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Evans Group Seminar, February 13, 1998 For a recent general review of the Simmons-Smith reaction see:
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Isolated from bark and leaves of Yuzuriha tree Used to cure asthma and vermicide in the early 20th century Compounds have been known since 1909. First structure solved in 1965
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Recent Applications of the Prins Reaction in Stereoselective Synthesis Matthew D. Shair Monday
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The Aza-Cope Rearrangement. Background and Application to Alkaloid Synthesis Mike calter Evans group seminar
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Introduction to Carbonium Ions Carbocation Stabilization Carbocation Structures by X-ray Crystallography Vinyl & Allyl Carbonium Ions Carbocations: Stability & Structure March, Advanced Organic Chemistry
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D. A. Evans Enolate Acylation Acylation & Carboxylation Chem 206 The Reaction: Acylation + Carboalkoxylation + Situations where the reaction is employed:
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Chemistry 206 Advanced Organic Chemistry Handout 27A Vicinal Elimination Reactions: An Overview Matthew D. Shair Wednesday
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Sulfur-Based Activating Groups Sulfur-Ylides Sulfur-Stabilized Carbanions: Structure Sulfone-Based Transformations Pummerer Rearrangement
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An Organizational Format for the Classification of Functional Groups. Applications to the Construction of Difunctional Relationships
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Leading References: Langer, P. Angew. Chem. Int. Ed. Engl. 2000, 39, 3049-3052. Ciganek, E. Org. React. 1997, 51, 201-350. Basavaiah, D.; et. al. Tetrahedron, 1996, 52, 8001-8062. Drewes, S. E.; Roos, G. H. P. Tetrahedron, 1988, 44, 4653-4670
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