·1542 工程科学学报,第43卷,第11期 [4]Li Z Y,Liu Y S,Jiang L J,et al.Research progress on adsorption 15上的吸附特性研究.燃料化学学报,2015,43(12):1482) purification technology of gaseous polycyclic aromatic [16]Wang Z Y,Liu Y S,Li Z Y,et al.Desorption behavior of hydrocarbons.ChinJ Eng,2018,40(2):127 ethanedioic acid and benzoic acid on activated carbon.ClESC, (李子宜,刘应书,姜理俊,等.气相多环芳烃的吸附净化技术研 2015,66(10):4016 究进展.工程科学学报,2018,40(2):127) (王占营,刘应书,李子宜,等.乙二酸和苯甲酸在活性炭上的脱 [5]Liu Y S,Li Z Y,Yang X,et al.Performance of mesoporous silicas 附行为.化工学报,2015,66(10):4016) (MCM-41 and SBA-15)and carbon (CMK-3)in the removal of [17]Otomo R,Kosugi R,Kamiya Y,et al.Modification of Sn-Beta gas-phase naphthalene:adsorption capacity,rate and zeolite:characterization of acidic/basic properties and catalytic regenerability.RSC Adv,2016,6(25):21193 performance in Baeyer-Villiger oxidation.Catal Sci Technol, [6]LiZ Y,Liu Y S,Yang X,et al.Performance of mesoporous silicas 2016,6(8):2787 and carbon in adsorptive removal of phenanthrene as a typical [18]Yang L H,Gao C H,Wang D,et al.Synthesis and adsorption of gaseous polycyclic aromatic hydrocarbon.Microporous ZSM-5 zeolite.J Hebei Univ Technol,2010,39(5):33 Mesoporous Mater,2017,239:9 (杨丽辉,高长虹,王东,等.ZSM5型分子筛的合成及其吸附性 [7]Yang X,Yi HH,Tang X L,et al.Behaviors and kinetics of 能.河北工业大学学报,2010,39(5):33) toluene adsorption-desorption on activated carbons with varying [19]Zhang L,Feng Z Y,Wei J Y,et al.Zeolite adsorbents used for pore structure.J Emviron Sci,2018,67:104 dutrex removal in cold start exhaust.Mater Rev,2012,26(13): [8]Kustov L,Golubeva V,Korableva A,et al.Alkaline-modified 139 ZSM-5 zeolite to control hydrocarbon cold-start emission. (张兰,冯朝阳,尉继英,等.分子筛对汽车冷启动尾气中芳香烃 Microporous Mesoporous Mater,2018,260:54 吸附性能的研究进展.材料导报,2012,26(13):139) [9]Lillo-Rodenas M A,Cazorla-Amoros D,Linares-Solano A. [20]Tansel B,Sager J,Rector T,et al.Significance of hydrated radius Behaviour of activated carbons with different pore size and hydration shells on ionic permeability during nanofiltration in distributions and surface oxygen groups for benzene and toluene dead end and cross flow modes.Sep Purif Technol,2006,51(1): adsorption at low concentrations.Carbon,2005,43():1758 40 [10]Koriabkina A O,de Jong A M,Schuring D,et al.Influence of the [21]Shiue A,Kang Y H,Hu S C,et al.Vapor adsorption characteristics acid sites on the intracrystalline diffusion of hexanes and their of toluene in an activated carbon adsorbent-loaded nonwoven mixtures within MFI-zeolites.J Phys Chem B,2002,106(37): fabric media for chemical filters applied to cleanrooms.Build 9559 Environ,2010,45(10):2123 [11]Jeppu G P,Clement T P.A modified Langmuir-Freundlich [22]Shen WL,LiJX.Yang Y,et al.Binary adsorption equilibrium of isotherm model for simulating pH-dependent adsorption effects./ CHa,N2 and COz on zeolite ZSM-5.CIESC J,2014,65(9):3490 Contam Hydrol,.2012,129-130:46 (沈文龙,李嘉旭,杨颖,等.基于沸石ZSM-5的CHN2/CO2二元 [12]Bulow M,Shen D M,Jale S.Measurement of sorption equilibria 体系吸附平衡.化工学报,2014,65(9):3490) under isosteric conditions:the principles,advantages and [23]Frantz T S,Ruiz W A,da Rosa C A,et al.Synthesis of ZSM-5 limitations.Appl Surf Sci,2002,196(1-4):157 with high sodium content for CO,adsorption.Microporous [13]Fu Y G,Liu Y S,Yang X,et al.Thermodynamic analysis of Mesoporous Mater,2016,222:209 molecular simulations of N2 and O,adsorption on zeolites under [24]Li X,Li Z,Luo L A.New TPD model for activation energy plateau special conditions.Appl SurfSci,2019,480:868 estimation.C/ESC J.2006,57(2):258 [14]Meng MM,Liu Y S,Li Z Y,et al.Adsorption characteristics of (李湘,李忠,罗灵爱.程序升温脱附活化能估算新模型.化工学 low concentration gaseous naphthalene on ordered mesoporous 报,2006,57(2):258) carbons.CIESC J,2017,68(8):3109 [25]Kondo S,Ishikawa T,Abe I,et al.Adsorption Science.2nd Ed. (孟苗苗,刘应书,李子宜,等.有序介孔碳对低浓度气相萘的吸 Translated by LiGX.Beijing:Chemical Industry Press,2006 附特性分析.化工学报,2017,68(8):3109) (近藤精一,石川达雄,安部郁夫.吸附科学2版.李国希,译.北 [15]Yang Q,Liu YS,Li Z Y,et al.Study on the adsorption behaviours 京:化学工业出版社,2006) of naphthalene on MCM-41 and SBA-15 mesoporous molecular [26]Yamashita R,Saito Y,Sakuragawa S.Molecular sieving behavior sieves.J Fuel Chem Technol,2015,43(12):1482 of carbonized wood:selective adsorption of toluene from a gas (杨权,刘应书,李子宜,等.茶在介孔分子筛MCM-41与SBA- mixture containing a-pinene.J Wood Sci,2009,55(6):446Li Z Y, Liu Y S, Jiang L J, et al. Research progress on adsorption purification technology of gaseous polycyclic aromatic hydrocarbons. Chin J Eng, 2018, 40(2): 127 (李子宜, 刘应书, 姜理俊, 等. 气相多环芳烃的吸附净化技术研 究进展. 工程科学学报, 2018, 40(2):127) [4] Liu Y S, Li Z Y, Yang X, et al. Performance of mesoporous silicas (MCM-41 and SBA-15) and carbon (CMK-3) in the removal of gas-phase naphthalene: adsorption capacity, rate and regenerability. RSC Adv, 2016, 6(25): 21193 [5] Li Z Y, Liu Y S, Yang X, et al. Performance of mesoporous silicas and carbon in adsorptive removal of phenanthrene as a typical gaseous polycyclic aromatic hydrocarbon. Microporous Mesoporous Mater, 2017, 239: 9 [6] Yang X, Yi H H, Tang X L, et al. Behaviors and kinetics of toluene adsorption-desorption on activated carbons with varying pore structure. J Environ Sci, 2018, 67: 104 [7] Kustov L, Golubeva V, Korableva A, et al. Alkaline-modified ZSM-5 zeolite to control hydrocarbon cold-start emission. Microporous Mesoporous Mater, 2018, 260: 54 [8] Lillo-Ródenas M A, Cazorla-Amorós D, Linares-Solano A. Behaviour of activated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentrations. Carbon, 2005, 43(8): 1758 [9] Koriabkina A O, de Jong A M, Schuring D, et al. Influence of the acid sites on the intracrystalline diffusion of hexanes and their mixtures within MFI-zeolites. J Phys Chem B, 2002, 106(37): 9559 [10] Jeppu G P, Clement T P. A modified Langmuir-Freundlich isotherm model for simulating pH-dependent adsorption effects. J Contam Hydrol, 2012, 129-130: 46 [11] Bülow M, Shen D M, Jale S. Measurement of sorption equilibria under isosteric conditions: the principles, advantages and limitations. Appl Surf Sci, 2002, 196(1-4): 157 [12] Fu Y G, Liu Y S, Yang X, et al. Thermodynamic analysis of molecular simulations of N2 and O2 adsorption on zeolites under plateau special conditions. Appl Surf Sci, 2019, 480: 868 [13] Meng M M, Liu Y S, Li Z Y, et al. Adsorption characteristics of low concentration gaseous naphthalene on ordered mesoporous carbons. CIESC J, 2017, 68(8): 3109 (孟苗苗, 刘应书, 李子宜, 等. 有序介孔碳对低浓度气相萘的吸 附特性分析. 化工学报, 2017, 68(8):3109) [14] Yang Q, Liu Y S, Li Z Y, et al. Study on the adsorption behaviours of naphthalene on MCM-41 and SBA-15 mesoporous molecular sieves. J Fuel Chem Technol, 2015, 43(12): 1482 (杨权, 刘应书, 李子宜, 等. 萘在介孔分子筛 MCM-41 与 SBA- [15] 15 上的吸附特性研究. 燃料化学学报, 2015, 43(12):1482) Wang Z Y, Liu Y S, Li Z Y, et al. Desorption behavior of ethanedioic acid and benzoic acid on activated carbon. CIESC J, 2015, 66(10): 4016 (王占营, 刘应书, 李子宜, 等. 乙二酸和苯甲酸在活性炭上的脱 附行为. 化工学报, 2015, 66(10):4016) [16] Otomo R, Kosugi R, Kamiya Y, et al. Modification of Sn-Beta zeolite: characterization of acidic/basic properties and catalytic performance in Baeyer–Villiger oxidation. Catal Sci Technol, 2016, 6(8): 2787 [17] Yang L H, Gao C H, Wang D, et al. Synthesis and adsorption of ZSM-5 zeolite. J Hebei Univ Technol, 2010, 39(5): 33 (杨丽辉, 高长虹, 王东, 等. ZSM-5型分子筛的合成及其吸附性 能. 河北工业大学学报, 2010, 39(5):33) [18] Zhang L, Feng Z Y, Wei J Y, et al. Zeolite adsorbents used for dutrex removal in cold start exhaust. Mater Rev, 2012, 26(13): 139 (张兰, 冯朝阳, 尉继英, 等. 分子筛对汽车冷启动尾气中芳香烃 吸附性能的研究进展. 材料导报, 2012, 26(13):139) [19] Tansel B, Sager J, Rector T, et al. Significance of hydrated radius and hydration shells on ionic permeability during nanofiltration in dead end and cross flow modes. Sep Purif Technol, 2006, 51(1): 40 [20] Shiue A, Kang Y H, Hu S C, et al. Vapor adsorption characteristics of toluene in an activated carbon adsorbent-loaded nonwoven fabric media for chemical filters applied to cleanrooms. Build Environ, 2010, 45(10): 2123 [21] Shen W L, Li J X, Yang Y, et al. Binary adsorption equilibrium of CH4 , N2 and CO2 on zeolite ZSM-5. CIESC J, 2014, 65(9): 3490 (沈文龙, 李嘉旭, 杨颖, 等. 基于沸石ZSM-5的CH4 /N2 /CO2二元 体系吸附平衡. 化工学报, 2014, 65(9):3490) [22] Frantz T S, Ruiz W A, da Rosa C A, et al. Synthesis of ZSM-5 with high sodium content for CO2 adsorption. Microporous Mesoporous Mater, 2016, 222: 209 [23] Li X, Li Z, Luo L A. New TPD model for activation energy estimation. CIESC J, 2006, 57(2): 258 (李湘, 李忠, 罗灵爱. 程序升温脱附活化能估算新模型. 化工学 报, 2006, 57(2):258) [24] Kondo S, Ishikawa T, Abe I, et al. Adsorption Science. 2nd Ed. Translated by Li G X. Beijing: Chemical Industry Press, 2006 ( 近藤精一, 石川达雄, 安部郁夫. 吸附科学. 2版. 李国希, 译. 北 京: 化学工业出版社, 2006) [25] Yamashita R, Saito Y, Sakuragawa S. Molecular sieving behavior of carbonized wood: selective adsorption of toluene from a gas mixture containing α-pinene. J Wood Sci, 2009, 55(6): 446 [26] · 1542 · 工程科学学报,第 43 卷,第 11 期