6.1运用4n+2规则,预料以下化合物中哪个是芳香性?哪个是非芳香性或反芳香性的?

5.1下列试剂哪个亲核性强? (1)氨、甲胺;(2)水、乙醇; (3)异丁醇、叔丁醇

Hoffmann, Angew. Chem. Int. Ed. 1979, 18, 563-572 (Stereochemistry of) Nakai, Chem. Rev. 1986, 86, 885-902 (Wittig Rearrangement) Evans, Accts. Chem. Res. 1974, 7, 147-55 (Sulfoxide Rearrangement)

Reading Assignment for week: Carey & Sundberg: Part A; Chapter 11 Concerted Pericyclic Reactions Pericyclic Reactions: Part–2 Chemistry 206 Advanced Organic Chemistry

Woodward-Hoffmann Theory R. B. Woodward and R. Hoffmann, The Conservation of Orbital Symmetry, Verlag Chemie, Weinheim, 1970. Frontier Molecular Orbital Theory I. Fleming, Frontier Orbitals and Organic Chemical Reactions

Olefin Addition RXns in Polyether Synthesis-1 Chem

Advanced Organic Chemistry Handout–10A Diastereoselective Attack of Electrophiles on Chiral Olefins Matthew D. Shair Wednesday

Carey & Sundberg: Part A; Chapter 7 Carbanions & Other Nucleophilic Carbon Species

1. Type II Diels-Alder II. Radical Reactions A. 5-Exo- and 6-Endo- Ring Formations

Carey, and Sundberg, Advanced Organic Chemistry, Part A fourth Edition, Chepter 13, \Photochemistry\, pp 743-789 \New insights into an old mechanism: