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How are molecular structures determined? One way is though the use of spectroscopic methods. Spectroscopy is the study of the interaction of energy with matter. When energy is applied to matter it can be absorbed, emitted, cause a chemical change, or be transmitted
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A mass spectrometer produces a spectrum of masses based on the structure of a molecule. It is a spectrum or plot of the distribution of ion masses corresponding to the formula weight of a molecule, fragments derived from the molecule, or both
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These spectra are often called carbon magnetic resonance (CMR) spectra or 13C NMR spectra. In some important ways 13C spectra are usually les complex and easier to interpret than proton (1H) NMR spectra
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There is a group of compounds in which carbon forms only two bonds. These neutral divalent carbon compounds are called carbenes. Most carbenes are highly unstable compounds that are capable of only fleeting existence. Soon after carbenes are formed they usually react with another molecule
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In the addition of HX to an unsymmetrically substituted alkene, the hydrogen atom adds to the carbon atom of the double bond that already has the greater number of hydrogen atoms and that the X group adds to the carbon having more alkyl substituents. Markovnikov’s rule can be restated by saying that, in the addition of HX to an alkene, the more stable carbocation intermediate is formed
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SN2 reactions are highly useful in organic synthesis because they enable use to convert one functional group into another —— functional group transformation (functional group interconversion)
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The C—X bond of alkyl halides is polarized. The carbon atom bears a partial positive charge, The halogen atom a partial negative charge
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An equimolar mixture of two enantiomers is called a racemic form (either a racemate or a racemic mixture). A racemic form shows no rotation of plane￾polarized light
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The primary source of alkanes is petroleum Natural gas consists chiefly of methane, but ethane, propane, butane, and isobutane are also present. Petroleum is a complex mixture of hydrocarbons that must be refined into different fraction before it can be used
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6.1 认识静态变量 6.2 静态变量的应用 6.3 变量的命令操作 6.4 变量数组的定义 6.5 动态管理数组变量 6.6 定时提醒小程序练习 6.7 课后练习
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