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SOLUTIONS TO TEXT PROBLEMS 15.1 The two primary alcohols, 1-butanol and 2-methyl-1-propanol, can be prepared by hydrogenation of the corresponding aldehydes
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SOLUTIONS TO TEXT PROBLEMS functions at both ends. Pentanedial is an acceptable IUPAC name for this compound.hyde 17.1 (b) The longest continuous chain in glutaraldehyd has five carbons and terminates in ald
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SOLUTIONS TO TEXT PROBLEMS 19.1 (b) The four carbon atoms of crotonic acid form continuous chain. Because there is a double bond between C-2 and C-3, crotonic acid is one of the stereoisomers of 2-butenoic acid. The chem
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SOLUTIONS TO TEXT PROBLEMS 21.1 Ethyl benz emuale cannor undergo the Claisen condensation, beca use it has no protons on its a- t has ho ts a-carbon on its a- atom and so cannot form an enolate Ethyl pentanoate and ethyl phenylacetate can undergo the Claisen condensation
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Chlorotoluene Benzyl chloride Of this group only benzyl chloride is not an aryl halide; its halogen is not attached to the aromatic ring but to an sp-hybridized carbon. Benzyl chloride has the weakest carbon-halogen bond, its measured carbon-chlorine bond dissociation energy being only 293 kJ/mol (70 kcal/mol). Homolytic cleavage of this bond produces a resonance-stabilized benzyl radical
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Look at the drawing from a perspective that permits you to see the carbon chain oriented ver tically with the aldehyde at the top and the Ch,oh at the bottom. Both groups should point away from you. When examined from this perspective, the hydrogen is to the left and the hydroxyl to the right with both pointing toward you
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The order of decreasing sequence rule precedence is H,N->HSCH2->-Co2\>H- When the molecule is oriented so that the lowest ranked substituent () is held away from us, the order of decreasing precedence traces clockwise path CH,SH Clockwise;thereforeR The reason why L-cysteine has the configuration while all the other L-amino acids have the S configuration lies in the fact that the-CHSH substituent is the only side chain that
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CONTENTS Preface xxv INTRODUCTION he Origins of Organic Chemistry 1 Berzelius, Wohler. and vitalism 1 The Structural Theory 3 Electronic Theories of Structure and Reactivity 3
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液力传动在传递动力的过程中,有能量损失。 包括三种:液力损失、容积损失、机械损失。 损失的表示用液力效率,容积效率 机械效率(注意:在这里与工程习ng一 致,便于|n卖文献,效率下标的表示与《流体机 械原理》中表示不同)
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串匹配(String Matching)问题是计算机科学中的一个基本问题,也是复杂性理论中研 究的最广泛的问题之一。它在文字编辑处理、图像处理、文献检索、自然语言识别、生物 学等领域有着广泛的应用。而且,串匹配是这些应用中最耗时的核心问题,好的串匹配算 法能显著地提高应用的效率。因此,研究并设计快速的串匹配算法具有重要的理论价值 实际意义
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