Intramolecular Enone-Olefin Photocycloadditions Directed Toward Natural Product Synthesis Travis Dunn DAE Group Friday Afternoon Seminar

\...every synthetic chemist is well advised to follow this fascinating field with appropriate attention.\

Advanced Organic Chemistry Handout–10A Diastereoselective Attack of Electrophiles on Chiral Olefins Matthew D. Shair Wednesday

Hoffmann, Angew. Chem. Int. Ed. 1979, 18, 563-572 (Stereochemistry of) Nakai, Chem. Rev. 1986, 86, 885-902 (Wittig Rearrangement) Evans, Accts. Chem. Res. 1974, 7, 147-55 (Sulfoxide Rearrangement)

Enantioselective Carbonyl Addition Handout

Carbonyl and Azomethine Electrophiles-1 Relevant Dunitz Articles Geometrical Reaction Coordinates. Il. Nucleophilic Addition to Reactivity Trends

Other Useful References Polyketide Biosynthesis Historical Perspective on the Aldol Reaction Aldol Diastereoselectivity Enolate Diastereoface Selectivity Absolute Control in the Aldol Process

An Organizational Format for the Classification of Functional Groups. Applications to the Construction of Difunctional Relationships

D. A. Evans Enolate Acylation Acylation & Carboxylation Chem 206 The Reaction: Acylation + Carboalkoxylation + Situations where the reaction is employed:

The product-determining step could be step A NabH3CN Rc R Meo Me Matthew d shair