《材料科学基础》系材料科学与工程学科的核心课程,属于专业基础课(4 学分)。内容包括原子结构与键合、晶体学基础、固体材料结构、晶体的塑性 形变、晶体缺陷、扩散等基础理论。突出材料微观结构、制备工艺与宏观性能 之间的关系

Chapter 1 Atomic Structure and Bonding 1.1 Atomic structure Atomic numbers and atomic masses 1. Atomic Models

1.2 Atomic bonding Bonding forces and energies FF net force attractive force repulsive force

2.5 Indices of crystal planes and directions I What's crystal planes anddirect ions? The atomic planes anddirections passing through the crystal arecalled(crystal) planes and directionsrespectively

2. Classification of materials based on structure Regularity in atom arrangement periodic or not (amorphous)

4. Rule for elongation or reduction of R D All R.D. in the region where K1 and K2 makes an obtuse(acute) angle will increase (reduce) its length after twinning

2.7 Some Important Crystallographic Formulas 1. Zone and zone equation All Planes parellel to common axis [uvw] constitute a (crystal) zone, the [u v w] zone. If (h k l) belongs to zone [u v w], then hukv+=0 2.ifhuk+hw=0,then[uvw] lies in(hk) 3. For cubic crystals, [h (h k)

3. 1 Basic concepts of al loys 1. Definition An alloy is the combination of metal(s) with other elements through chemical bonding. Termino logy

1. Sing le crystal ver sus po l crystal 1. For single crystals there is only one type of structure with same orientation Single crystals is characterized by anisotropy 2. Polycrystal consists of a lot of grain, small single crystals, With same structure but different orientations. These small single crystals are called grains. The boundaries between them are called grain boundaries

Paulings three rules governing the structure of ionic compounds 1. Anion Coordination polyhedron rule Each cation is surrounded by an anion polyhedron, the distance between anion and cation is r=rt tr, while the cn depends on rt/r