Carbonyl and Azomethine Electrophiles-1 Relevant Dunitz Articles Geometrical Reaction Coordinates. Il. Nucleophilic Addition to Reactivity Trends

Other Useful References Polyketide Biosynthesis Historical Perspective on the Aldol Reaction Aldol Diastereoselectivity Enolate Diastereoface Selectivity Absolute Control in the Aldol Process

An Organizational Format for the Classification of Functional Groups. Applications to the Construction of Difunctional Relationships

D. A. Evans Enolate Acylation Acylation & Carboxylation Chem 206 The Reaction: Acylation + Carboalkoxylation + Situations where the reaction is employed:

The product-determining step could be step A NabH3CN Rc R Meo Me Matthew d shair

Isolated from bark and leaves of Yuzuriha tree Used to cure asthma and vermicide in the early 20th century Compounds have been known since 1909. First structure solved in 1965

Smith, K. and A. Pelter (1991). Hydroboration of C=C and Alkynes. Comprehensive Organic Synthesis. B. M. Trost and I. Fleming. Oxford, Pergamon Press. 8: 703. Beletskaya, I. and A. Pelter (1997). “Hydroborations catalysed by transition metal complexes

Dart Epoxides as Electrophiles Chem 206 Parker, R. E.; Isaacs, N. C. Chem. Rev. 1959, 59, 737-799. Rosowsky, A. In The Chemistry of Heterocyclic Compounds;

Acyclic Conformational Analysis-1 Ethane, Propane, Butane & Pentane Conformations Introduction to Allylic Strain Reading Assignment for week

Allylic 1-3-Strain as a Controlling Element in Stereoselective Transformations TSO(2C)4 R. W. Hoffmann, Angew. Chem. Int. Ed. Engl. 2000, 39, 2054-2070 CH2)lOTs Conformation Design of Open-Chain Compounds