厦门大学化学化工学院：《有机化学》课程教学资源（课件讲稿，双语版）第四章 卤代烃 4.5.4-4.8

厦门大学化学化工学院：《有机化学》课程教学资源（课件讲稿，双语版）第六章 炔烃和共轭二烯 Alkynes and Conjugated Dienes 6.4 共轭二烯 Conjugated Dienes

9.1 醛 酮的结构 命名和物理性质 Structure, Nomenclature and Physical Properties 9.2 醛酮的制备 Preparations

10.1A Production of Radicals 10.2A Homolytic Bond Dissociation Energies and Heats of Reaction

11.15A Ethers by Intermolecular Dehydration of Alcohols

Acid-Catalyzed hydration of Alkenes Oxymercuration-Demeruration Hydroboration-Oxidation

No addition of bromine No oxidation No hydroation Slow addition at high temperature and pressure

Many other pairs of reagents that form cabocations (orcarbocationlike species) may be used as well

If a chiral atom attached to the carbonyl group, the stereoselectivity of nucleophilic addition follows the Cram’s rule

17.7 Lithium Enolates 17.8 α-Selenation: A Synthesis of α,β-Unsaturated Carbonyl Compounds 17.9 Additions to α,β-Unsaturated Aldehydes and Ketones