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1 Crystal Basics 2 Symmetry 3 Crystal Structure Analysis 4 Crystal Chemistry 5 Some Important Crystal Structures
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Prelog Strain: van der Waals interactions Baeyer Strain: bond angle distortion away from the ideal Pitzer Strain: torsional rotation about a sigma bond Baeyer Strain for selected ring sizes size of ring Ht of Combustion
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Classification of Functional Groups Each substituent attached to carbon activates that carbon toward a polar reaction by either resonance or induction or both. Induction
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Bonding Considerations: Carbon vs Silicon Chem 206 Bonding Considerations: Carbon vs Silicon
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Sulfur-Based Activating Groups Sulfur-Ylides Sulfur-Stabilized Carbanions: Structure Sulfone-Based Transformations Pummerer Rearrangement
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An Organizational Format for the Classification of Functional Groups. Applications to the Construction of Difunctional Relationships
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Tautomerism in C=O and C=NR Systems C=O Enolization with Metal Amide Bases C=O Enolization: Kinetic Acidities Mild Methods for Enolate Generation Enolate Structure: A Survey of X-ray Structures
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Carey & Sundberg: Part A; Chapter 7 Carbanions & Other Nucleophilic Carbon Species
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Woodward-Hoffmann Theory R. B. Woodward and R. Hoffmann, The Conservation of Orbital Symmetry, Verlag Chemie, Weinheim, 1970. Frontier Molecular Orbital Theory I. Fleming, Frontier Orbitals and Organic Chemical Reactions
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Advanced Organic Chemistry Handout–10A Diastereoselective Attack of Electrophiles on Chiral Olefins Matthew D. Shair Wednesday
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