SOLUTIONS TO TEXT PROBLEMS 2.1 A carbonyl group is=. Of the two carbonyl functions in prostaglandin E one belongs to the ketone family, the other to the carboxylic acids. Ketone OH Carboxylic acid functional group

SOLUTIONS TO TEXT PROBLEMS 3.1 (b) The sawhorse formula contains four carbon atoms in an unbranched chain. The compound is butane, CH:CH,CH, CH3 CH3 HH H-H CH ()Rewrite the structure to show its constitution. The compound is

SOLUTIONS TO TEXT PROBLEMS 5.1 (b) Writing the structure in more detail, we see that the longest continuous chain contains four carbon atoms

SOLUTIONS TO TEXT PROBLEMS 9.1 The reaction is an acid-base process; water is the proton donor. Two separate proton-transfer steps are involved

10.1 As noted in the sample solution to part(a), a pair of electrons is moved from the double bond toward the positively charged carbon

assuming that there is no resonance stabilization in 1, 3,5-cycloheptatriene, we predict that its heat of hydrogenation will be three times that of cycloheptene or 330/mol (78.9 kcal/mol)

SOLUTIONS TO TEXT PROBLEMS 14.1 () Magnesium bears a cyclohexyl substituent and a chlorine. Chlorine is named as an anion. The compound is cyclohexylmagnesium chloride. 14.2 (b) The alkyl bromide precursor to sec-butyllithiur must be sec-butyl bromide

SOLUTIONS TO TEXT PROBLEMS 15.1 The two primary alcohols, 1-butanol and 2-methyl-1-propanol, can be prepared by hydrogenation of the corresponding aldehydes

Oxirane 2-(Chloromethyl)oxirane This compound is more commonly known as epichlorohydrin. (c)Epoxides may be named by adding the prefix epoxy to the IUPAC name of a parent compound specifying by number both atoms to which the oxygen is attached

SOLUTIONS TO TEXT PROBLEMS functions at both ends. Pentanedial is an acceptable IUPAC name for this compound.hyde 17.1 (b) The longest continuous chain in glutaraldehyd has five carbons and terminates in ald