹1) ,李艳霞2) ,周洪宇1) 1) 北京科技大学材料科学与工程学院,北京 100083 2) 北华航天工业学院材料系,廊坊 065000 通信作者,E-mail: qifeng_guo@ 126. com 摘 要 采用伪半固态触变成形工艺制备了 40% 、56% 和 63% 三种不同 SiC 体积分数颗粒增强 Al 基电子封装材料,并借助 光学显微镜和扫描电镜分析了材料中 Al 和 SiC 的形态分布及其断口形貌,测定了材料的密度、致密度、热导率、热膨胀系数、 抗压强度和抗弯强度. 结果表明,通过伪半固态触变成形工艺可制备出的不同 SiC 体积分数 Al 基电子封装材料,其致密度 高,热膨胀系数可控,材料中 Al 基体相互连接构成网状,SiC 颗粒均匀镶嵌分布于 Al 基体中. 随着 SiC 颗粒体积分数的增加, 电子封装材料密度和室温下的热导率稍有增加,热膨胀系数逐渐减小,室温下的抗压强度和抗弯强度逐渐增加. SiC/Al 电子 封装材料的断裂方式为 SiC 的脆性断裂,同时伴随着 Al 基体的韧性断裂. 关键词 电子封装; 颗粒增强复合材料; 触变成形; 热导率; 热膨胀; 材料强度 分类号 TN405 Microstructure and properties of SiCp /Al electronic packaging materials fabricated by pseudo-semi-solid thixoforming GUO Ming-hai 1) ,LIU Jun-you1) ,JIA Cheng-chang1) ,GUO Shi-ju1) ,LI Yan-xia2) ,ZHOU Hong-yu1) 1) School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China 2) Department of Materials,North China Institute of Aerospace Engineering,Langfang 065000,China Corresponding author,E-mail: qifeng_guo@ 126. com ABSTRACT SiC particles reinforced Al matrix composites with three different SiC volume fractions of 40% ,56% and 63% for electronic packaging were prepared by pseudo-semi-solid thixoforming. The Al and SiC distribution and the fractographs of the SiCp /Al electronic packaging materials were examined by optical microscopy and scanning electron microscopy. The density,relative density, thermal conductivity ( TC) ,coefficient of thermal expansion ( CTE) ,compressive strength and bending strength of the SiCp /Al electronic packaging materials were tested. It is found that the SiCp /Al electronic packaging materials have controllable coefficients of thermal expansion and high relative density. The Al matrix is connected into a network,and SiC particles are uniformly distributed in the Al matrix. When the SiC volume fraction increases,the density and thermal conductivity at room temperature lightly increase,the coefficient of thermal expansion gradually decreases,and the compressive strength and bending strength increase. The main fracture mode of the SiC/Al electronic packaging materials is brittle fracture of SiC particles accompanied by ductile fracture of the Al matrix at the same time. KEY WORDS electronic packaging; particle reinforced composites; thixoforming; thermal conductivity; thermal expansion; strength of materials 收稿日期: 2013--04--17 DOI: 10. 13374 /j. issn1001--053x. 2014. 04. 011; http: / /journals. ustb. edu. cn 半导体集成电路的速度和集成度提高,导致芯 片发热率增加,电路工作温度上升. 实验证明,单个 元件的失效率与其工作温度呈指数关系,功能则与 其成反比[1],因而如何提高芯片的散热效率,使得