Idea Develops the concept of chemical potential and shows how it can be used to account for the equilibrium composition of chemical reaction Equilibrium co

相律 Phase Rules Phase diagrams are extremely useful for systems with multiple components, and serve to describe physical and chemical equilibria over range of different compositions, as well as points where substances are mutually miscible, or even when a system has to be brought to a specific set of conditions for equilbrium to exist(e.g., pressure

热力学定律— Helmholtz and Gibbs energies Consider a system in thermal equilibrium with surroundings, at temp. T For change in the system with transfer of heat, the Clausius inequality is

热力学第一定律 热化学(ThermoChemistry) 1.吸热反应&放热反应 2.标准态:指定温度(通常是298.15K),一个标准大气压 标准焓变ΔH°:变化前后物质都处于标准态. 3.热化学方程式:注明状态 标准摩尔焓变△Hm;标准反应焓变ΔrH°

The rate theory of unimolecular reaction 单分子反应速率理论 Mechanism of Complex reactions 复杂反应

Definitions ·ld:“derived from living organisms New: \chemistry of carbon compounds\ From inorganic to organic, Wohler, 1828

3.1 酸碱反应及其平衡常数 3.2 酸度对弱酸(碱)形体分布的影响

第一章概论 3.基准试剂主体含量大于99.9%;高纯试剂杂质含量少;专用试剂指在某一特殊应用中无 干扰,如光谱纯、色谱纯。 6.标定c(NaOH)=0.05mol·-1时,草酸m=0.05×0.025×63=0.08g 0.0002 称量误差E=008=0.25%>0.1% 0.08 而m(邻)=0.05×0.025×204=0.26g

北京大学：《分析化学 Analytical Chemistry》课程教学资源（PPT课件讲稿）第四章 络合滴定法 混合金属离子的选择性滴定、络合滴定的方式及应用

3.8.1酸碱标准溶液的配制与标定 3.8.2 CO2对酸碱滴定的影响 3.8.3 应用示例