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Here is a typical carbonium ion question that you should be able to handle by the end of the course. Write out a mechanism for the following transformation
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Introduction to Carbonium Ions Carbocation Stabilization Carbocation Structures by X-ray Crystallography Vinyl & Allyl Carbonium Ions Carbocations: Stability & Structure March, Advanced Organic Chemistry
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Bonding Considerations: Carbon vs Silicon Chem 206 Bonding Considerations: Carbon vs Silicon
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D. A. Evans Enolate Acylation Acylation & Carboxylation Chem 206 The Reaction: Acylation + Carboalkoxylation + Situations where the reaction is employed:
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Chemistry 206 Advanced Organic Chemistry Handout 27A Vicinal Elimination Reactions: An Overview Matthew D. Shair Wednesday
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Sulfur-Based Activating Groups Sulfur-Ylides Sulfur-Stabilized Carbanions: Structure Sulfone-Based Transformations Pummerer Rearrangement
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Krista Beaver Synthetic Applications of α-Diazocarbonyl Derivatives Chem 206 Synthetic Applications of α-Diazocarbonyl Compounds An Evans Group Afternoon Seminar Krista Beaver January 15, 1999 Leading References:
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An Organizational Format for the Classification of Functional Groups. Applications to the Construction of Difunctional Relationships
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Nitro and Diazo Groups Historical Perspective Charge Affinity Patterns Functional Group Classification Scheme The Chemistry of the –NO2 Group
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Double Stereodifferentiating Aldol Reactions The Mukaiyama Aldol Reaction Variant Allylmetal Nucleophiles as Enolate Synthons
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