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Thorndike called the association between sense impressions and impulses to action a bond or a connection. This marked the first formal attempt to link sensory events to behavior. Earlier brands of associationism attempted to show how ideas became linked together; thus Thorndike's
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一、 商业票据(commercial paper) 二、 国债(treasury bill) 三、 银行存单(certificate of deposit) 四、公司债券(corporate bond) 五、 抵押债券(mortgage) 六、回购协议(repurchase agreement)
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7.1 Introduction 7.2 Homolytic bond dissociation nergies 7.3 The reactions of alkanes with halogens
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Chapter 6 Ionic Reactions--- Nucleophilic substitution and elimination reactions of alkylhalides (卤代烃的亲核取代反 Because halogen atoms are more electronegative 应和消除反应) than carbon, the carbon-halogen bond of alkyl halides is polarized; the carbon atom bears a partial positive charge, the halogen atom a partial negative charge
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12.1 Introduction Systems that have a p orbital on an atom adjacent to a double bond---molecules with delocalized pi￾bonds– are called conjugated unsaturated systems
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In the addition of HX to an unsymmetrically substituted alkene, the hydrogen atom adds to the carbon atom of the double bond that already has the greater number of hydrogen atoms and that the X group adds to the carbon having more alkyl substituents. Markovnikov’s rule can be restated by saying that, in the addition of HX to an alkene, the more stable carbocation intermediate is formed
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The C—X bond of alkyl halides is polarized. The carbon atom bears a partial positive charge, The halogen atom a partial negative charge
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The most characteristic reaction of aldehydes and ketones is nucleophilic addition to the carbon-oxygen double bond
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The reactivity of organometallic compounds increases with the percent ionic character of the carbon-metal bond. RLi and RMgX are of great importance in organic synthesis
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10.1A Production of Radicals 10.2A Homolytic Bond Dissociation Energies and Heats of Reaction
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