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If a chiral atom attached to the carbonyl group, the stereoselectivity of nucleophilic addition follows the Cram’s rule
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Many other pairs of reagents that form cabocations (orcarbocationlike species) may be used as well
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10.1A Production of Radicals 10.2A Homolytic Bond Dissociation Energies and Heats of Reaction
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9.3 醛酮的反应 Reactions of Aldehydes and Ketones
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9.1 醛 酮的结构 命名和物理性质 Structure, Nomenclature and Physical Properties 9.2 醛酮的制备 Preparations
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厦门大学化学化工学院:《有机化学》课程教学资源(课件讲稿,双语版)第八章 醇和醚 Alcohols and Ethers 8.2 醚 Ethers
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厦门大学化学化工学院:《有机化学》课程教学资源(课件讲稿,双语版)第十章 羧酸 Carboxylic Acids(10.1-10.4)
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7.3 芳香烃的化学性质 Reactions of Aromatic Hydrocarbons 7.4 苯环上亲电取代的定位规律 Orientation of Reactions on Substituted Aromatic Rings
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4.1 卤代烃的分类 结构和命名 Classification, Structure, and Nomenclature of Alkyl Halides 4.2 卤代烃的物理性质 Physical Properties of Alkyl Halides 4.3 卤代烃的化学性质 Chemical properties of Alkyl Halides
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1.12A The Structure of Methane sp3 Hybridization The 4 sp3 orbitals should be oriented at angles of 109.5° with respect to each other. An sp3-Hybridized carbon gives a tetrahedral structure for methane, and with four equivalent C—H bonds
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