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Energy and the Relative Stability Kinetic energy is the energy an object has because of its motion. Potential energy is stored energy. It exists only when an attractive or repulsive force exists between objects
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The primary source of alkanes is petroleum Natural gas consists chiefly of methane, but ethane, propane, butane, and isobutane are also present. Petroleum is a complex mixture of hydrocarbons that must be refined into different fraction before it can be used
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The different arrangements of atoms caused by rotation about a single bond are called conformations (构象)of the molecule, and a specific conformation is called a conformer (构象异构体, conformation isomer). An analysis of the energy changes that a molecule undergoes as groups rotate about single bonds is called a conformational analysis (构象分析)
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An equimolar mixture of two enantiomers is called a racemic form (either a racemate or a racemic mixture). A racemic form shows no rotation of plane￾polarized light
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The C—X bond of alkyl halides is polarized. The carbon atom bears a partial positive charge, The halogen atom a partial negative charge
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First order overall (一级反应) The reaction is a unimolecular nucleophilic substitution(单分子亲核取代反应)
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There is a group of compounds in which carbon forms only two bonds. These neutral divalent carbon compounds are called carbenes. Most carbenes are highly unstable compounds that are capable of only fleeting existence. Soon after carbenes are formed they usually react with another molecule
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How are molecular structures determined? One way is though the use of spectroscopic methods. Spectroscopy is the study of the interaction of energy with matter. When energy is applied to matter it can be absorbed, emitted, cause a chemical change, or be transmitted
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These spectra are often called carbon magnetic resonance (CMR) spectra or 13C NMR spectra. In some important ways 13C spectra are usually les complex and easier to interpret than proton (1H) NMR spectra
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A mass spectrometer produces a spectrum of masses based on the structure of a molecule. It is a spectrum or plot of the distribution of ion masses corresponding to the formula weight of a molecule, fragments derived from the molecule, or both
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