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Cycloalkanes with only one ring are named by attaching the prefix cyclo- to the names of the alkanes possessing the same number of carbon atoms
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The different arrangements of atoms caused by rotation about a single bond are called conformations (构象)of the molecule, and a specific conformation is called a conformer (构象异构体, conformation isomer). An analysis of the energy changes that a molecule undergoes as groups rotate about single bonds is called a conformational analysis (构象分析)
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Isomers are different compounds that have the same molecular formula. Constitutional isomers are isomers that differ because their atoms are connected in a different order. Stereoisomers differ only in arrangement of their atoms in space.Stereoisomers are not constitutional isomers. Enantiomers are stereoisomers whose molecules are nonsuperposable mirror images of each other. Diastereomer are stereoisomers whose molecules are not mirror images of each other
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Before 1951 only relative configurations of chiral molecules were known. Configurations of chiral molecules were related to each other through reactions of known stereochemistry. The standard compound was glyceraldehyde
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First order overall (一级反应) The reaction is a unimolecular nucleophilic substitution(单分子亲核取代反应)
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1. The experimental conditions — temperature and acid concentration — that are required to being about dehydration are closely related to the structure of the individual alcohol. The relative ease with which alcohols undergo dehydration is in the following order:
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Part I Lead-in (Task 1-5) Part II In-Class Reading (Text Structure; Word Study; Sentence Study) Part III After-Class Reading (Passage One; Passage Two)
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How are molecular structures determined? One way is though the use of spectroscopic methods. Spectroscopy is the study of the interaction of energy with matter. When energy is applied to matter it can be absorbed, emitted, cause a chemical change, or be transmitted
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A mass spectrometer produces a spectrum of masses based on the structure of a molecule. It is a spectrum or plot of the distribution of ion masses corresponding to the formula weight of a molecule, fragments derived from the molecule, or both
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These spectra are often called carbon magnetic resonance (CMR) spectra or 13C NMR spectra. In some important ways 13C spectra are usually les complex and easier to interpret than proton (1H) NMR spectra
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